10.57647/ijes.2027.04881

Geochemical Evidence from Olivine for Mantle Metasomatism and Magma Evolution in Eocene Basalts, North Ardabil, NW Iran

  1. Department of Earth Science, University of Tabriz, Tabriz, Iran
  2. Department of Earth Sciences, University of Geneva, Geneva, Switzerland

Received: 2025-06-16

Revised: 2025-09-19

Accepted: 2025-11-20

Published Online: 2026-03-26

How to Cite

Mohammadrezai, S., Jahangiri, A., Caricchi, L., & Moayyed, M. (2026). Geochemical Evidence from Olivine for Mantle Metasomatism and Magma Evolution in Eocene Basalts, North Ardabil, NW Iran. Iranian Journal of Earth Sciences. https://doi.org/10.57647/ijes.2027.04881

PDF views: 49

Abstract

The Eocene volcanic rocks of north Ardabil, NW Iran, provide valuable insight into the dynamic history of mantle processes and subduction-related magmatism along the Alborz-Azarbaijan magmatic belt. This study combines new petrographic observations, whole-rock geochemistry, and high-precision mineral chemistry, focusing on olivine phenocrysts from pyroxene-phyric basalt, basalt, and trachybasalt. These basalts exhibit porphyritic textures, characterized by a dominant presence of clinopyroxene, olivine, and plagioclase within a fine-grained groundmass. Four distinct olivine types were identified based on size, zoning patterns, and chemical composition, with forsterite (Fo) contents ranging from Fo59 to Fo92. Whole-rock geochemical analyses classify the host rocks as High-K subalkaline, characterized by LILEs and LREEs, along with depletion of HFSEs and HREEs, consistent with formation in a subduction-related arc setting. Elevated concentrations of Ni, Ca, and Mn in olivine phenocrysts and whole-rock compositions suggest a mantle source dominated by re-fertilized peridotite, with contributions from pyroxenite. Moreover, geochemical signatures indicate complex mantle metasomatism involving carbonate- and silicate-rich sediment melts, reflecting heterogeneous metasomatic processes beneath this volcanic field during the Eocene.

Keywords

  • Volcanic rocks,
  • Olivine,
  • Eocene,
  • Metasomatism,
  • North Ardebil,
  • NW Iran

