References

  1. Gawande, M.B., K. Ariga, and Y. Yamauchi, SingleAtom Catalysts. 2021. p. 2101584.
  2. Jeong, H., et al., Highly durable metal ensemble catalysts with full dispersion for automotive applications beyond single-atom catalysts. Nature Catalysis, 2020. 3(4): p. 368-375.
  3. Chen, Y., et al., Single-atom catalysts: synthetic strategies and electrochemical applications. Joule, 2018. 2(7): p. 1242-1264.
  4. Gawande, M.B., P. Fornasiero, and R. Zbořil, Carbon-based single-atom catalysts for advanced applications. ACS Catalysis, 2020. 10(3): p. 2231-2259.
  5. Ratnayake, S., et al., Combined Zr and Y phosphate coatings reinforced with chemically anchored B2O3 for the oxidation inhibition of carbon fiber. Materialia, 2021. 15: p. 100984.
  6. Liu, Y., et al., Unravelling the Enigma of Nonoxidative Conversion of Methane on Iron SingleAtom Catalysts. Angewandte Chemie International Edition, 2020. 59(42): p. 18586-18590.
  7. Peng, Y., B. Lu, and S. Chen, Carbonsupported single atom catalysts for electrochemical energy conversion and storage. Advanced Materials, 2018. 30(48): p. 1801995.
  8. Yang, Y., et al., Recent progress of carbon-supported single-atom catalysts for energy conversion and storage. Matter, 2020. 3(5): p. 1442-1476.
  9. Fan, M., et al., Improving the catalytic activity of carbonsupported single atom catalysts by polynary metal or heteroatom doping. Small, 2020. 16(22): p. 1906782.
  10. Zhuo, H.-Y., et al., Theoretical understandings of graphene-based metal single-atom catalysts: stability and catalytic performance. Chemical Reviews, 2020. 120(21): p. 12315-12341.
  11. Tang, Y., et al., Theoretical insights into the CO/NO oxidation mechanisms on single-atom catalysts anchored H4, 4, 4-graphyne and H4, 4, 4-graphyne/graphene sheets. Fuel, 2022. 319: p. 123810.
  12. Hu, L., et al., Density functional calculation of transition metal adatom adsorption on graphene. Physica B: Condensed Matter, 2010. 405(16): p. 3337-3341.
  13. Wu, M., et al., Stability, electronic, and magnetic behaviors of Cu adsorbed graphene: A first-principles study. Applied Physics Letters, 2009. 94(10): p. 102505.
  14. Chan, K.T., J. Neaton, and M.L. Cohen, First-principles study of metal adatom adsorption on graphene. Physical Review B, 2008. 77(23): p. 235430.
  15. Liu, X., et al., Bonding and charge transfer by metal adatom adsorption on graphene. Physical Review B, 2011. 83(23): p. 235411.
  16. Rivera‐Cárcamo, C. and P. Serp, Single atom catalysts on carbonbased materials. ChemCatChem, 2018. 10(22): p. 5058-5091.
  17. Jing, N., et al., Effect of defects on Young's modulus of graphene sheets: a molecular dynamics simulation. Rsc Advances, 2012. 2(24): p. 9124-9129.
  18. Banhart, F., J. Kotakoski, and A.V. Krasheninnikov, Structural defects in graphene. ACS nano, 2011. 5(1): p. 26-41.
  19. XIE, P.-Y., et al., Enhanced bonding between noble metal adatoms and graphene with point defects. Acta Physico-Chimica Sinica, 2012. 28(2): p. 331-337.
  20. Wu, J., et al., Tuning the Electrochemical Reactivity of Boronand NitrogenSubstituted Graphene. Advanced Materials, 2016. 28(29): p. 6239-6246.
  21. Qiu, H.J., et al., Nanoporous graphene with singleatom nickel dopants: an efficient and stable catalyst for electrochemical hydrogen production. Angewandte Chemie International Edition, 2015. 54(47): p. 14031-14035.
