Microwave assisted Pd(OAc)2-catalyzed chemoselective reduction of aryl α,β-unsaturated esters with triethylsilane

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  • Yogesh Kumar1,
  • Renuka Yadav1,
  • Anshu Kumar Sinha1,
  • Pooja Rawat1,
  • Gyandshwar Kumar Rao1,
  • Chandra Mohan Srivastava2,
  • Nirmala Kumari Jangid3,
  • Anamika Srivastava3,
  • Manish Srivastava3,
  • Varun Rawat*1,
  1. Department of Applied Chemistry, Amity School of Applied Sciences, Amity University Haryana, Gurugram-122413 (Haryana), India.
  2. Centre for Polymer Technology, Amity School of Applied Sciences, Amity University Haryana, Gurugram-122413 (Haryana), India.
  3. Department of Chemistry, Banasthali Vidyapith, Banasthali-304022 (Rajasthan), India.

Published in Issue 2024-02-03

How to Cite

Kumar, Y., Yadav, R., Sinha, A. K., Rawat, P., Rao, G. K., Srivastava, C. M., Jangid, N. K., Srivastava, A., Srivastava, M., & Rawat, V. (2024). Microwave assisted Pd(OAc)2-catalyzed chemoselective reduction of aryl α,β-unsaturated esters with triethylsilane. Iranian Journal of Catalysis, 10(3). https://oiccpress.com/ijc/article/view/3562

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Abstract

< p>In this communication, we have reported that the Pd(OAc)2âEt3SiH-DMF system promotes the microwave-assisted chemoselective reduction of aryl α,β-unsaturated esters in good yields. The protocol affords a convenient reduction of aryl-conjugated double bonds even in presence of other functional groups like esters, phenols, and ethers.

Keywords

  • Chemoselective,
  • Microwave,
  • Palladium,
  • reduction,
  • Triethylsilane.
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