References

  1. Abbasi S., Khalatbari-Jafari M., Sahbari P. (2005) Geological map of Razi (1: 100,000 scale). Geological Survey of Iran, Tehran.
  2. Abdolahadi A., Sheikhzakariaee S.J., Yazdi A., Mousavi S.Z. (2025) Plio-Quaternary Adakite Genesis and Post-collisional Processes: Whole Rock Constraints and Sr, Nd Isotopic Compositions in Alborz Magmatic Belt, Ardabil, Iran, Journal of Mining and Environment, 16(2):737-765. DOI: https://doi.org/10.22044/jme.2024.14781.2801
  3. Agard P., Omrani J., Jolivet L., Mouthereau F. (2005) Convergence history across Zagros (Iran): Constraints from collisional and earlier deformation. International Journal of Earth Sciences 94:401–419. DOI: https://doi.org/10.1007/s00531-005-0481-4
  4. Ahmadzadeh G., Mobashergermi M., Ravankhah A. (2023) Petrology, geochemistry and petrogenesis of Eocene volcanic rocks from Khan Ali Darasi, north of Lahrod city, northwest Iran. Researches in Earth Sciences 14(1):45–63. DOI: https://doi.org/10.48308/esrj.2023.101419
  5. Alavi M. (1994) Tectonics of the Zagros Orogenic Belt of Iran: New data and interpretations. Tectonophysics 229(3–4):211–238. DOI: https://doi.org/10.1016/0040-1951(94)90030-2
  6. Allen M., Jackson J., Walker R. (2004) Late Cenozoic reorganization of the Arabia–Eurasia collision and the comparison of short-term and long-term deformation rates. Tectonics 23(2):1–18. DOI: https://doi.org/10.1029/2003TC001530
  7. Ammannati E., Jacob D. E., Avanzinelli R., Foley S. F., Conticelli S. (2016) Low Ni olivine in silica-undersaturated ultrapotassic igneous rocks as evidence for carbonate metasomatism in the mantle. Earth and Planetary Science Letters 444:64–74. DOI: https://doi.org/10.1016/j.epsl.2016.03.039
  8. Arjmandzadeh R.,, Sharifi Teshnizi E., Ahmadi A.A., Mahdavi A., Tavsoli S., Dabiri R. (2021) The mineralogy, geochemistry and genesis of Aghol-Messi sedimentary copper-uranium deposit, Tabas block, Central Iran, Researches in Earth Sciences, 11(4): 47-70. DOI: https://doi.org/10.52547/esrj.11.4.47
  9. Arndt N. T., Guitreau M., Boullier A. M., Le Roex A., Tommasi A., Cordier P., Sobolev A. (2010) Olivine and the origin of kimberlite. Journal of Petrology 51:573–602. DOI: https://doi.org/10.1093/petrology/egp080
  10. Babakhani A. R., Nazer N. H., Amidi M. (1991) Geological map of Lahrood (1: 100,000 scale). Geological Survey of Iran, Tehran.
  11. Berberian M., King G. C. P. (1981) Towards a paleogeography and tectonic evolution of Iran. Canadian Journal of Earth Sciences 18(2):210–265. DOI: https://doi.org/10.1139/e81-019
  12. Bindeman I. N., Ponomareva V. V., Bailey J. C., Valley J. W. (2004) Volcanic arc of Kamchatka: A province with high-δ¹⁸O magma sources and large-scale ¹⁸O/¹⁶O depletion of the upper crust. Geochimica et Cosmochimica Acta 68(4):841–865. DOI: https://doi.org/10.1016/j.gca.2003.07.009
  13. Borghini G., Fumagalli P., Arrigoni F., Rampone E., Berndt J., Klemme S., Tiepolo M. (2023) Fast REE re-distribution in mantle clinopyroxene via reactive melt infiltration. Geochemical Perspectives Letters 26:40–44. DOI: https://doi.org/10.7185/geochemlet.2323
  14. Borojenie T. H., Sheykhzakariaei S.J., Dabiri R., Yazdi A. (2025) Petrogenesis and tectonic implications of Neoproterozoic to Cenozoic A-type granitoids in NW Iran: geochemical and tectonic constraints, Iranian Journal of Earth Sciences, 17(4): 1-19. DOI: https://doi.org/10.57647/j.ijes.2025.16894
