In this study, the nanoporous γ-alumina catalysts were prepared by the sol-gel method using hydrolysis of aluminum isopropoxide in the presence of TX-100 or gelatin/TX-100 mixture. Catalysts were characterized by XRD, FT-IR, TEM, BET-BJH and N2 adsorption-desorption isotherms. To investigate reactivity and selectivity of the synthesized catalysts, dehydration reaction of 2-octanol was carried out in […]
Elham Amouhadi was born in 1983 in Esfahan, Iran. She received her B.Sc. in Applied Chemistry (2005) and M.Sc. in Inorganic Chemistry (2016) from Islamic Azad University Shahreza Branch. She is currently working towards her Ph.D. under the supervision of Professor Razieh Fazaeli at Islamic Azad University Shahreza Branch. Her research interest is the design, […]
In the current study, a new methodology for the epoxidation of alkenes was developed. In this regard, the required ligand was synthesized from the reaction of isatin and 1,4-phenylenediamine to afford (3Z,3’Z)-3,3′-(1,4-phenylenebis(azaneylylidene))bis(indolin-2-one) ligand. Then, the two coordinate ligands were metallated using Cd and Mn/Fe/Co/Ni to obtain a series of hybrid dual metallic complexes containing (Cd […]
In this research, a novel approach for the epoxidation of alkene derivatives was constructed. Based on this fact, the appropriate ligand was provided from the reaction of hydrazine hydrate and 5-methyl-1,3,4-thiadiazole-2-thiol. Then, after preparation of the intermediate compound, the treatment of the pointed compound and 4-hydroxy-3,5-dimethoxybenzaldehyde in the presence of a few drops of glacial […]