  22. Jiang, K. and H. Wang, Electrocatalysis over graphene-defect-coordinated transition-metal single-atom catalysts. Chem, 2018. 4(2): p. 194-195.
  23. Chouhan, A., H.P. Mungse, and O.P. Khatri, Surface chemistry of graphene and graphene oxide: A versatile route for their dispersion and tribological applications. Advances in Colloid and Interface Science, 2020: p. 102215.
  24. Pei, S., et al., Green synthesis of graphene oxide by seconds timescale water electrolytic oxidation. Nature communications, 2018. 9(1): p. 1-9.
  25. Ren, S., et al., Graphene-supported metal single-atom catalysts: a concise review. Science China Materials, 2020. 63(6): p. 903-920.
  26. Ma, D., et al., Graphyne as a promising substrate for the noble-metal single-atom catalysts. Carbon, 2015. 95: p. 756-765.
  27. Liu, R., et al., Nitrogen-doped graphdiyne as a metal-free catalyst for high-performance oxygen reduction reactions. Nanoscale, 2014. 6(19): p. 11336-11343.
  28. Axet, M.R., et al., Surface coordination chemistry on graphene and two-dimensional carbon materials for well-defined single atom supported catalysts. Advances in Organometallic Chemistry, 2019. 71: p. 53-174.
  29. Aggarwal, M., et al., Photocatalytic Carbon Dioxide Reduction: Exploring the Role of Ultrathin 2D Graphitic Carbon Nitride (g-C3N4). Chemical Engineering Journal, 2021: p. 131402.
  30. Yang, M., et al., Structural stability and O2 dissociation on nitrogen-doped graphene with transition metal atoms embedded: A first-principles study. Aip Advances, 2015. 5(6): p. 067136.
  31. Kong, N., et al., Single Vanadium Atoms Anchored on Graphitic Carbon Nitride as a High-Performance Catalyst for Non-oxidative Propane Dehydrogenation. ACS nano, 2020. 14 (5): p. 5772-5779.
  32. Li, X.-H. and M. Antonietti, Metal nanoparticles at mesoporous N-doped carbons and carbon nitrides: functional Mott–Schottky heterojunctions for catalysis. Chemical Society Reviews, 2013. 42 (16): p. 6593-6604.
  33. Nasir, S., et al., Carbon-based nanomaterials/allotropes: A glimpse of their synthesis, properties and some applications. Materials, 2018. 11(2): p. 295.
  34. Shinohara, H., Endohedral metallofullerenes. Reports on Progress in Physics, 2000. 63(6): p. 843.
  35. Sun, B.-Y., et al., Entrapping of exohedral metallofullerenes in carbon nanotubes:(CsC60) n@ SWNT nano-peapods. Journal of the American Chemical Society, 2005. 127(51): p. 17972-17973.
  36. Changgeng, D., et al., Geometric and electronic structures of metal-substituted fullerenes C 59 M (M= Fe, Co, Ni, and Rh). The Journal of chemical physics, 1999. 111(18): p. 8481-8485.
  37. Stoyanov, S.R., A.V. Titov, and P. Král, Transition metal and nitrogen doped carbon nanostructures. Coordination Chemistry Reviews, 2009. 253(23-24): p. 2852-2871.
  38. Marco-Martínez, J., et al., Enantioselective Cycloaddition of Münchnones onto [60] Fullerene: Organocatalysis versus Metal Catalysis. Journal of the American Chemical Society, 2014. 136(7): p. 2897-2904.
  39. Soltani, A., et al., Interaction of hydrogen with Pd-and co-decorated C24 fullerenes: density functional theory study. Synthetic Metals, 2017. 234: p. 1-8.
  40. He, H., et al., Bioadhesive injectable hydrogel with phenolic carbon quantum dot supported Pd single atom nanozymes as a localized immunomodulation niche for cancer catalytic immunotherapy. Biomaterials, 2022. 280: p. 121272.