  15. Cancel Vazquez S. M., Rooney T. O., Brown E. L., Bollinger A., Bastow I. D., Steiner R. A., Kappelman J. (2024) Basaltic pulses and lithospheric thinning—Plio-Pleistocene magmatism and rifting in the Turkana Depression (East African Rift System). Journal of Geophysical Research: Solid Earth 129(8): e2024JB029166. DOI: https://doi.org/10.1029/2024JB029166
  16. Castillo P. R., Hilton D. R., Halldórsson S. A. (2014) Trace element and Sr-Nd-Pb isotope geochemistry of Rungwe Volcanic Province, Tanzania: Implications for a Superplume source for East Africa Rift magmatism. Frontiers in Earth Science 2:21. DOI: https://doi.org/10.3389/feart.2014.00021
  17. Castro A., Aghazadeh M., Badrzadeh Z., Chichorro M. (2013) Late Eocene–Oligocene post-collisional monzonitic intrusions from the Alborz magmatic belt, NW Iran: An example of monzonite magma generation from a metasomatized mantle source. Lithos 180–181:109–127. DOI: https://doi.org/10.1016/j.lithos.2013.08.009
  18. Cordier C., Sauzeat L., Arndt N. T., Boullier A. M., Batanova V., Barou F. (2015) Metasomatism of the lithospheric mantle immediately precedes kimberlite eruption: New evidence from olivine composition and microstructures. Journal of Petrology 56:1775–1796. DOI: https://doi.org/10.1093/petrology/egv054
  19. Dabiri R., Akbari-Mogaddam M., Ghaffari M. (2018) Geochemical evolution and petrogenesis of the eocene Kashmar granitoid rocks, NE Iran: implications for fractional crystallization and crustal contamination processes, Iranian Journal of Earth Sciences 10 (1): 68-77.
  20. De Hoog J. C. M., Gall L., Cornell D. H. (2010) Trace-element geochemistry of mantle olivine and application to mantle petrogenesis and geothermobarometry. Chemical Geology 270:196–215. DOI: https://doi.org/10.1016/j.chemgeo.2009.11.017
  21. Elkins L. J., Bourdon B., Lambart S. (2019) Testing pyroxenite versus peridotite sources for marine basalts using U-series isotopes. Lithos 332–333:226–244. DOI: https://doi.org/10.1016/j.lithos.2019.02.011
  22. Elmi R., Arian M. A., Ashja Ardalan A., Yazdi A. (2025) Petrology of volcanism in the Alasht-Haraz road of the Alborz mountain range, south of Amol (north of Iran), Iranian Journal of Earth Sciences, 17(3): 1-16. DOI: https://doi.org/10.57647/j.ijes.2025.16800
  23. Espanon V. R., Chivas A. R., Kinsley L. P. J., Dosseto A. (2014) Geochemical variations in the Quaternary Andean back-arc volcanism, southern Mendoza, Argentina. Lithos 208–209:251–264. DOI: https://doi.org/10.1016/j.lithos.2014.09.010
  24. Fadaeian M., Jahangiri A., Ao S., Kamali A. A., Xiao W. (2022) Geochemistry and petrogenesis of shoshonitic dyke swarm in the northeast of Meshkinshahr, NW Iran. Minerals 12(3):309. DOI: https://doi.org/10.3390/min12030309
  25. Foley S. F., Jacob D. E., O’Neill H. S. C. (2011) Trace element variations in olivine phenocrysts from Ugandan potassic rocks as clues to the chemical characteristics of parental magmas. Contributions to Mineralogy and Petrology 162(1):1–20. DOI: https://doi.org/10.1007/s00410-010-0579-y
  26. Foley S. F., Prelević D., Rehfeldt T., Jacob D. E. (2013) Minor and trace elements in olivines as probes into early igneous and mantle melting processes. Earth and Planetary Science Letters 363:181–191. DOI: https://doi.org/10.1016/j.epsl.2012.11.025
  27. Furman T. (2007) Geochemistry of East African Rift basalts: An overview. Journal of African Earth Sciences 48(2–3):147–160. DOI: https://doi.org/10.1016/j.jafrearsci.2006.06.009
  28. Gall H., Furman T., Hanan B., Kürkcüoğlu B., Sayıt K., Yürür T., Pickard Sjoblom M., Şen E., Alıcı Şen P. (2021) Post-delamination magmatism in south-central Anatolia. Lithos 398–399:106299. DOI: https://doi.org/10.1016/j.lithos.2021.106299
