10.57647/j.ijes.2025.16794

Geochemistry of core sediments in the southern coast of Caspian Sea, Mazandaran, Iran: Implication for paleoclimate

  1. Department of Geology, Faculty of Sciences, Science and Research Branch, Islamic Azad University, Tehran, Iran.
  2. Department of Reclamation of Arid and Mountainous Regions, Faculty of Natural Resources, University of Tehran, Karaj, Iran
  3. Department of Geology, Faculty of Science, North Tehran Branch, Islamic Azad University, Tehran, Iran
Geochemistry of core sediments in the southern coast of Caspian Sea, Mazandaran, Iran: Implication for paleoclimate

Received: 2024-02-09

Revised: 2024-04-10

Accepted: 2024-06-08

Published in Issue 2025-07-10

How to Cite

Dehghan Chenari, A., Feiznia, S., Aleali, M., & Ghorashi, M. (2025). Geochemistry of core sediments in the southern coast of Caspian Sea, Mazandaran, Iran: Implication for paleoclimate. Iranian Journal of Earth Sciences, 17(3). https://doi.org/10.57647/j.ijes.2025.16794

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Abstract

The present study conducted a geochemical analysis on the core sediments from the Jouybar and Zaghmarz areas located on the South Coast of the Caspian Sea in northern Iran. The aim of the study was to investigate the paleoclimate conditions and recycling effects of these sediments. The cores, named AZS (Azad University Shorsahra area) and AM (Amirabad), have depths of 9.3 m and 8.2 m respectively. They consist of three lithological units, including sandy mud, muddy, and silty sand. A total of 50 samples were collected from these units for X-ray diffraction (XRD), geochemistry (ICP-AES), and radiocarbon analyses. The X-ray diffraction analysis revealed that the samples were predominantly composed of clay and non-clay minerals. Various chemical indexes based on major and trace elements were used to assess the intensity of weathering. The results showed that sandy mud and muddy sediments experienced slightly higher weathering compared to silty sand sediments, indicating a weak to moderate degree of chemical weathering in the source region. Additionally, the A-CN-K and SiO2 vs. (Al2O3+K2O+Na2O) plots supported the conclusion of weak to moderate chemical weathering in arid and semi-arid paleoclimate conditions. Furthermore, the index of compositional variability (ICV) and the relationships between Zr/Sc and Th/Sc ratios suggested that sedimentary recycling in the core sediments was negligible. Binary plots of V/Cr vs U/Th and Ni/Co vs U/Th indicated that dysoxic/oxic conditions predominantly prevailed during the deposition of the two cores' sediments.

