Application of multipurpose dimethyl formamide-like task specific ionic liquid as a recyclable reagent for direct iodination of alcohols

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  • Ahmed Ali Hullio1,
  • G.M. Mastoi2,
  1. Dr. M.A Kazi Institute of chemistry, University of Sindh Jamshoro-76080, Pakistan.
  2. Dr. M.A Kazi Institute of Chemistry, University of Sindh Jamshoro-76080 Sindh, Pakistan.

Published in Issue 2024-02-03

How to Cite

Hullio, A. A., & Mastoi, G. (2024). Application of multipurpose dimethyl formamide-like task specific ionic liquid as a recyclable reagent for direct iodination of alcohols. Iranian Journal of Catalysis, 1(2). https://oiccpress.com/ijc/article/view/3534

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Abstract

A direct and an efficient conversion of a wide range of primary, secondary even tertiary alcohols to the corresponding iodides have been achieved under ionic liquid conditions. The method involves preparation of ionic liquid-based iminium chloride intermediate from DMF-like ionic liquid then stirring it with alcohol in present of sodium iodide. The higher yields of alkyl iodides were obtained within minimum time with simplest operational procedure. The DMF-like ionic liquids could be recycled.

Keywords

  • Alcohols and alkyl iodides.,
  • DMF-like ionic liquid,
  • Iminium chloride,
  • Thioiminium salt,
  • Vilsmier reagent
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