  29. Ghasempour M.R., Ghazi J.M., Biabangard H., Dabiri R. (2014) Petrogenic significance of the Plio-Quaternary Nehbandan mafic lavas, Eastern Iran, Iranian Journal of Earth Sciences, 6(2): 133-141.
  30. Giuliani A., Foley S. F. (2016) The geochemical complexity of kimberlite rocks and their olivine populations: A comment on Cordier et al. (Journal of Petrology, 56, 1775–1796, 2015). Journal of Petrology 57:927–932. DOI: https://doi.org/10.1093/petrology/egw026
  31. Hassanzadeh J., Wernicke B. (2016) The Neotethyan Sanandaj-Sirjan zone of Iran as an archetype for passive margin-arc transitions. Tectonics 35(3):586–621. DOI: https://doi.org/10.1002/2015TC003926
  32. Herzberg C. (2011) Identification of source lithology in the Hawaiian and Canary Islands: Implications for origins. Journal of Petrology 52(1):113–146. DOI: https://doi.org/10.1093/petrology/egr015
  33. Herzberg C., Asimow P. D. (2008) Petrology of some oceanic island basalts: PRIMELT2.XLS software for primary magma calculation. Geochemistry, Geophysics, Geosystems 9(9):1–29. DOI: https://doi.org/10.1029/2008GC002057
  34. Herzberg C., Cabral R. A., Jackson M. G., Vidito C., Day J., Hauri E. H. (2014) Phantom Archean crust in Mangaia hot-spot lavas and the meaning of heterogeneous mantle. Earth and Planetary Science Letters 396:97–106. DOI: https://doi.org/10.1016/j.epsl.2014.03.065
  35. Herzberg C., Vidito C., Starkey N. A. (2016) Nickel–cobalt contents of olivine record origins of mantle peridotite and related rocks. American Mineralogist 101(9):1952–1966. DOI: https://doi.org/10.2138/am-2016-5538
  36. Hofmann A. W., White W. M. (1982) Mantle plumes from ancient oceanic crust. Earth and Planetary Science Letters 57(1–2):421–436. DOI: https://doi.org/10.1016/0012-821X(82)90161-3
  37. Honarmand M., van der Boon A., Neubauer F., Heberer B., Li Q., Kuiper K. F., Mason P. R. D., Krijgsman W. (2024) Geochemical constraints on the geodynamic setting of Alborz-Azerbaijan Cenozoic magmatism. Chemical Geology 645:1–23. DOI: https://doi.org/10.1016/j.chemgeo.2023.121889
  38. Humayun M., Qin L., Norman M. D. (2004) Geochemical evidence for excess iron in the mantle beneath Hawaii. Science 306(5693):91–94. DOI: https://doi.org/10.1126/science.1101050
  39. Irvine T. N., Baragar W. R. A. (1971) A guide to the chemical classification of the common volcanic rocks. Canadian Journal of Earth Sciences 8(5):523–548. DOI: https://doi.org/10.1139/e71-055
  40. Jackson S. E. (2008) LAMTRACE data reduction software for LA-ICP-MS. In: Sylvester P. (ed) Mineralogical Association of Canada Short Course Series 40:305–307. DOI: https://doi.org/10.3749/9780921294801.app01
  41. Jochum K. P., Weis U., Stoll B., Kuzmin D., Yang Q., Raczek I., Jacob D. E., Stracke A., Birbaum K., Frick D. A., Günther D., Enzweiler J. (2011) Determination of reference values for NIST SRM 610–617 glasses following ISO guidelines. Geostandards and Geoanalytical Research 35:397–429. DOI: https://doi.org/10.1111/j.1751-908X.2011.00120.x
  42. Kamenetsky V. S., Kamenetsky M. B., Sobolev A. V., Alexander V. G., Sylvie D., Kevin F., Victor V. S., Dmitry V. K. (2008) Olivine in the Udachnaya-East kimberlite (Yakutia, Russia): Types, compositions and origins. Journal of Petrology 49:823–839. DOI: https://doi.org/10.1093/petrology/egm033
  43. Kelemen P. B., Hart S. R., Bernstein S. (1998) Silica enrichment in the continental upper mantle via melt/rock reaction. Earth and Planetary Science Letters 164(3–4):387–406. DOI: https://doi.org/10.1016/S0012-821X(98)00233-7
