Eco-friendly preparation and characterization of CuMn2O4 nanoparticles with the green capping agent and their photocatalytic and photovoltaic applications

Authors

• Ali Sobhani-Nasab * ¹
• Mohammad Eghbali-Arani ²
• Seyed Mostafa Hosseinpour-Mashkani ¹
• Farhad Ahmadi ^{3, 4}
• Mehdi Rahimi-Nasrabadi ⁵

1. Young Researchers and Elite Club, Arak Branch, Islamic Azad University, Arak, Iran.
2. Department of Physics, University of Kashan, Kashan, Iran.
3. Department of Medicinal Chemistry, School of Pharmacy-International Campus, Iran University of Medical Sciences,
4. Tehran, Iran.
5. Department of Physics, Faculty of Science, University of Hormozgan, Bandar-Abbas, Iran.

Abstract

In this study, copper manganese oxide (CuMn₂O₄) nanoparticles were successfully synthesized by a simple sol-gel technique in the presence of lactose as the green capping agent. The lactose concentration effect on the crystalline size and magnetic properties of final products were systematically investigated. The structural, morphological, magnetic, and optical properties of as-obtained products were examined by techniques such as the Fourier transform infrared (FT-IR) spectroscopy, energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), scanning electron microscopy (FESEM), vibrating-sample magnetometer (VSM) and UV–Vis diffuse reflectance spectroscopy. SEM and VSM results show that lactose concentrations play an important role in the magnetic properties and morphology of CuMn₂O₄ nanoparticles. Degradation of type of dye (Rhodamine B = Rh B and Methyl orange = MO) under ultraviolet light was examined to assess the feasibility of using CuMn₂O₄ for photocatalytic activities. To demonstrate the possibility of developing an inexpensive solar cell, FTO/TiO₂/CuMn₂O₄/Pt-FTO, the CuMn₂O₄ paste was put on the top of the TiO₂ through the doctor blade technique.

Keywords

• Green capping agent
• Sol-gel technique
• Photocatalysis
• CuMn2O4
• nanoparticles