  41. Fan, X., et al., A conjugated porous polymer complexed with a single-atom cobalt catalyst as an electrocatalytic sulfur host for enhancing cathode reaction kinetics. Energy Storage Materials, 2021. 41: p. 14-23.
  42. Kamiya, K., et al., Platinum-modified covalent triazine frameworks hybridized with carbon nanoparticles as methanol-tolerant oxygen reduction electrocatalysts. Nature Communications, 2014. 5(1): p. 1-6.
  43. Jiao, S., et al., Point-defect-optimized electron distribution for enhanced electrocatalysis: towards the perfection of the imperfections. Nano Today, 2020. 31: p. 100833.
  44. Zhang, L., et al., Single-atom catalyst: a rising star for green synthesis of fine chemicals. National Science Review, 2018. 5(5): p. 653-672.
  45. Singh, B., et al., Singleatom catalysts: a sustainable pathway for the advanced catalytic applications. Small, 2021. 17(16): p. 2006473.
  46. Guo, J., et al., A minireview on the synthesis of single atom catalysts. RSC advances, 2022. 12(15): p. 9373-9394.
  47. Kaiser, S.K., et al., Single-atom catalysts across the periodic table. Chemical reviews, 2020. 120(21): p. 11703-11809.
  48. Vilé, G., et al., Cover Picture: A Stable SingleSite Palladium Catalyst for Hydrogenations (Angew. Chem. Int. Ed. 38/2015). Angewandte Chemie International Edition, 2015. 54(38): p. 10987-10987.
  49. Xi, J., et al., Confined-interface-directed synthesis of Palladium single-atom catalysts on graphene/amorphous carbon. Applied Catalysis B: Environmental, 2018. 225: p. 291-297.
  50. Reuillard, B., et al., A Poly (cobaloxime)/Carbon Nanotube Electrode: Freestanding Buckypaper with PolymerEnhanced H2Evolution Performance. Angewandte Chemie, 2016. 128(12): p. 4020-4025.
  51. Kim, Y.T., et al., Fine size control of platinum on carbon nanotubes: from single atoms to clusters. Angewandte Chemie International Edition, 2006. 45(3): p. 407-411.
  52. Tran, P.D., et al., Noncovalent modification of carbon nanotubes with pyrenefunctionalized nickel complexes: carbon monoxide tolerant catalysts for hydrogen evolution and uptake. Angewandte Chemie, 2011. 123(6): p. 1407-1410.
  53. Georgakilas, V., et al., Noncovalent functionalization of graphene and graphene oxide for energy materials, biosensing, catalytic, and biomedical applications. Chemical reviews, 2016. 116(9): p. 5464-5519.
  54. He, X., et al., Mechanochemical kilogram-scale synthesis of noble metal single-atom catalysts. Cell Reports Physical Science, 2020. 1(1): p. 100004.
  55. Chen, X., et al., Highly active and stable single iron site confined in graphene nanosheets for oxygen reduction reaction. Nano Energy, 2017. 32: p. 353-358.
  56. Cui, X., et al., A graphene composite material with single cobalt active sites: a highly efficient counter electrode for dyesensitized solar cells. Angewandte Chemie International Edition, 2016. 55(23): p. 6708-6712.
  57. Robertson, A.W., et al., Spatial control of defect creation in graphene at the nanoscale. Nature communications, 2012. 3(1): p. 1-7.
  58. Robertson, A.W., et al., Dynamics of single Fe atoms in graphene vacancies. Nano letters, 2013. 13(4): p. 1468-1475.
  59. Wang, H., et al., Doping monolayer graphene with single atom substitutions. Nano letters, 2012. 12(1): p. 141-144.
  60. Wang, H., et al., Interaction between single gold atom and the graphene edge: A study via aberration-corrected transmission electron microscopy. Nanoscale, 2012. 4(9): p. 2920-2925.
  61. Chen, Y.N., X. Zhang, and Z. Zhou, Carbonbased substrates for highly dispersed nanoparticle and even singleatom electrocatalysts. Small Methods, 2019. 3(9): p. 1900050.
