An efficient and green method for the synthesis of pyrano[3,2-c]chromene or pyrano[4,3-b]pyrone derivatives is described by using a three-component condensation process of malononitrile, aldehyde, and 4-hydroxycoumarine or 4-hydroxypyrone in [BMIm]BF4-LiCl as an ionic liquid.
A new type of magnetically-recoverable catalyst was synthesized by the immobilization of H3PW12O40 on the surface of silica-encapsulated -Fe2O3 nanoparticles. A series of novel 1,3,5-triaryl pyrazoline derivatives has been synthesized by the reaction of chalcone and phenylhydrazine in the presence of the -Fe2O3@SiO2-PW12nanoparticles, in high yields. The structures of compounds obtained were determined by IR […]
In this research, different alcohols and phenols are subjected to the reaction with HMDS in the presence of ionic liquid and silica-supported catalysts. Silylation was accomplished under mild reaction conditions at room temperature in short reaction times and good to excellent yields.
Vahid Khakyzadeh was born in Hamedan, Iran. He received his B.S. degree (Pure Chemistry) and M.S. degree (Organic Chemistry) from Bu-Ali Sina University, Hamedan, Iran, at 2008, 2010 respectively under supervision of professor Mohammad Ali Zolfigol. He is currently working on his Ph. D. under the supervision of professor Mohammad Ali Zolfigol in organic chemistry. […]
A practical and green method for the synthesis of 5H-dibenzo[b,i]xanthene-tetraones and spiro[dibenzo[b,i]xanthene-13,3′-indoline]-pentaones by the condensation of 2-hydroxynaphthalene-1,4-dione with aldehydes or isatins, respectively, in the presence of a catalytic amount of cellulose sulfuric acid (CSA) under solvent-free conditions at 100 °C is described. The significant features of this procedure are high yields of the products, simple […]
Surface of mesostructured silica, KIT-6, was modified by grafting 3-aminopropyl-triethoxysilane (APTES) to have the positive charge, and thus, to provide sites for the immobilization of H3PW12O40 (PW12). This modified-nanosized mesoporous silica (PW12-APTES@ KIT-6) was characterized by FTIR, XRD, BET and TEM. The oxidation of sulfides occurs effectively and selectively with H2O2 as the oxidant. PW12-APTES@KIT-6 […]
Two possible isomers of some 1,3-diaryl-H-benzo[f]chromene have been studied using density functional theory. Structures of E1 and E2 isomers were optimized at the B3LYP and MP2 levels with different basis sets. The total electronic energies show that E2 isomer is about 3-5 kcal/mol more stable than E1 isomer and this energy difference is attributed to […]
The direct and indirect methods in solvent media and grinding method in a solvent-free media were used to prepare the MCM-41/ZnO and MCM-48/ZnO photocatalysts. The X-ray diffraction (XRD) patterns showed that zinc oxide nanoparticles were put into MCM-41 and MCM-48 substrates and there were ZnO crystallites as secondary phase in the extra framework of mesoporous […]
A highly efficient procedure for the preparation of N,N’-alkylidenebisamides in the presence of BF3.SiO2 as a catalyst is described. N,N’-alkylidenebisamides have been prepared via one-pot three-component condensation reaction of various aldehydes and amides. All of the reactions proceeded in high yields and in moderately short reaction times.
Sulfuric acid {[3-(3-silicapropyl)sulfanyl]propyl}ester (SASPSPE) is employed as a recyclable catalyst for the synthesis of α-amino nitriles. These syntheses were performed via a one-pot three-component condensation of aldehydes, amines, and trimethylsilyl cyanide under mild reaction conditions at room temperature. The catalyst could be recycled and reused several times without any loss of efficiency.