Keywords

  • Caspian Sea,
  • Paleoclimate,
  • Source-area weathering,
  • Core sediments

References

  1. Aghanabati A (2004) Geology of Iran. Geological Survey and mineral exploration of Iran. (in Persian)
  2. Al Khirbash S, Al Semhi K, Richard L, Nasir S, Al Harthy AR (2013) Rare earth element mobility during laterization of the mafic rocks of the Oman Mountains. Arabian Journal of Geosciences 7: 5443-5454.
  3. Armstrong Altrin JS, Lee YI, Verma SP, & Ramasamy S (2004) Geochemistry of sandstones from the upper Miocene Kudankulam Formation Southern India: implications for provenance, weathering and tectonic setting. Journal of sedimentary Research 74(2): 285-297.
  4. Bai Y, Liu Z, Sun P, Liu R, Hu X, Zhao H, Xu Y (2015) Rare earth and major element geochemistry of Eocene fine-grained sediments in oil shale- and coal-bearing layers of the Meihe Basin, northeast China. Journal of Asian Earth Sciences 97: 89-101.
  5. Bauluz B, Mayayo MJ, Fernandez-Nieto C, Gonzalez Lopez JM (2000) Geochemistry of Precambrian and Paleozoic siliciclastic rocks from the Iberian Range (NE Spain): implications for source-area weathering, sorting, provenance, and tectonic setting. Chemical Geology 168(1-2): 135-150.
  6. Bhatia MR, Crook KA (1986) Trace element characteristics of greywackes and tectonic setting discrimination of sedimentary basins. Contributions to Mineralogy and Petrology 92(2): 181-193.
  7. Calvert SE, Pedersen TF (1993) Geochemistry of recent oxic and anoxic sediments: implications for the geological record. Marine geology 113(1-2): 67-88.
  8. Campo MD, Papa CD, Jiménez-Millán J, Nieto F (2007) Clay mineral assemblages and analcime formation in a Palaeogene fluvial-lacustrine sequence (Maíz Gordo Formation Palaeogen) from northwestern Argentina. Sedimentary Geology 201(1-2): 56-74.
  9. Cao HS, Guo W, Shan XL, Ma L, Sun PC (2015) Paleolimnological environments and organic accumulation of the Nenjiang Formation in the Southeastern Songliao Basin, China. Oil Shale 32 (1): 5-24.
  10. Cardenas A, Girty G H, Hanson AD, Lahren MM (1996) Assessing differences in composition between low metamorphic grade mudstone and high-grade schists using log ratio techniques. The Journal of Geology 104(3): 279-293.
  11. Chamley H (1989) Clay Minerals. In: Clay Sedimentology. Springer,3-20
  12. Chen J, An Z, Liu L, Ji J, Yang J, Chen, Y. (2001) Variations in chemical compositions of the eolian dust in Chinese Loess Plateau over the past 2.5 Ma and chemical weathering in the Asian inland. Science in China Series D: Earth Science 44: 403-413.
  13. Christopher RG, Elderfield H (1990) Application of the Ce anomaly as a paleoredox indicator: the ground rules. Paleoceanography 5(5): 823-833.
  14. Cingolani CA, Manassero M, Abre P (2003) Composition, provenance, and tectonic setting of Ordovician siliciclastic rocks in the San Rafael block: Southern extension of the Precordillera crustal fragment, Argentina. Journal of South American Earth Sciences 16(1): 91-106.
  15. Cox R, Lowe DR, Cullers RL (1995) The influence of sediment recycling and basement composition on evolution of mud rock chemistry in the southwestern United States. Geochimica et Cosmochimica Acta 59(14): 2919-2940.
  16. Cullers RL (1988) Mineralogical and chemical changes of soil and stream sediment formed by intense weathering of the Danburg granite, Georgia, U.S.A. Lithos 21(4): 301-314.
  17. Cullers RL (2000) The geochemistry of shales, siltstones and sandstones of Pennsylvanian-Permian age, Colorado, USA: Implications for provenance and metamorphic studies. Lithos 51(3): 181-203.
