10.1007/s40097-014-0144-8

Desulfurization of gasoline using novel mesoporous carbon adsorbents

  1. Research Laboratory of Nanoporous Materials, Faculty of Chemistry, Iran University of Science and Technology, Tehran, 16846-13114, IR
  2. Research Laboratory of Advanced Materials, Chemistry and Chemical Engineering Research Center of Iran, Tehran, IR
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Published in Issue 17-12-2014

How to Cite

Anbia, M., & Karami, S. (2014). Desulfurization of gasoline using novel mesoporous carbon adsorbents. Journal of Nanostructure in Chemistry, 5(1 (March 2015). https://doi.org/10.1007/s40097-014-0144-8

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Abstract

Abstract Ordered mesoporous carbon (OMC) adsorbents have been prepared using spherical SBA-16 mesoporous silica, as a template. The synthesized materials were studied by X-ray diffraction, scanning electron microscopy and nitrogen adsorption–desorption isotherms. OMCs have been tested for adsorption of dibenzothiophene (DBT) as model sulfur compound from gasoline fuels. The OMC showed higher sulfur adsorption due to large mesopore volume and high specific surface area. The results confirm the significance of the adsorbent pore size and its surface chemistry for the adsorption of DBT from petroleum fuels. Langmuir and Freundlich isotherm models were used to fit equilibrium data for OMC. The equilibrium results were best demonstrated by the Langmuir isotherm.

Keywords

  • Mesoporous SBA-16,
  • OMC,
  • Adsorption,
  • Gasoline fuels,
  • Dibenzothiophene