  62. Wang, L., et al., Preparation, characterization and catalytic performance of single-atom catalysts. Chinese Journal of Catalysis, 2017. 38(9): p. 1528-1539.
  63. Song, Z., et al., Recent Advances in MOFDerived Single Atom Catalysts for Electrochemical Applications. Advanced Energy Materials, 2020. 10(38): p. 2001561.
  64. Kaneti, Y.V., et al., Nanoarchitectured design of porous materials and nanocomposites from metalorganic frameworks. Advanced materials, 2017. 29(12): p. 1604898.
  65. Zhao, S.-N., et al., Highly efficient heterogeneous catalytic materials derived from metal-organic framework supports/precursors. Coordination Chemistry Reviews, 2017. 337: p. 80-96.
  66. Ma, T.Y., et al., Metal–organic framework derived hybrid Co3O4-carbon porous nanowire arrays as reversible oxygen evolution electrodes. Journal of the American Chemical Society, 2014. 136(39): p. 13925-13931.
  67. Jiao, L. and H.-L. Jiang, Metal-organic-framework-based single-atom catalysts for energy applications. Chem, 2019. 5(4): p. 786-804.
  68. Zhou, D., et al., Atomic regulation of metal-organic framework derived carbon-based single-atom catalysts for electrochemical CO 2 reduction reaction. Journal of Materials Chemistry A, 2021.
  69. Zou, L., et al., SingleAtom Catalysts Derived from Metal–Organic Frameworks for Electrochemical Applications. Small, 2021. 17(16): p. 2004809.
  70. Yin, P., et al., Single cobalt atoms with precise Ncoordination as superior oxygen reduction reaction catalysts. Angewandte Chemie, 2016. 128(36): p. 10958-10963.
  71. Zhang, F., et al., In situ mosaic strategy generated Co-based N-doped mesoporous carbon for highly selective hydrogenation of nitroaromatics. Journal of Catalysis, 2017. 348: p. 212-222.
  72. Wang, J., et al., Design of N-coordinated dual-metal sites: a stable and active Pt-free catalyst for acidic oxygen reduction reaction. Journal of the American Chemical Society, 2017. 139(48): p. 17281-17284.
  73. Xia, Y., Z. Yang, and R. Mokaya, Templated nanoscale porous carbons. Nanoscale, 2010. 2(5): p. 639-659.
  74. Liang, H.-W., et al., Mesoporous metal–nitrogen-doped carbon electrocatalysts for highly efficient oxygen reduction reaction. Journal of the American Chemical Society, 2013. 135(43): p. 16002-16005.
  75. Zhang, N., et al., Single-atom site catalysts for environmental catalysis. Nano Research, 2020: p. 1-18.
  76. Sun, S., et al., Single-atom catalysis using Pt/graphene achieved through atomic layer deposition. Scientific reports, 2013. 3(1): p. 1-9.
  77. Yan, H., et al., Single-atom Pd1/graphene catalyst achieved by atomic layer deposition: remarkable performance in selective hydrogenation of 1, 3-butadiene. Journal of the American chemical society, 2015. 137(33): p. 10484-10487.
  78. Zhang, Q. and J. Guan, Singleatom catalysts for electrocatalytic applications. Advanced Functional Materials, 2020. 30(31): p. 2000768.
  79. Zhao, Y., R. Tang, and R. Huang, Palladium supported on graphitic carbon nitride: an efficient and recyclable heterogeneous catalyst for reduction of nitroarenes and Suzuki coupling reaction. Catalysis Letters, 2015. 145(11): p. 1961-1971.
  80. Shang, Y., et al., Carbon-based single atom catalyst: Synthesis, characterization, DFT calculations. Chinese Chemical Letters, 2021.
  81. Tavakkoli, M., et al., Mesoporous Single-Atom-Doped Graphene–Carbon Nanotube Hybrid: Synthesis and Tunable Electrocatalytic Activity for Oxygen Evolution and Reduction Reactions. ACS Catalysis, 2020. 10(8): p. 4647-4658.
