In this study, CuI nanoparticles as an efficient catalyst was used for the synthesis of 14-phenyl-8H-dibenzo[a,i]xanthene-8,13(14H)-diones using aldehydes, 2-naphthol and 2-hydroxynaphthalene-1,4-dione in aqueous media. In this study, it was found that water was the most effective solvent compared to others. Among several catalysts that were tested for this multi-component synthesis, CuI nanoparticles were the best […]
In the present study, the effects of calcium doping on the performance of the co-precipitated Cu-MgO catalysts prepared with different calcium loadings in the selective hydrogenation of furfuraldehyde were investigated. The results proved that the addition of this promoter had a remarkable impact on the catalytic performance. The conversion of furfuraldehyde enhanced up to 83% […]
A Simple and efficient method for synthesis of tetrahydropyrimido[4,5-b]quinoline derivatives via three component reaction of aromatic aldehydes, dimedone and 6-amino uracil derivatives using a catalytic amount of sulfonic acid functionalized nanoporous silica (SBA-15-Pr-SO3H) is described. The advantages of this method are easy and clean work-up, high yield, mild reaction condition, reusable catalyst and environmentally benign […]
Titania nanotubes (TNT) prepared by anodization of Ti foils were used for water splitting in a standalone cell. The concentration polarization between the anode side (1M NaOH) and cathode side (0.5 M H2SO4) ensured that the water splitting reaction could take place with no external bias and separate H2 and O2 evolution could be achieved. […]
This study introduces a green and efficient method for preparation of biologically-active substituted 4H-pyrans using the one-pot three-component reaction of aromatic aldehydes, dimedone and malononitrile in the presence of cobalt oxide nanoparticles. Co3O4 nanoparticles were used as an efficient catalyst for the synthesis of polyhydroquinoline derivatives by the reaction of aromatic aldehydes, ethyl acetoacetate, dimedone […]
Meysam Yarie was born in 1987 in Malayer/ Hamedan, Iran. He received his B.Sc. in Applied Chemistry (2010) from Malek-Ashtar University of Technology and M.Sc. in Organic Chemistry (2012) from Kurdistan University under the supervision of Dr. Kamal Amani. He is currently working towards his Ph.D. under the supervision of Professor Mohammad Ali Zolfigol. His […]
The present study deals with analysis of the activity of catalysts prepared by addition of different metals to Copper and Cobalt based catalysts for CO oxidation and the variation in activity caused by changes in composition. A series of catalysts were prepared with Cu:Co molar ratio 1:4 and a third metal (M= Ce, Ni, Au, […]
This article describe the applicability of 1,4-disulfopiperazine-1,4-diium chloride ([Piper-(SO3H)2].2Cl) as a green, versatile and Brönsted acidic ionic catalyst in the promotion of the synthesis of phthalazine derivatives via one-pot three component reaction between aromatic aldehydes, 1,3-diketone derivatives and phthalhydrazide under solvent-free reaction conditions. The main advantages of this method are: (1) simplicity of the procedure, […]
Nano-sized protonated ZSM–5 ( H-ZSM-5nanozeolite) was successfully synthesized by the hydrothermal method using the bagasse ash (BGA) as a new silica source. Cultivated BGA in the south of the Caspian Sea (Mazandaran province, Iran) was used for extracting silica powder. H-ZSM-5 was characterized by Fourier transform infrared (FT-IR), X-ray diffraction (XRD), scanning electronic microscopy (SEM) […]
Nickel oxide (NiO) nano-size powder is synthesized using nickel (II) acetate tetrahydrate, sodium lauryl sulfate (SLS) and ammonia as precursors. Applied surfactant is anionic surfactant. The sample was characterized by FT-IR, X-ray diffraction (XRD), scanning electron microscopy (SEM). The results obtained confirm the presence of nickel oxide nano-powders produced during chemical precipitation. Evaluation of the […]