References

  1. Fallah and Azizian (2012) Removal of thiophenic compounds from liquid fuel by different modified activated carbon cloths (pp. 45-52) https://doi.org/10.1016/j.fuproc.2011.09.012
  2. Muzic et al. (2010) Study of diesel fuel desulfurization by adsorption (pp. 487-495) https://doi.org/10.1016/j.cherd.2009.08.016
  3. Ania and Bands (2006) Metal-loaded polystyrene-based activated carbons as dibenzothiophene removal media via reactive adsorption (pp. 2404-2412) https://doi.org/10.1016/j.carbon.2006.05.016
  4. Houalla et al. (1980) Hydrodesulfurization of methyl-substituted dibenzothiophenes catalyzed by sulfide Co-Mo/γ-Al2O3 (pp. 523-527) https://doi.org/10.1016/0021-9517(80)90400-5
  5. Song (2003) An overview of new approaches to deep desulfurization for ultra-clean gasoline, diesel fuel and jet fuel (pp. 211-263) https://doi.org/10.1016/S0920-5861(03)00412-7
  6. Cristol et al. (2004) DBT derivatives adsorption over molybdenum sulfide catalysts: a theoretical study (pp. 138-147) https://doi.org/10.1016/j.jcat.2004.02.008
  7. Ma et al. (1995) Hydrodesulfurizationreactivities of narrow-cut fractions in a gas oil (pp. 748-754) https://doi.org/10.1021/ie00042a006
  8. Ma et al. (1994) Hydrodesulfurizationreactivities of various sulfur compounds in diesel fuel (pp. 218-222) https://doi.org/10.1021/ie00026a007
  9. Song (2002) Fuel processing for low-temperature and high-temperature fuel cells: challenges, and opportunities for sustainable development in the 21st century https://doi.org/10.1016/S0920-5861(02)00231-6
  10. Awuala et al. (2014) Selective cesium removal from radioactive liquid waste by crown ether immobilized new class conjugate adsorbent (pp. 227-235) https://doi.org/10.1016/j.jhazmat.2014.06.011
  11. Blanco-Brieva et al. (2013) Thermal regeneration of the metal organic frameworks used in the adsorption of refractory organosulfur compounds from liquid fuels (pp. 459-465) https://doi.org/10.1016/j.fuel.2012.08.003
  12. Delitala et al. (2008) Liquid-phase thiophene adsorption on MCM-22 zeolite https://doi.org/10.1016/j.micromeso.2007.06.018
  13. Tang et al. (2008) Deep desulfurization by selective adsorption on a heteroatoms zeolite prepared by secondary synthesis (pp. 1-6) https://doi.org/10.1016/j.fuproc.2007.06.002
  14. Wang et al. (2011) A theoretical study of thiophenic compounds adsorption on cation-exchanged Y zeolites (pp. 7539-7544) https://doi.org/10.1016/j.apsusc.2011.03.115
  15. Tang et al. (2011) Adsorption desulfurization on a nanocrystalline NaY zeolite synthesized using carbon nanotube templated growth (pp. 779-787) https://doi.org/10.1080/10916460903070025
  16. Che et al. (2003) Direct observation of 3D mesoporous structure by scanning electron microscopy (SEM): SBA-15 silica and CMK-5 carbon (pp. 2182-2185) https://doi.org/10.1002/anie.200250726
  17. Awual et al. (2014) Radioactive cesium removal from nuclear wastewater by novel inorganic and conjugate adsorbents (pp. 127-135) https://doi.org/10.1016/j.cej.2013.12.072
  18. Kim et al. (2005) Characterization of mesoporous carbons synthesized with SBA-16 silica template (pp. 1560-1571) https://doi.org/10.1039/b417804a
  19. Awual et al. (2013) Evaluation of lanthanide sorption and their coordination mechanism by EXAFS measurement using novel hybrid adsorbent (pp. 558-566) https://doi.org/10.1016/j.cej.2013.04.015
  20. Han et al. (2003) New nanoporous carbon materials with high adsorption capacity and rapid adsorption kinetics for removing humic acids (pp. 131-135) https://doi.org/10.1016/S1387-1811(02)00611-X
  21. Ohkubo et al. (2002) Adsorption properties of templated mesoporous carbon (CMK-1) for nitrogen and supercritical methane experiment and GCMC simulation (pp. 6523-6528) https://doi.org/10.1021/jp0200369
  22. Joo et al. (2001) Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles (pp. 169-172) https://doi.org/10.1038/35084046
  23. Jun et al. (2000) Synthesis of new nanoporous carbon with hexagonally ordered mesostructure (pp. 10712-10713) https://doi.org/10.1021/ja002261e
  24. Khazaeli et al. (2013) A new functionalized resin and its application in flame atomic absorption spectrophotometric determination of trace amounts of heavy metal ions after solid phase extraction in water samples https://doi.org/10.1016/j.microc.2012.06.002
  25. Zhao et al. (1998) Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores (pp. 548-552) https://doi.org/10.1126/science.279.5350.548
  26. Zhao et al. (1998) Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures (pp. 6024-6036) https://doi.org/10.1021/ja974025i
  27. Guo et al. (2005) Adsorption of vitamin B12 on ordered mesoporous carbons coated with PMMA (pp. 2344-2351) https://doi.org/10.1016/j.carbon.2005.04.014
  28. Anbia and Parvin (2011) Desulfurization of fuels by means of a nanoporous carbon adsorbent (pp. 641-647) https://doi.org/10.1016/j.cherd.2010.09.014
  29. FarzinNejad et al. (2013) Synthesis of magnetic mesoporous carbon and its application for adsorption of dibenzothiophene (pp. 376-384) https://doi.org/10.1016/j.fuproc.2012.09.002
  30. Palomino et al. (2014) Mesoporous silica nanoparticles for high capacity adsorptive desulfurization (pp. 14890-14895) https://doi.org/10.1039/C4TA02570A
  31. Haji and Erkey (2003) Removal of dibenzothiophene from model diesel by adsorption on carbon aerogels for fuel cell applications https://doi.org/10.1021/ie030518m
  32. SunaErses et al. (2005) Determination of solid waste sorption capacity for selected heavy metals in landfills (pp. 223-232) https://doi.org/10.1016/j.jhazmat.2005.02.011