  82. Li, H., et al., Carbon-supported metal single atom catalysts. New Carbon Materials, 2018. 33(1): p. 1-11.
  83. Zhang, H., et al., Singleatom catalysts: emerging multifunctional materials in heterogeneous catalysis. Advanced Energy Materials, 2018. 8(1): p. 1701343.
  84. Fu, X., et al., In situ polymer graphenization ingrained with nanoporosity in a nitrogenous electrocatalyst boosting the performance of polymerelectrolytemembrane fuel cells. Advanced Materials, 2017. 29(7): p. 1604456.
  85. Chung, H.T., et al., Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst. Science, 2017. 357(6350): p. 479-484.
  86. Mahanta, U., et al., Ionic-liquid-based deep eutectic solvents as novel electrolytes for supercapacitors: COSMO-SAC predictions, synthesis, and characterization. ACS Sustainable Chemistry & Engineering, 2019. 8(1): p. 372-381.
  87. Veena Gopalan, E., et al., Template-assisted synthesis and characterization of passivated nickel nanoparticles. Nanoscale research letters, 2010. 5(5): p. 889-897.
  88. Zhao, S., et al., Controlled Onepot Synthesis of Nickel Single Atoms Embedded in Carbon Nanotube and Graphene Supports with High Loading. ChemNanoMat, 2020. 6(7): p. 1063-1074.
  89. Chen, Z., et al., SingleAtom Catalysis: From Simple Reactions to the Synthesis of Complex Molecules. Advanced Materials, 2021: p. 2103882.
  90. Ding, S., et al., High-temperature flame spray pyrolysis induced stabilization of Pt single-atom catalysts. Applied Catalysis B: Environmental, 2021. 281: p. 119471.
  91. Yang, X.-F., et al., Single-atom catalysts: a new frontier in heterogeneous catalysis. Accounts of chemical research, 2013. 46(8): p. 1740-1748.
  92. Asokan, C., L. DeRita, and P. Christopher, Using probe molecule FTIR spectroscopy to identify and characterize Pt-group metal based single atom catalysts. Chinese Journal of Catalysis, 2017. 38(9): p. 1473.
  93. Bakandritsos, A., et al., MixedValence SingleAtom Catalyst Derived from Functionalized Graphene. Advanced Materials, 2019. 31(17): p. 1900323.
  94. Choi, W.I., et al., Combinatorial Search for highactivity hydrogen catalysts based on transitionmetalembedded graphitic carbons. Advanced Energy Materials, 2015. 5(23): p. 1501423.
  95. Xiao, M., et al., Solar energy conversion on g-C3N4 photocatalyst: light harvesting, charge separation, and surface kinetics. Journal of energy chemistry, 2018. 27(4): p. 1111-1123.
  96. Gao, C., et al., Heterogeneous single-atom photocatalysts: Fundamentals and applications. Chemical reviews, 2020. 120(21): p. 12175-12216.
  97. Wang, Q., et al., Single-atom catalysts for photocatalytic reactions. ACS Sustainable Chemistry & Engineering, 2019. 7(7): p. 6430-6443.
  98. Zhou, P., et al., Metal single atom strategy greatly boosts photocatalytic methyl activation and C–C coupling for the coproduction of high-value-added multicarbon compounds and hydrogen. ACS Catalysis, 2020. 10(16): p. 9109-9114.
  99. Chu, C., et al., Spatially separating redox centers on 2D carbon nitride with cobalt single atom for photocatalytic H2O2 production. Proceedings of the National Academy of Sciences, 2020. 117(12): p. 6376-6382.
  100. Zhao, Q., et al., Effective and durable Co single atomic cocatalysts for photocatalytic hydrogen production. ACS applied materials & interfaces, 2017. 9(49): p. 42734-42741.
  101. Lin, C., et al., Porphyrin-Based Metal–Organic Frameworks for Efficient Photocatalytic H2 Production under Visible-Light Irradiation. Inorganic Chemistry, 2021. 60(6): p. 3988-3995.