  18. Cullers RL, Podkovyrov VN (2000) Geochemistry of the Mesoproterozoic Lakhanda shales in southeastern Yakutia, Russia: Implications for mineralogical and provenance control, and recycling. Precambrian Research 104(1-2): 77-93.
  19. Das BK, Al-Mikhlafi AS, Kaur P (2006) Geochemistry of Mansar Lake sediments, Jammu, India: Implication for Source-area weathering, provenance, and tectonic setting. Journal of Asian Earth Sciences 26(6): 649-668.
  20. Deepthi K, Natesan U, Muthulakshmi AL, Ferrer VA, Venugopalan V P, Narasimhan SV (2013) Geochemical characteristics and depositional environment of Kalpakkam, southeast coast of India. Environmental earth sciences 69: 2357-2364.
  21. Dill H (1986) Metallogenesis of Early Paleozoic Graptolite Shales from the Graefenthal Horst (Northern Bavaria-Federal Republic of Germany). Economic Geology 81(4): 889-903.
  22. Dixon JB, Weed SB (1992) Minerals in soil environments. 2nd ed. Soil Science Society of America Journal
  23. Dypvik H (1984) Geochemical compositions and depositional conditions of Upper Jurassic and Lower Cretaceous Yorkshire clays. England. Geological Magazine 121:489-504.
  24. Fedo CM, Eriksson KA, Krogstad EJ (1996) Geochemistry of shales from the Archean (3.0 Ga) Buhwa Greenstone Belt, Zimbabwe: implications for provenance and source area weathering. Geochimica et Cosmochimica Acta 60(10): 1751-1763.
  25. Fedo CM, Nesbitt HW, Young GM (1995) Unravelling the effects of potassium metasomatism in sedimentary rocks and paleosols, with implications for paleoweathering conditions and provenance. Geology 23(10): 921-924.
  26. Fedo CM, Young GM, Nesbitt GM (1997a) Paleoclimatic control on the composition of the Paleoproterozoic serpent formation, Huronian supergroup, Canada: a green-house to icehouse transition. Precambrian Research 86(3-4): 201-223.
  27. Fedo CM, Young GM, Nesbitt HW, Hanchar JM (1997b) Potassic and sodic metasomatism in the southern Province of the Canadian Shield: evidence from the Paleoproterozoic serpent formation, Huronian supergroup, Canada. Precambrian Research 84(1-2): 17-36.
  28. Folk RL (1974) Petrography of Sedimentary Rocks, Hemphill Publishing Company 182 pp.
  29. Fu XG, Wang J, Chen WB, Feng XL, Wang D, Song CY, Zeng SQ (2015) Organic accumulation in lacustrine rift basin: constraints from mineralogical and multiple geochemical proxies. International Journal of Earth Sciences 104: 495-511.
  30. Fu XG, Wang J, Chen WB, Feng XL, Wang D, Song CY, Zeng SQ (2016) Elemental geochemistry of the early Jurassic black shales in the Qiangtang Basin, eastern Tethys: constraints for paleoenvironment conditions. Geological Journal 51(3): 443-454.
  31. Fu XG, Wang J, Zeng YH, Tan FW, He JL (2011) Geochemistry and origin of rare earth elements (REEs) in the Shengli River oil shale, northern Tibet, China. Geochemistry 71(1): 21-30.
  32. Gallala W, Gaied ME, Montacer M (2009) Detrital mode, mineralogy and geochemistry of the Sidi Aïch Formation (Early Cretaceous) in central and southwestern Tunisia: Implications for provenance, tectonic setting and paleoenvironment. Journal of African Earth Sciences 53(3-4): 159-170.
  33. Gang L, Dongsheng Z (2007). Application of microelements analysis in identifying sedimentary environment——taking Qianjiang Formation in the Jianghan Basin as an example. Petroleum Geology & Experimental 29(3): 307-310.( in chainese)
  34. Gao S, Dong G, Li B (1985) The variable of chemical elements contents in paleo-Aeolian sand strata and climatic environment at Yulin area, Shaanxi province. Journal of desert research 5: 25−30.
  35. Ghosh S, Sarkar S, Ghosh P (2012) Petrography and major element geochemistry of the Permo Triassic sandstones, central India: implications for provenance in an intracratonic pull-apart basin. Journal of Asian Earth Sciences 43(1): 207-240.
