10.1007/s40097-019-0293-x

Synthesis and characterization of epoxy/graphite/nano-copper nanocomposite for the fabrication of bipolar plate for PEMFCs

  1. Department of Chemistry, Rasht Branch, Islamic Azad University, Rasht, 3516-41335, IR
  2. Department of Chemistry, Shahr-e-Qods Branch, Islamic Azad University, Tehran, IR Material and Nuclear Fuel Cyclic Research School, NSTRI, Tehran, IR
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Published in Issue 23-01-2019

How to Cite

Soleimani Alavijeh, M., Kefayati, H., Nozad Golikand, A., & Shariati, S. (2019). Synthesis and characterization of epoxy/graphite/nano-copper nanocomposite for the fabrication of bipolar plate for PEMFCs. Journal of Nanostructure in Chemistry, 9(1 (March 2019). https://doi.org/10.1007/s40097-019-0293-x

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Abstract

Abstract In this research, the synthesis of a suitable nanocomposite in terms of properties and economics for use in bipolar plates in proton-exchange membrane fuel cells (PEMFCs) has been carried out successfully. Nowadays, bipolar plates play a significant role in fuel cells which is absolutely important in renewable energy industry. So, epoxy/graphite/nano-copper nanocomposite bipolar plates are prepared by bulk molding compound process. Graphite and nano-copper were added as primary and secondary fillers to the composite, respectively. Epoxy resin was selected since fabrication bulk molding can be done with ease and also because of its lower cost compared to other materials. Although graphite could increase conductive characteristics, it is not sufficient for bipolar plates. Therefore, we boost the conductive properties by increasing nano-copper. Due to the small size of nanoscale copper, it can be well dispersed in polymer and graphite matrix; nano-copper can release conductive properties perfectly throughout the composite. Different percentages of nano-copper, graphite and constant percentage of epoxy are used for this purpose. The electrical resistance, flexural strength, and density of composites were measured according to the applicable standards. The morphology of the prepared plate was studied by scanning electron microscopy (SEM) and X-ray diffraction (XRD) found that fillers disperse well in the matrix. Innovations in this work include improving properties and increasing the efficiency of the nanocomposite by adding metal nanoparticles (copper). Graphical Abstract