  102. Roy, S. and E. Reisner, VisibleLightDriven CO2 Reduction by Mesoporous Carbon Nitride Modified with Polymeric Cobalt Phthalocyanine. Angewandte Chemie International Edition, 2019. 58(35): p. 12180-12184.
  103. Wang, K., et al., Molten salt assistant synthesis of three-dimensional cobalt doped graphitic carbon nitride for photocatalytic N2 fixation: experiment and DFT simulation analysis. Chemical Engineering Journal, 2019. 368: p. 896-904.
  104. Guo, X.-W., et al., Single-atom molybdenum immobilized on photoactive carbon nitride as efficient photocatalysts for ambient nitrogen fixation in pure water. Journal of Materials Chemistry A, 2019. 7(34): p. 19831-19837.
  105. Zeng, Z., et al., Single-atom platinum confined by the interlayer nanospace of carbon nitride for efficient photocatalytic hydrogen evolution. Nano Energy, 2020. 69: p. 104409.
  106. Wang, F., et al., The facile synthesis of a single atom-dispersed silver-modified ultrathin gC 3 N 4 hybrid for the enhanced visible-light photocatalytic degradation of sulfamethazine with peroxymonosulfate. Dalton Transactions, 2018. 47(20): p. 6924-6933.
  107. Qiu, S., et al., Carbon dots decorated ultrathin CdS nanosheets enabling in-situ anchored Pt single atoms: A highly efficient solar-driven photocatalyst for hydrogen evolution. Applied Catalysis B: Environmental, 2019. 259: p. 118036.
  108. Ma, M., et al., Role of N in TransitionMetalNitrides for Anchoring PlatinumGroup Metal Atoms toward SingleAtom Catalysis. Small Methods, 2022: p. 2200295.
  109. Gao, G., et al., Single atom (Pd/Pt) supported on graphitic carbon nitride as an efficient photocatalyst for visible-light reduction of carbon dioxide. Journal of the American Chemical Society, 2016. 138(19): p. 6292-6297.
  110. Wang, F., et al., Novel ternary photocatalyst of single atom-dispersed silver and carbon quantum dots co-loaded with ultrathin g-C3N4 for broad spectrum photocatalytic degradation of naproxen. Applied catalysis B: environmental, 2018. 221: p. 510-520.
  111. Ye, X., Y. Cui, and X. Wang, FerroceneModified Carbon Nitride for Direct Oxidation of Benzene to Phenol with Visible Light. ChemSusChem, 2014. 7(3): p. 738-742.
  112. Yang, J., et al., Electronic Metal–Support Interaction of SingleAtom Catalysts and Applications in Electrocatalysis. Advanced Materials, 2020. 32(49): p. 2003300.
  113. Lu, B., Q. Liu, and S. Chen, Electrocatalysis of single-atom sites: impacts of atomic coordination. ACS Catalysis, 2020. 10(14): p. 7584-7618.
  114. Umer, M., et al., Machine learning assisted high-throughput screening of transition metal single atom based superb hydrogen evolution electrocatalysts. Journal of Materials Chemistry A, 2022. 10(12): p. 6679-6689.
  115. Hu, J., et al., Carbon-based Single Atom Catalysts for Tailoring ORR Pathway: A Concise Review. Journal of Materials Chemistry A, 2021.
  116. Pu, Z., et al., Single-atom catalysts for electrochemical hydrogen evolution reaction: recent advances and future perspectives. Nano-Micro Letters, 2020. 12(1): p. 1-29.
  117. Fan, L., et al., Atomically isolated nickel species anchored on graphitized carbon for efficient hydrogen evolution electrocatalysis. Nature communications, 2016. 7(1): p. 1-7.
  118. Chen, X., et al., Multiscale porous single-atom Co catalysts for epoxidation with O 2. Journal of Materials Chemistry A, 2022. 10(11): p. 6016-6022.