  44. Khodabandeh A., Amini Fazl A., Emami M. H. (1997) Geological map of Ardebil (1: 100,000 scale). Geological Survey of Iran, Tehran.
  45. Liu H., Xiao Y., Sun H., Tong F., Heuser A., Churikova T., Wörner G. (2020) Trace elements and Li isotope compositions across the Kamchatka arc: Constraints on slab-derived fluid sources. Journal of Geophysical Research: Solid Earth 125(5): e2019JB019237. DOI: https://doi.org/10.1029/2019JB019237
  46. Matzen A. K., Baker M. B., Beckett J. R., Stolper E. M. (2013) The temperature and pressure dependence of nickel partitioning between olivine and silicate melt. Journal of Petrology 54(12):2521–2545. DOI: https://doi.org/10.1093/petrology/egt055
  47. Mazandarani R., Sheikh Zakariaee S.J., Mortazavi, S.M., Yazdi A. (In press) Geodynamics and tectonic setting of volcanic rocks from Tineh to Reineh (Haraz road) in Iran, Geopersia, Doi: https://doi.org/10.22059/geope.2025.395984.648823
  48. McDonough W. F., Sun S. S. (1995) The composition of the Earth. Chemical Geology 120(3–4):223–253. DOI: https://doi.org/10.1016/0009-2541(94)00140-4
  49. Mitchell R. H. (1986) Kimberlites: Mineralogy, geochemistry, and petrology (442 pp.). Plenum Press.
  50. Mitchell R. H. (1995) Kimberlites, orangeites and related rocks (410 pp.). Plenum Press. DOI: https://doi.org/10.1007/978-1-4615-1993-5
  51. Mitchell R. H. (2008) Petrology of hypabyssal kimberlites: Relevance to primary magma compositions. Journal of Volcanology and Geothermal Research 174(1–3):1–8. DOI: https://doi.org/10.1016/j.jvolgeores.2007.12.024
  52. Mitchell R. H., Tappe S. (2010) Discussion of “Kimberlites and aillikites as probes of the continental lithospheric mantle,” by Francis and Patterson (Lithos v. 109, p. 72–80). Lithos 115(1):288–292. DOI: https://doi.org/10.1016/j.lithos.2009.10.017
  53. Mollai H., Dabiri R., Torshizian H. A., Pe-Piper G., Wang W. E. (2021) Upper Neoproterozoic garnet-bearing granites in the Zeber-Kuh region from east central Iran micro plate: Implications for the magmatic evolution in the northern margin of Gondwanaland, Geologica Carpathica 72 (6): 461-81. DOI: https://doi.org/10.31577/GeolCarp.72.6.2
  54. Nosova A., Dubinina E., Sazonova L. G., Kargin A., Lebedeva N., Khvostikov V., Burmii Z. P., Kondrashov I., Tret’yachenko V. V. (2017) Geochemistry and oxygen isotopic composition of olivine in kimberlites from the Arkhangelsk Province: Contribution of mantle metasomatism. Petrology 25(2):150–180. DOI: https://doi.org/10.1134/S0869591117010064
  55. Pearce J. A., Peate D. W. (1995) Tectonic implications of the composition of volcanic arc magmas. Annual Review of Earth and Planetary Sciences 23:251–285. DOI: https://doi.org/10.1146/annurev.ea.23.050195.001343
  56. Peccerillo A., Taylor S. R. (1976) Geochemistry of Eocene calc-alkaline volcanic rocks from the Kastamonu area, northern Turkey. Contributions to Mineralogy and Petrology 58:63–81. DOI: https://doi.org/10.1007/BF00384745
  57. Pilbeam L. H., Nielsen T. F. D., Waight T. E. (2013) Digestion fractional crystallization (DFC): An important process in the genesis of kimberlites. Evidence from olivine in the Majuagaa kimberlite, southern West Greenland. Journal of Petrology 54:1399–1425. DOI: https://doi.org/10.1093/petrology/egt016
  58. Plank T., Langmuir C. H. (1998) The chemical composition of subducting sediment and its consequences for the crust and mantle. Chemical Geology 145(3–4):325–394. DOI: https://doi.org/10.1016/S0009-2541(97)00150-2