  36. Gosse JC, Fred MP (2001) Terrestrial in situ cosmogenic nuclides: theory and application. Quaternary Science Reviews 20(14): 1475-1560.
  37. Gromet LP, Dymek RF, Haskin LA, Korotev RV (1984) The North American shale composite: its composition, major and trace element characteristics. Geochimica et Cosmochimica Acta 48(12): 2469-2482
  38. Harnois L (1988) The new index, a new chemical index of weathering. Sedimentary geology 55(3): 319-322.
  39. Hassan S, Ishiga H, Roser BP, Dozen K, Naka T (1999) Geochemistry of Permian Triassic shales in the Salt range, Pakistan: implications for provenance and tectonism at the Gondwana margin. Chemical Geology 158 (3-4): 293-314.
  40. Herron MM (1988) Geochemical classification of terrigenous sands and shales from core of log data. Journal of Sedimentary Research 58(5): 820-829.
  41. Hessler AM, Lowe DR (2006) Weathering and sediment generation in the Archean: an integrated study of the evolution of siliciclastic sedimentary rocks of the 3.2 Ga Moodies Group, Barberton Greenstone Belt, South Africa. Precambrian Research 151(3-4): 185-210.
  42. Jehangir Khan M., Ghazi S., Mehmood M., Yazdi A., Naseem A.A., Serwar U., Zaheer A., Ullah H. (2021) Sedimentological and provenance analysis of the Cretaceous Moro formation Rakhi Gorge, Eastern Sulaiman Range, Pakistan. Iranian Journal of Earth Sciences 13(4): 252-266. DOI: https://doi.org/10.30495/ijes.2021.1917721.1564
  43. Jin Z, Li F, Cao J, Wang S, Yu J (2006) Geochemistry of Daihai lake sediments, Inner Mongolia, north China: Implications for provenance, sedimentary sorting, and catchment weathering. Geomorphology 80(3-4): 147-163.
  44. Jin ZD, Zhang EL (2002) Paleoclimate implication of Rb/Sr ratios from lake sediments. Science and Technology Engineering 2(3): 20-22.
  45. Jones B, Manning DA (1994) Comparison of geochemical indices used for the interpretation of paleo-redox conditions in ancient mudstones. Chemical geology 111(1-4): 111-129.
  46. Lahijani H, Tavakoli V (2012) Identifying provenance of South Caspian coastal sediments using mineral distribution pattern. Quaternary International 261: 128-137.
  47. Lee YI (2009) Geochemistry of shales of the Upper Cretaceous Hayang Group, SE Korea: Implications for provenance and source weathering at an active continental margin Sediment. Sedimentary Geology 215(1-4): 1-12.
  48. Lerman A, Imboden DM, Gat JR (1995) Physics and chemistry of lakes. Springer-Verlag, Berlin.
  49. Lézin C, Andreu B, Pellenard P, Bouchez JL, Emmanuel L, Fauré P, Landrein P (2013) Geochemical disturbance and paleoenvironmental changes during the Early Toarcian in NW Europe. Chemical Geology 341: 1-15.
  50. Li Y, Wang N, Cheng HY, Long H, Zhao Q (2009) Holocene environmental change in the marginal area of the Asian monsoon: a record from Zhuye Lake, NW China. Boreas 38(2): 349-361.
  51. Long H, Shen J (2015) Underestimated 14 C-based chronology of late Pleistocene high lake-level events over the Tibetan Plateau and adjacent areas: Evidence from the Qaidam Basin and Tengger Desert. Science China Earth Sciences 58: 183-194.
  52. Ma PF, Wang LC, Wang CS, Wu X H, Wei YS (2015) Organic-matter accumulation of the lacustrine lunpola oil shale, central Tibetan plateau: controlled by the paleoclimate, provenance, and drainage system. International Journal of Coal Geology 147: 58-70.
  53. Madhava Raju J, Ramírez-Montoya E, Monreal R, González-León CM, Pi-Puig T, Espinoza-Maldonado IG, Grijalva-Noriega FJ (2016) Paleoclimate, paleoweathering and paleoredox conditions of Lower Cretaceous shales from the Mural Limestone, Tuape section, northern Sonora, Mexico: constraints from clay mineralogy and geochemistry. Revista Mexicana de Ciencias Geológicas 33: 34-48.
