Density functional theory (DFT) calculations were performed to investigate the properties of planar, tubular and conical forms of silicon nanostructures. The evaluated parameters including averaged bond lengths, binding energies, gap energies and dipole moments were then evaluated for the optimized models of study. The results indicated that the bond lengths between silicon atoms are different […]
The Scanning Probe Microscopes (SPMs) based lithographic techniques have been demonstrated as an extremely capable patterning tool. Manipulating surfaces, creating atomic assembly, fabricating chemical patterns, imaging topography and characterizing various mechanical properties of materials in nanometer regime are enabled by this technique. In this paper, a qualified overview of diverse lithographical methods mostly based on […]
Nanocrystalline ZrO2 with particle size of about 38 nm was directly synthesized by sol-gel auto-combustion method. The overall process involved three steps: formation of homogeneous sol at 50-55°C; formation of dried gel at 110°C, and combustion of the dried gel at 400°C. Experiments revealed that ZrO2 dried gel derived from glycine (Fuel) and nitrate sol […]
This paper reports the correlation between film thickness, nanostructure and DC electrical properties of copper thin films deposited by PVD method on glass substrate. X-ray diffraction (XRD) and atomic force microscopy (AFM) were used for crystallography and morphology investigation, respectively. Resistivity was measured by four point probe instrument, while a Hall effects measurement system was […]
We report on the synthesis, morphology, chemically and structurally of TiO2-CuO-SiO2 nanostructure with different precursors molar ratio and calcined temperatures. In the present work, ternary reactive powders in the TiO2-CuO-SiO2 systems have been obtained using the sol-gel method, by the simultaneous gelation of all cations. The compounds and other elements change in special chemical and […]
In the past decades, many methods have been developed to synthesize zero- dimensional nanoparticles, quasi–one–dimensional (1D) CuO nanostructures, such as metal organic deposition technique, microwave irradiation, sol-gel-like dip technique, reverse micelle-assisted route, chemical method, and simple template free solution route. Among those synthesis methods, hydrothermal and chemical reaction methods are of particular interest because they […]
We report on the synthesis, morphology, chemically and structurally of TiO2-NiO-SiO2 nanostructure. The TiO2-NiO-SiO2 nanostructure was synthesized by a method based on the sol-gel method, by the simultaneous gelation of all cations. The coatings were deposited on dried soda-lime glass slides by spin coating. Composite powders and coating on glass have been characterized by XRD, […]
In this work, the synthesis of porous structure of cadmium oxide with multilayered sheet-like morphology in nano-meter size using adipic acid as soft template by solvothermal/thermal decomposition process is reported. Chemical analyses exhibited that the formation of porous sheet-like structure is originated from bidentate coordination mode of adipate units to Cd-center. It was found that […]
Calix[8]arenes of conformational rigid were isolated. The NMR parameters of the structure of calix[8]arenes have been compared. The study of organic structures to form nanoporous materials is well-known in chemistry phenomena to find the crystal form of calix[8]arene as supramolecule. Investigated and compared hydrogen bonding, oxygen and nitrogen atoms effect on calix[8]arene and its complexes […]
Mesoporous nanostructured γ-Al2O3 powders were synthesized through multi- step precipitation procedures using the pH-swing technique. Structural and morphological characteristics in addition to the thermal behavior of the procured samples were characterized via X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), fourier transform infrared (FT-IR) spectroscopy, thermogravimetry-derivative thermal gravimetric (TG-DTG) and N2 adsorption–desorption isotherm. Plackett-Burman […]