  59. Prelević D., Foley S. F. (2007) Accretion of arc-oceanic lithospheric mantle in the Mediterranean: Evidence from extremely High-Mg olivines and Cr-rich spinel inclusions from lamproites. Earth and Planetary Science Letters 256(1–2):120–135. DOI: https://doi.org/10.1016/j.epsl.2007.01.018
  60. Prelević D., Jacob D. E., Foley S. F. (2013) Recycling plus: A new recipe for the formation of Alpine-Himalayan orogenic mantle lithosphere. Earth and Planetary Science Letters 362:187–197. DOI: https://doi.org/10.1016/j.epsl.2012.11.035
  61. Putirka K. D. (2008) Thermometers and barometers for volcanic systems. Reviews in Mineralogy and Geochemistry 69(1):61–120. DOI: https://doi.org/10.2138/rmg.2008.69.3
  62. Roeder P. L., Emslie R. F. (1970) Olivine-liquid equilibrium. Contributions to Mineralogy and Petrology 29:275–289. DOI: https://doi.org/10.1007/BF00371276
  63. Roeder P. L., Schulze D. J. (2008) Crystallization of groundmass spinel in kimberlite. Journal of Petrology 49(8):1473–1495. DOI: https://doi.org/10.1093/petrology/egn034
  64. Rollinson H. R. (1993) Using geochemical data: Evaluation, presentation, interpretation. Routledge, London, 384 pp. DOI: https://doi.org/10.4324/9781315845548
  65. Rooney T. O., Girard G., Tappe S. (2020) The impact on mantle olivine resulting from carbonated silicate melt interaction. Contributions to Mineralogy and Petrology 175(6):56–71. DOI: https://doi.org/10.1007/s00410-020-01694-0
  66. Salehpour S., Arian M.A., Rad A.J., Zarei Sahamieh R., Yazdi A. (2025) Geochemistry and technomagmatic environment of Eocene volcanic rocks in Yuzbashi Chay region, west of Qazvin (Iran), Iranian Journal of Earth Sciences, 17(1): 1-13. https://doi.org/10.57647/j.ijes.2025.1701.04
  67. Shafaii Moghadam H., Li Q. L., Li X. H., Stern R. J., Levresse G., Santos J. F., Lopez Martinez M., Ducea M. N., Ghorbani G., Hassannezhad A. (2020) Neotethyan subduction ignited the Iran arc and backarc differently. Journal of Geophysical Research: Solid Earth 125(4): e2019JB018460. DOI: https://doi.org/10.1029/2019JB018460
  68. Shaw C. S. J. (2024) Clinopyroxenite xenoliths record magma transport and crystallization in the middle and upper crust: A case study from the Rockeskyllerkopf Volcanic Complex, West Eifel, Germany. Journal of Petrology 65(4): egae035. DOI: https://doi.org/10.1093/petrology/egae035
  69. Shu Y., Nielsen S. G., Le Roux V., Wörner G., Blusztajn J., Auro M. (2022) Sources of dehydration fluids underneath the Kamchatka arc. Nature Communications 13:4467. DOI: https://doi.org/10.1038/s41467-022-32211-5
  70. Søager N., Portnyagin M., Hoernle K., Holm P. M., Hauff F., Garbeschönberg D. (2015) Olivine major and trace element compositions in southern Payenia basalts, Argentina: Evidence for pyroxenite-peridotite melt mixing in a back-arc setting. Journal of Petrology 56:1495–1518. DOI: https://doi.org/10.1093/petrology/egv043
  71. Sobolev A. V., Chaussidon M. (1996) Melt inclusions in minerals as a source of principal petrological information: New data from olivine phenocrysts of basalts and kimberlites. Petrology 4(3):209–220.
  72. Sobolev A. V., Hofmann A. W., Kuzmin D. V., Yaxley G. M., Arndt N. T., Chung S. L., Gurenko A. A. (2007) The amount of recycled crust in sources of mantle-derived melts. Science 316(5823):412–417. DOI: https://doi.org/10.1126/science.1138113
  73. Sobolev A. V., Hofmann A. W., Sobolev S. V., Nikogosian I. K. (2005) An olivine-free mantle source of Hawaiian shield basalts. Nature 434(7033):590–597. DOI: https://doi.org/10.1038/nature03411