  54. Mazumder R (2017) Sediment provenance, Influences on compositional change from source to sink. Sediment Provenance
  55. McLennan SM, Hemming S, McDaniel DK, Hanson, GN (1993) Geochemical approaches to sedimentation, provenance, and tectonics. Special Papers-Geological Society of America 21-21.
  56. McLennan SM, Taylor SR, Kröner A (1983) Geochemical evolution of Archean shales from South Africa, The Swaziland and Pongola Supergroups. Precambrian Research 22(1-2): 93-124.
  57. Meng QT, Liu ZJ, Bruch AA (2012) Paleoclimatic evolution during the Eocene and its influence on oil shale mineralization, Fushun Basin, China. Journal of Asian Earth Sciences 45: 95-105.
  58. Moradi AV, Sari A, Akkaya P (2016) Geochemistry of the Miocene oil shale (Hançili Formation) in the Çankırı-Çorum Basin, Central Turkey: implications for Paleoclimate conditions, source-area weathering, provenance and tectonic setting. Sedimentary Geology 341: 289-303.
  59. Morford JL, Martin WR, Carney CM (2009) Uranium diagenesis in sediments underlying bottom waters with high oxygen content. Geochimica et Cosmochimica Acta 73(10): 2920-2937.
  60. Nath BN, Bau M, Rao BR, Rao CM (1997) Trace and rare earth elemental variation in Arabian Sea sediments through a transect across the oxygen smallest zone. Geochimica et Cosmochimica Acta 61 (12): 2375-2388.
  61. Nesbitt HW, Markovics G, Price R C (1980) Chemical processes affecting alkalis and alkaline earth during continental weathering. Geochimica et cosmochimica acta 44(11): 1659-1666.
  62. Nesbitt HW, Young GM (1982) Early Proterozoic climates and plate motions inferred from major element chemistry of lutites. Nature 299(5885): 15-717.
  63. Nesbitt HW, Young GM (1984) Prediction of some weathering trends of plutonic and volcanic rocks based on thermodynamic and kinetic considerations. Geochimica et cosmochimica acta 48(7): 1523-1534.
  64. Otari, M and Dabiri, R. (2015) Geochemical and environmental assessment of heavy metals in soils and sediments of Forumad Chromite mine, NE of Iran. Journal of Mining and Environment 6(2): 251-261.
  65. Pettijohn FJ, Potter PE, Siever R (2012). Sand and sandstone. Springer Science & Business Media.
  66. Rahman MJJ, Suzuki S (2007) Composition of Neogene shales from the Surma Group, Bengal Basin, Bangladesh: Implications for provenance and tectonic setting. Austrian Journal of Earth Sciences 100: 54-64.
  67. Riquier L, Tribovillard N, Averbuch O, Devleeschouwer X, Riboulau A (2006) The Late Frasnian Kellwasser horizons of the Harz Mountains (Germany): two oxygen-deficient periods resulting from different mechanism. Chemical Geology 233(1-2): 137-155.
  68. Roy D, Roser BP (2012) Geochemistry of the Tertiary sequence in the Shahbajpur-1 well, Hatia Trough, Bengal Basin, Bangladesh: Provenance, source weathering and province affinity. Journal of Life and Earth Science 7: 1-13.
  69. Sahoo PK, Guimaraes JTF, Souza-Filho PWM, Da Silvam MS, Maturity CW, Powell MA (2016) Geochemistry of upland lacustrine sediments from Serra dos Carajas, Southeastern Amazon, Brazil: Implications for catchment weathering, provenance, and sedimentary processes. Journal of South American Earth Sciences 72: 178-190.
  70. Selvaraj K, Chen CTA (2006) Moderate chemical weathering of subtropical Taiwan: constraints from solid-phase geochemistry of sediments and sedimentary rocks. The Journal of Geology 114(1): 101-116.
  71. Shaltami OR (2012) Mineral composition and environmental geochemistry of the beach sediments along the Mediterranean coast from Benghazi to Bin Jawwad, Northeast Libya, 139.
