In this paper, Ag/ZnO/HZSM-5ternary nanocomposites with different Ag loadings were prepared by the photo precipitation method. The prepared photocatalysts were characterized by XRD, BET, SEM and TEM. The photocatalytic activity of ZnO/HZSM-5 for 4-nitrophenol (4-NP) degradation was increased by silver doping. Effects of various parameters such as the initial concentration of 4-NP, pH and Ag […]
A novel and cost-effective catalyst for synthesis of 2,3′-dihydroquinazolin-4-(1H)-ones was developed utilizing a combined nanocomposite obtained from bonding TiCl3 to hydroxyl groups of nanofibrillated cellulose as a green and inexpensive support.The structure of the catalyst was investigated using the Fourier transform infrared spectroscopy (FT-IR), field emission scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS) techniques […]
Pyridinium based ionic liquids derived from β-picoline and n-alkylbromides were synthesized by a simple procedure at ambient temperature and then characterized. These neutral ionic liquids were investigated for their dual role as the solvent and promoter for the selective synthesis of a series of N-monomethylanilines using dimethylcarbonate as the methylating agent. A solvent free green […]
Meysam Yarie was born in 1987 in Malayer/ Hamedan, Iran. He received his B.Sc. in Applied Chemistry from Malek-Ashtar University of Technology and M.Sc. in Organic Chemistry from Kurdistan University under the supervision of Dr. Kamal Amani. He received his Ph.D. from Bu-Ali Sina University under the supervision of Professor Mohammad Ali Zolfigol. He is […]
The interaction in the system of SnO2 and h-MoO3 prepared by their joint mechanical activation in a roller-ring vibratory mill was investigated. A series of catalysts was prepared with SnO2: h-MoO3 molar ratio 1:1; 1:2.3; 2.3:1 and 5.7:1. The catalysts were characterized by various techniques including X-ray phase, X-ray diffraction (XRD) and synchronous thermal analysis, […]
In this work, an efficient and green procedure for the synthesis of dihydro-2-oxypyrroles has been developed. One-pot four-component condensation reaction of aniline derivatives (2 mmol), dialkyl acetylene dicarboxylate (1 mmol), and aldehydes ( 1 mmol) was done in ethanol at 65 °C in the presence of nano-Fe3O4@SiO2/SnCl4 as a magnetically reusable heterogeneous acid catalyst. The […]
Unripe grape juice (verjuice) as a natural catalyst was successfully applied to perform the one-pot reaction of aryl aldehydes, malononitrile, hydrazine hydrate and ethyl acetoacetate to synthesize pyranopyrazole derivatives in aqueous ethanol at room temperature in excellent yields. Furthermore, unripe grape juice catalyzed one-pot synthesis of hexahydroquinoline-3-carboxamide derivatives by the four-component reaction of arylaldehydes, dimedone, […]
In this work, at first, nano ZrO2 and Fe3O4/ZrO2 nanocomposite were prepared by sol-gel and co-precipitation methods, respectively. Then, Ag nanoparticles (Ag NPs) were mixed with themin environmentally friendly and mild conditions using C. cyanus flower extract as a reducing and stabilizing agent. The synthesized nanocomposites were characterized by FT-IR, XRD, FE-SEM, EDS, and VSM […]
1-Methyl-1H-imidazol-3-ium 2,3,4,5,6-pentafluorophenolate [mim]C6F5O as a novel nano ionic liquid was designed, synthesized and characterized by using various techniques such as Fourier transform spectroscopy infrared (FT-IR), nuclear magnetic resonance (NMR), x-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive x-ray spectroscopy (EDX), thermal gravimetric analysis (TGA), derivative thermal gravimetric (DTG) and elemental analysis […]
The kinetic characteristics of the Ni/Al2O3 and Ni/MgO-Al2O3 catalysts were investigated in CO2 reforming of methane (CRM). The reaction orders (α and β) and the rate constant (k) were calculated using the non-linear regression analysis, in which the sum of the squared differences of calculated and experimental CO2 reforming of methane rates were minimized. The […]