  74. Sobolev N. V., Sobolev A. V., Tomilenko A. A., Kovyazin S. V., Batanova V. G., Kuz'min D. V. (2015) Paragenesis and complex zoning of olivine macrocrysts from unaltered kimberlite of the Udachnaya-East pipe, Yakutia: Relationship with the kimberlite formation conditions and evolution. Russian Geology and Geophysics 56(1–2):260–279. DOI: https://doi.org/10.1016/j.rgg.2015.01.019
  75. Soltanmohammadi A., Grégoire M., Rabinowicz M., Gerbault M., Ceuleneer G., Rahgoshay M., Bystricky M., Benoit M. (2018) Transport of volatile-rich melt from the mantle transition zone via compaction pockets: Implications for mantle metasomatism and the origin of alkaline lavas in the Turkish–Iranian Plateau. Journal of Petrology 59(12):2273–2310. DOI: https://doi.org/10.1093/petrology/egy097
  76. Straub S. M., LaGatta A. B., Martin-Del Pozzo A. L., Langmuir C. H. (2008) Evidence from High-Ni olivines for a hybridized peridotite/pyroxenite source for orogenic andesites from the central Mexican Volcanic Belt. Geochemistry, Geophysics, Geosystems 9(3): Q03007. DOI: https://doi.org/10.1029/2007GC001583
  77. Toplis M. J., Carroll M. R. (1995) An experimental study of the influence of oxygen fugacity on Fe-Ti oxide stability, phase relations, and mineral-melt equilibria in ferro-basaltic systems. Journal of Petrology 36(5):1137–1170. DOI: https://doi.org/10.1093/petrology/36.5.1137
  78. Ulianov A., Müntener O., Schaltegger U., Bussy F. (2012) The data treatment dependent variability of U–Pb zircon ages obtained using mono-collector, sector field, laser ablation ICP-MS. Journal of Analytical Atomic Spectrometry 27(4):663–676. DOI: https://doi.org/10.1039/C2JA10358C
  79. Ulmer P. (1989) The dependence of the Fe²⁺–Mg cation-partitioning between olivine and basaltic liquid on pressure, temperature and composition: An experimental study to 30 kbars. Contributions to Mineralogy and Petrology 101(3):261–273. DOI: https://doi.org/10.1007/BF00375311
  80. Vasigh Y. (2016) Petrogenesis of volcanic rocks from Razei region in Northwest Ardabil, Iran. Iranian Journal of Earth Sciences 8(1):69–77.
  81. Whitney D. L., Evans B. W. (2010) Abbreviations for names of rock-forming minerals. American Mineralogist 95:185–187. DOI: https://doi.org/10.2138/am.2010.3371
  82. Wölki D., Haase K., Schoenhofen M., Beier C., Regelous M., Krumm S. H., Günther T. (2018) Evidence for melting of subducting carbonate-rich sediments in the western Aegean Arc. Chemical Geology 483:463–473. DOI: https://doi.org/10.1016/j.chemgeo.2018.03.014
  83. Xie S., Keays R. R., Xiao L., Huo Q., Ihlenfeld C. (2009) Platinum-group element geochemistry of the continental flood basalts in the central Emeishan Large Igneous Province, SW China. Chemical Geology 260(3–4):246–261. DOI: https://doi.org/10.1016/j.chemgeo.2009.01.021
  84. Yang Z. F., Zhou J. H., Qian Q. (2016) On the chemical markers of pyroxenite contributions in continental basalts in Eastern China: Implications for source lithology and the origin of basalts. Journal of Petrology 157(1–3):18–31. DOI: https://doi.org/10.1016/j.earscirev.2016.04.001
  85. Yazdi A., Ashja-Ardalan A., Emami M.H., Dabiri R., Foudazi M. (2019) Magmatic interactions as recorded in plagioclase phenocrysts of quaternary volcanics in SE Bam (SE Iran), Iranian Journal of Earth Sciences 11(3): 215-224. https://doi.org/10.30495/ijes.2019.667379
  86. Zhang Z., Mahoney J. J., Mao J., Wang F. (2006) Geochemistry of picritic and associated basalt flows of the western Emeishan flood basalt province, China. Journal of Petrology 47(10):1997–2019. DOI: https://doi.org/10.1093/petrology/egl034