10.1007/s40097-016-0195-0

Synthesis of Bi2WO6 nanoplates using oleic acid as a green capping agent and its application for thiols oxidation

  1. Department of Chemistry, Iran University of Science and Technology, Tehran, 16846-13114, IR
Cover Image

Published in Issue 06-05-2016

How to Cite

Rahimi, R., Pordel, S., & Rabbani, M. (2016). Synthesis of Bi2WO6 nanoplates using oleic acid as a green capping agent and its application for thiols oxidation. Journal of Nanostructure in Chemistry, 6(2 (June 2016). https://doi.org/10.1007/s40097-016-0195-0

HTML views: 6

PDF views: 66

Abstract

Abstract Bi 2 WO 6 nanoplates were synthesized by a simple one-step hydrothermal method using oleic acid (OA) as a green and cheap capping agent. The X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDS) were used to characterize the products. The interaction between the precursor product and oleic acid was studied by Fourier Transform Infrared (FT-IR). In addition, the catalytic activity of prepared Bi 2 WO 6 for the oxidation of thiols to disulfides as an important reaction in both biological and chemical processes was investigated. It was found to be an efficient catalyst for the selective oxidation of thiols to the corresponding disulfides, without over-oxidation, at room temperature.

Keywords

  • Bi2WO6,
  • Oleic acid,
  • Thiol oxidation,
  • Green capping agent

References

  1. Patel and Mishra (2004) Cetyltrimethylammonium dichromate: a mild oxidant for coupling amines and thiols (pp. 1371-1372) https://doi.org/10.1016/j.tetlet.2003.12.068
  2. Wu et al. (1996) Preparation of disulfides by the oxidation of thiols using bromine (pp. 191-196) https://doi.org/10.1080/00397919608003879
  3. McKillop et al. (1990) Efficicient, high yield, oxidation of thiols and selenols to disulphides and diselenides (pp. 5007-5010) https://doi.org/10.1016/S0040-4039(00)97790-6
  4. Pryor et al. (1982) Oxidation of thiols by nitric oxide and nitrogen dioxide: synthetic utility and toxicological implications (pp. 156-159) https://doi.org/10.1021/jo00340a038
  5. Soleiman-Beigi and Taherinia (2014) Simple and efficient oxidative transformation of thiols to disulfides using Cu (NO3) 2·3H2O in H2O/AcOEt (pp. 1151-1154) https://doi.org/10.1007/s00706-014-1178-9
  6. Wallace (1996) Reactions of thiols with metals. I. Low-temperature oxidation by metal oxides 1 (pp. 1217-1221) https://doi.org/10.1021/jo01342a056
  7. Huang et al. (2012) Controllable synthesis and visible-light-responsive photocatalytic activity of Bi2WO6 fluffy microsphere with hierarchical architecture (pp. 132-138) https://doi.org/10.1016/j.jcis.2011.12.056
  8. Yao et al. (2012) Biomimetic Bi2WO6 with hierarchical structures from butterfly wings for visible light absorption (pp. 21-24) https://doi.org/10.1016/j.matlet.2012.02.116
  9. Shang et al. (2008) Bi2WO6 nanocrystals with high photocatalytic activities under visible light (pp. 10407-10411) https://doi.org/10.1021/jp0773841
  10. Shang et al. (2009) A practical visible-light-driven Bi2WO6 nanofibrous mat prepared by electrospinning (pp. 6213-6218) https://doi.org/10.1039/b907849e
  11. Mann and Skrabalak (2011) Synthesis of single-crystalline nanoplates by spray pyrolysis: a metathesis route to Bi2WO6 (pp. 1017-1022) https://doi.org/10.1021/cm103007v
  12. Liu et al. (2015) Synthesis and characterization of Bi2WO6 nanoplates using egg white as a biotemplate through sol-gel method (pp. 401-404) https://doi.org/10.1016/j.matlet.2014.10.131
  13. Cao et al. (2011) Microwave-assisted solution-phase preparation of flower-like Bi2WO6 and its visible-light-driven photocatalytic properties (pp. 306-311) https://doi.org/10.1039/C0CE00031K
  14. Yoshimura and Byrappa (2008) Hydrothermal processing of materials: past, present and future (pp. 2085-2103) https://doi.org/10.1007/s10853-007-1853-x
  15. Dumrongrojthanath et al. (2013) Hydrothermal synthesis of Bi2WO6 hierarchical flowers with their photonic and photocatalytic properties (pp. 71-77) https://doi.org/10.1016/j.spmi.2012.11.001
  16. He et al. (2011) Self-assembled 3D hierarchical clew-like Bi2WO6 microspheres: synthesis, photo-induced charges transfer properties, and photocatalytic activities (pp. 4053-4059) https://doi.org/10.1039/c0ce00918k
  17. Tang et al. (2012) One-step preparation of bismuth tungstate nanodisks with visible-light photocatalytic activity (pp. 171-173) https://doi.org/10.1016/j.matlet.2011.10.080
  18. Li et al. (2008) Synthesis and visible-light photocatalytic property of Bi2WO6 hierarchical octahedron-like structures (pp. 365-371) https://doi.org/10.1007/s11671-008-9168-7
  19. Zhang and Zhu (2005) Synthesis of square Bi2WO6 nanoplates as high-activity visible-light-driven photocatalysts (pp. 3537-3545) https://doi.org/10.1021/cm0501517
  20. Geng et al. (2014) Fabrication and enhanced visible-light photocatalytic activities of BiVO4/Bi2WO6 composites (pp. 46054-46059) https://doi.org/10.1039/C4RA07427K
  21. Pawsey et al. (2002) Self-assembly of carboxyalkylphosphonic acids on metal oxide powders (pp. 5205-5212) https://doi.org/10.1021/la015749h
  22. Shukla et al. (2003) FTIR study of surfactant bonding to FePt nanoparticles (pp. 178-184) https://doi.org/10.1016/S0304-8853(03)00469-4
  23. Blyholder et al. (1995) Structure and orientation of oleic acid adsorbed onto silica gel (pp. 151-158) https://doi.org/10.1016/0927-7757(95)03326-7