Keywords

  • Bipolar plate,
  • Nanocomposite,
  • Fuel cell,
  • Nano-copper,
  • Graphite

References

  1. Panwar et al. (2011) Role of renewable energy sources in environmental protection (pp. 1513-1524) https://doi.org/10.1016/j.rser.2010.11.037
  2. John (2017) A realizable renewable energy future. Renewable and non-renewable energy consumption anld economic growth in emerging economies: Evidence from bootstrap panel causality (pp. 757-763) https://doi.org/10.1016/j.renene.2017.05.008
  3. Mathiesen et al. (2015) Smart energy systems for coherent 100% renewable energy and transport solutions (pp. 139-154) https://doi.org/10.1016/j.apenergy.2015.01.075
  4. Shafiee and Topal (2009) When will fossil fuel reserves be diminished? (pp. 181-189) https://doi.org/10.1016/j.enpol.2008.08.016
  5. Dimitriou and Tsujimura (2017) A review of hydrogen as a compression ignition engine fuel (pp. 24470-24486) https://doi.org/10.1016/j.ijhydene.2017.07.232
  6. Edwards et al. (2008) Hydrogen and fuel cells: towards a sustainable energy future (pp. 4356-4362) https://doi.org/10.1016/j.enpol.2008.09.036
  7. Agbossou et al. (2001) Renewable energy systems based on hydrogen for remote applications (pp. 168-172) https://doi.org/10.1016/S0378-7753(01)00495-5
  8. Magdalena and Veziroglu (2005) The properties of hydrogen as fuel tomorrow in a sustainable energy system for a cleaner planet (pp. 795-802)
  9. Shu et al. (2010) Novel functionalized carbon nanotubes as cross-links reinforced vinyl ester/nanocomposite bipolar plates for polymer electrolyte membrane fuel cells (pp. 7808-7817) https://doi.org/10.1016/j.jpowsour.2009.10.020
  10. Chen et al. (2010) Study on the preparation and properties of novolac epoxy/graphite composite bipolar plate for PEMFC (pp. 3105-3109) https://doi.org/10.1016/j.ijhydene.2009.08.030
  11. Liao et al. (2008) Preparation and properties of carbon nanotube/polypropylene nanocomposite bipolar plates for polymer electrolyte membrane fuel cells (pp. 1225-1232) https://doi.org/10.1016/j.jpowsour.2008.06.097
  12. Taherian et al. (2012) Preparation and properties of a phenolic/graphite nanocomposite bipolar plate for proton exchange membrane fuel cell (pp. 39-46) https://doi.org/10.1149/2.005206jss
  13. Antunes and De-Oliveira (2011) Investigation on the corrosion resistance of carbon black-graphite-poly (vinylidene fluoride) composite bipolar plates for polymer electrolyte membrane fuel cells (pp. 12474-12485) https://doi.org/10.1016/j.ijhydene.2011.06.131
  14. Kim et al. (2012) Material selection windows for hybrid carbons/poly (phenylene sulfide) composite for bipolar plates of the fuel cell (pp. 537-545) https://doi.org/10.1016/j.polymertesting.2012.02.006
  15. Phuttachart et al. (2014) PMMA/PU/CB composite bipolar plate for direct methanol fuel cell (pp. 516-524) https://doi.org/10.1016/j.egypro.2014.07.105
  16. Mele and Bozzini (2010) Localised corrosion processes of austenitic stainless steel bipolar plates for polymer electrolyte membrane fuel cells (pp. 3590-3596) https://doi.org/10.1016/j.jpowsour.2009.11.144
  17. Wind et al. (2002) Metallic bipolar plates for PEM fuel cells (pp. 256-260) https://doi.org/10.1016/S0378-7753(01)00950-8
  18. Min et al. (2012) Honeycomb-like nanocomposite Ti-Ag-N films prepared by pulsed bias arc ion plating on titanium as bipolar plates for unitized regenerative fuel cells (pp. 196-202) https://doi.org/10.1016/j.jpowsour.2011.10.022
  19. Borrell et al. (2011) Alumina-carbon nanofibers nanocomposites obtained by spark plasma sintering for proton exchange membrane fuel cell bipolar plates (pp. 599-605) https://doi.org/10.1002/fuce.201100042
  20. Park et al. (2010) Performance and long-term stability of Ti metal and stainless steels as a metal bipolar plate for a direct methanol fuel cell (pp. 4320-4328) https://doi.org/10.1016/j.ijhydene.2010.02.010
  21. Barranco et al. (2010) Cr and Zr/Cr nitride CAE-PVD coated aluminum bipolar plates for polymer electrolyte membrane fuel cells (pp. 11489-11498) https://doi.org/10.1016/j.ijhydene.2010.05.050
  22. Liao et al. (2010) Preparation and properties of functionalized multiwalled carbon nanotubes/polypropylene nanocomposite bipolar plates for polymer electrolyte membrane fuel cells (pp. 263-270) https://doi.org/10.1016/j.jpowsour.2009.06.064
  23. Matsuura et al. (2006) Study on the metallic bipolar plate for proton exchange membrane fuel cell (pp. 74-78) https://doi.org/10.1016/j.jpowsour.2006.04.064
  24. Nygran et al. (2014) Influence of deposition temperature and amorphous carbon on microstructure and oxidation resistance of magnetron sputtered nanocomposite Cr C films (pp. 143-153) https://doi.org/10.1016/j.apsusc.2014.03.014
  25. Du et al. (2010) Preparation and properties of thin epoxy/compressed expanded graphite composite bipolar plates for proton exchange membrane fuel cells (pp. 794-800) https://doi.org/10.1016/j.jpowsour.2009.08.033
  26. Kuan and Ma (2004) Preparation, electrical, mechanical and thermal properties of a composite bipolar plate for a fuel cell (pp. 7-17) https://doi.org/10.1016/j.jpowsour.2004.02.024
  27. Sulong et al. (2013) Rheological and mechanical properties of carbon nanotube/Graphite/SS316L/polypropylene nanocomposite for a conductive polymer composite (pp. 54-61) https://doi.org/10.1016/j.compositesb.2013.01.022
  28. Li and Shimizu (2008) Conductive PVDF/PA6/CNTs nanocomposites fabricated by dual formation of continuous and nanodispersion structures (pp. 5339-5344) https://doi.org/10.1021/ma8006834
  29. Kakati et al. (2010) Electrochemical and mechanical behavior of carbon composite bipolar plate for fuel cell (pp. 4185-4194) https://doi.org/10.1016/j.ijhydene.2010.02.033
  30. Liao et al. (2008) Preparation and properties of carbon nanotube-reinforced vinyl ester/nanocomposite bipolar plates for polymer electrolyte membrane fuel cells (pp. 175-182) https://doi.org/10.1016/j.jpowsour.2007.10.064
  31. Tawfik et al. (2007) Metal bipolar plates for PEM fuel cell—A review (pp. 755-767) https://doi.org/10.1016/j.jpowsour.2006.09.088