10.1007/s40097-018-0252-y

Asymmetric attachment and functionalization of plasmonic nanoparticles on ceramic interfaces

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  • Daniel Stadler1,
  • Shifaa Mohammed Siribbal1,
  • Isabel Gessner1,
  • Senol Öz1,
  • Shaista Ilyas1,
  • Sanjay Mathur*1,
  1. Department of Chemistry, Inorganic Chemistry, University of Cologne, Cologne, 50939, DE
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Published in Issue 12-02-2018

How to Cite

Stadler, D., Siribbal, S. M., Gessner, I., Öz, S., Ilyas, S., & Mathur, S. (2018). Asymmetric attachment and functionalization of plasmonic nanoparticles on ceramic interfaces. Journal of Nanostructure in Chemistry, 8(1 (March 2018). https://doi.org/10.1007/s40097-018-0252-y
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Abstract

Abstract The demands for materials that integrate more than one functional imaging or therapeutic unit are of increasing interest for biomedical applications. Here, we present the step-by-step preparation of asymmetric and optically active particles, namely, Gd 2 O 3 @Ag, Gd 2 O 3 @Au, SiO 2 –N 3 @Au, and SiO 2 –SH@Au . Successful attachment of plasmonic nanoparticles to the surface of metal-oxide spheres without necessity of a potentially toxic inter-adhesive layer was proven by optical methods as well as X-ray photoelectron spectroscopy. The combination of optical and magnetic properties as present in Gd 2 O 3 @Ag and Gd 2 O 3 @Au Janus-type particles leads to dual-imaging probes for optical and magnetic resonance imaging. In addition, functional groups, such as azide groups, were linked to the surface of silica particles previous to Au nanoparticle attachment. Subsequent site-selective click reactions with 5-FAM were successfully performed as demonstrated by UV–Vis measurements. All described systems exhibited excellent long-term stability and can, therefore, be considered as promising candidates for theranostic applications. Graphical abstract

Keywords

  • Theranostics,
  • Janus particles,
  • Optical materials,
  • Sputter deposition,
  • Magnetic
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