10.1007/s40097-017-0232-7

Synthesis of conductive polymer-coated mesoporous MCM-41 for textile dye removal from aqueous media

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  • Ali Torabinejad1,
  • Navid Nasirizadeh*1,
  • Mohammad Esmail Yazdanshenas1,
  • Habib-Allah Tayebi2,
  1. Department of Textile and Polymer Engineering, Yazd Branch, Islamic Azad University, Yazd, IR
  2. Department of Textile Engineering, Islamic Azad University of Qaemshahr, Qaemshahr, IR
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Published in Issue 19-07-2017

How to Cite

Torabinejad, A., Nasirizadeh, N., Yazdanshenas, M. E., & Tayebi, H.-A. (2017). Synthesis of conductive polymer-coated mesoporous MCM-41 for textile dye removal from aqueous media. Journal of Nanostructure in Chemistry, 7(3 (September 2017). https://doi.org/10.1007/s40097-017-0232-7
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Abstract

Abstract In this paper, we aimed to evaluate Acid Blue 62 removal from aqueous media, using mesoporous silicate MCM-41, loaded with polypyrrole (PPy) and polyaniline (PAni) composites. PPy/MCM-41 nanocomposite showed higher performance than PAni/MCM-41 due to its smaller molecule size. For characterizing the synthesized composites, different methods were applied. The Langmuir model showed the greatest agreement with the experimental findings ( q m , 55.55 mg g −1 ). The kinetic study also confirmed the compatibility between the pseudo-second-order model and adsorption. Moreover, we measured Gibbs free energy changes (Δ G o ) and enthalpy changes (Δ H o ). Considering the negative Δ G o and positive Δ H o , AB62 adsorption on PPy/MCM-41 nanocomposite can be considered a spontaneous, endothermic reaction.

Keywords

  • Adsorption,
  • Acid Blue 62,
  • Polypyrrole,
  • Polyaniline,
  • MCM-41
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