  72. Song Y, Liu Z, Meng Q, Wang Y (2016) Petrography and geochemistry characteristics of the lower Cretaceous Muling Formation from the Laoheishan Basin, Northeast China: implications for provenance and tectonic setting. Mineralogy and Petrology 111 (3): 383-397.
  73. Sun LH, Gui HR, Chen S (2012) Geochemistry of sandstones from the Neoproterozoic Shijia Formation, northern Anhui Province, China: implications for provenance, weathering and tectonic setting. Geochemistry 72(3): 253-260.
  74. Suttner LJ, Dutta PK (1986) Alluvial sandstone composition and paleoclimate; I, Framework mineralogy. Journal of Sedimentary Research 56(3): 329-345.
  75. Tao HF, Sun S, Wang ZQ, Yang XF, Jiang L (2014) Petrography and geochemistry of Lower Carboniferous greywacke and mudstones in Northeast Junggar, China: implications for provenance, source weathering, and tectonic setting. Journal of Asian Earth Sciences 87: 11-25.
  76. Taylor SR, McLennan SM (1985) The Continental Crust: Its Composition and Evolution. Blackwell Scientific Publications.
  77. Tribovillard N, Algeo TJ, Lyons T, Riboulleau A (2006) Trace metals as paleoredox and paleoproductivity proxies: an update. Chemical geology 232(1-2): 12-32.
  78. Vahdati Daneshmand F, Saidi A (1991) Explanatory text of the Sari quadrangle map, Iran, Scale 1:250000. Geological Survey and mineral exploration of Iran (in Persion).
  79. Verma SP, Armstrong-Altrin JS (2013) New multi-dimensional diagrams for tectonic discrimination of siliciclastic sediments and their application to Precambrian basins. Chemical Geology 355: 117-133.
  80. Von Eynatten H, Barceló-Vidal C, Pawlowsky-Glahn V (2003) Modelling compositional change: the example of chemical weathering of granitoid rocks, Mathematical Geology 35: 231-251.
  81. Wang ZW, Wang J, Fu XG, Zhan WZ, Yu F, Feng XL, Song CY, Chen WB, Zeng SQ (2017) Organic material accumulation of Carnian mudstones in the North Qiantang Depression, eastern Tethys: controlled by the paleoclimate, paleoenvironment, and provenance. Marine and Petroleum Geology 88: 440-457.
  82. Wei ZQ, Zhong W, Chen YQ, Tan LL (2015) Supergene geochemical elements of swampy basin in the sub-tropical monsoon region: a case study of Dingnan Dahu in Jiangxi Province. Progress in Geography 34(7): 909-917.
  83. Wilmsen M, Fürsich FT, Seyed-Emami K, Majidifard MR, Taheri J (2009b) The Cimmerian Orogeny in northern Iran: tectono-stratigraphic evidence from the foreland. Terra Nova 21(3): 211-218.
  84. Yan DT, Chen DZ, Wang QC, Wang JG (2010) Large-scale climate fluctuations in the latest Ordovician on the Yangtze block, South China. Geology 38(7), 599-602.
  85. Yang S, Jung HS (2004) Two unique weathering regimes in the Changjiang and Huanghe drainage basins: geochemical evidence from river sediments. Sedimentary Geology 164(1-2): 19-34.
  86. Yunfei W (1993) Lacustrine carbonate chemical sedimentation and climatic-environmental evolution—a case study of Qinghai lake and Daihai lake. Oceanologia et Limnologia Sinica 24(1): 31-36.
  87. Zeng SQ, Wang J, Fu XG, Chen WB, Feng XL, Wang D, Song CY, Wang ZW (2015) Geochemical characteristics, redox conditions, and organic matter accumulation of marine oil shale from the Chang liang Mountain area, northern Tibet. China. Marine and Petroleum Geology 64: 203-221.
  88. Zhang LF, Sun M, Wang SG, Yu XY (1998) The composition of shales from the Ordos basin, China: effects of source weathering and diagenesis. Sedimentary Geology 116(1-2): 129-141.
  89. Zhou L, Algeo TJ, Shen J, Hu ZF, Gong H, Xie S, Huang JH, Gao S (2015) Changes in marine productivity and redox conditions during the late Ordovician Hirnantian glaciation. Paleogeography. Palaeoclimatology. Paleoecology 420: 223-234.