  119. Fei, H., et al., Atomic cobalt on nitrogen-doped graphene for hydrogen generation. Nature communications, 2015. 6(1): p. 1-8.
  120. Zitolo, A., et al., Identification of catalytic sites for oxygen reduction in iron-and nitrogen-doped graphene materials. Nature materials, 2015. 14(9): p. 937-942.
  121. Zhang, X., et al., Catalytically active single-atom niobium in graphitic layers. Nature communications, 2013. 4(1): p. 1-7.
  122. Guo, J., et al., Ultrasmall tungsten carbide catalysts stabilized in graphitic layers for high-performance oxygen reduction reaction. Nano Energy, 2016. 28: p. 261-268.
  123. Zhang, Z., et al., Facile synthesis of a Ru-dispersed N-doped carbon framework catalyst for electrochemical nitrogen reduction. Catalysis Science & Technology, 2020. 10(5): p. 1336-1342.
  124. Sun, T., et al., Single-atomic cobalt sites embedded in hierarchically ordered porous nitrogen-doped carbon as a superior bifunctional electrocatalyst. Proceedings of the National Academy of Sciences, 2018. 115(50): p. 12692-12697.
  125. Cao, L., et al., Identification of single-atom active sites in carbon-based cobalt catalysts during electrocatalytic hydrogen evolution. Nature Catalysis, 2019. 2(2): p. 134-141.
  126. Deng, D., et al., A single iron site confined in a graphene matrix for the catalytic oxidation of benzene at room temperature. Science advances, 2015. 1(11): p. e1500462.
  127. Vidal, S., et al., Fullerenes for catalysis: metallofullerenes in hydrogen transfer reactions. Chemical Communications, 2017. 53(35): p. 4842-4844.
  128. Jin, C., et al., Single-atom nickel confined nanotube superstructure as support for catalytic wet air oxidation of acetic acid. Communications Chemistry, 2019. 2(1): p. 1-7.
  129. Zhang, B., et al., Stabilizing a platinum1 singleatom catalyst on supported phosphomolybdic acid without compromising hydrogenation activity. Angewandte Chemie, 2016. 128(29): p. 8459-8463.
  130. Mitchell, S., E. Vorobyeva, and J. Pérez‐Ramírez, The multifaceted reactivity of singleatom heterogeneous catalysts. Angewandte Chemie International Edition, 2018. 57(47): p. 15316-15329.
  131. Erünal, E., et al., Enhancement of hydrogen storage capacity of multi-walled carbon nanotubes with palladium doping prepared through supercritical CO2 deposition method. International Journal of Hydrogen Energy, 2018. 43(23): p. 10755-10764.
  132. Li, M., et al., Highly efficient single atom cobalt catalyst for selective oxidation of alcohols. Applied Catalysis A: General, 2017. 543: p. 61-66.
  133. He, W.-L., et al., Suspending ionic single-atom catalysts in porphyrinic frameworks for highly efficient aerobic oxidation at room temperature. Journal of catalysis, 2018. 358: p. 43-49.
  134. Lee, M., S. Ko, and S. Chang, Highly selective and practical hydrolytic oxidation of organosilanes to silanols catalyzed by a ruthenium complex. Journal of the American Chemical Society, 2000. 122(48): p. 12011-12012.
  135. Sen, R., D. Saha, and S. Koner, Lanthanide carboxylate frameworks: efficient heterogeneous catalytic system for epoxidation of olefins. Catalysis letters, 2012. 142(1): p. 124-130.
  136. Sofer, Z., et al., Uranium-and thorium-doped graphene for efficient oxygen and hydrogen peroxide reduction. ACS nano, 2014. 8(7): p. 7106-7114.
  137. Liu, J.-C., et al., Theoretical understanding of the stability of single-atom catalysts. National Science Review, 2018. 5(5): p. 638-641.
  138. Wang, H., et al., Surpassing the single-atom catalytic activity limit through paired Pt-O-Pt ensemble built from isolated Pt 1 atoms. Nature communications, 2019. 10(1): p. 1-12.