10.1007/s40097-021-00440-7

The natural non-ionic magnetic surfactants: nanomicellar and interfacial properties

  1. Surface Chemistry Research Laboratory, Faculty of Chemistry, Iran University of Science and Technology, Tehran, IR

Published in Issue 12-09-2021

How to Cite

Sohrabi, B., Mansouri, F., & Karimi, S. (2021). The natural non-ionic magnetic surfactants: nanomicellar and interfacial properties. Journal of Nanostructure in Chemistry, 12(5 (October 2022). https://doi.org/10.1007/s40097-021-00440-7

Abstract

Abstract In some applications, including the interaction of surfactants with petroleum products, the use of magnetic surfactants is a good idea for collecting the oil leaked from ships on seawater; however, the high use of these materials in various industries has resulted in environmental pollution. In this paper, first, by adding Iron (III) chloride hexahydrate (FeCl 3 (H 2 O) 6 ), Nickel(II) chloride hexahydrate (NiCl 2 (H 2 O) 6 ), Cobalt (II) chloride hexahydrate (CoCl 2 (H 2 O) 6 ), surfactants of magnetic cetyltrimethylammonium bromide and dodecyltrimethylammonium bromide were prepared. Then, for the first time, with the help of these salts, the natural surfactant extracted from the Licorice roots has been magnetized as an environmentally friendly surfactant. Next, the surface properties of these materials were examined and the performances of magnetic and non-magnetic samples were compared. Ultimately, a mixture of synthetic and natural magnetic surfactants was used to disperse the oil, and the emulsion produced was collected by the magnet, and its performance was compared with the mixture of natural and synthetic non-magnetic surfactants. Graphic abstract

Keywords

  • Environmentally friendly surfactant,
  • Natural magnetic surfactant,
  • Nanomicelles,
  • Magnetic field,
  • Oil dispersion

References

  1. Rosen, M.J., Kunjappu, J.T.: Surfactants and interfacial phenomena. John Wiley & Sons (2012)
  2. Puerto, M.C.: Surfactants: fundamentals and applications in the petroleum industry-Cambridge University Press, 2000, p. 621, ISBN 0-521-64067-9. Chem. Eng. J. 1, 63 (2001)
  3. Hussain et al. (2020) Influence of lipophilic tail and linker groups on the surface and thermal properties of the synthesized dicationic surfactants for oilfield applications https://doi.org/10.1016/j.molliq.2020.114172
  4. Shehzad et al. (2021) Magnetic surfactants: a review of recent progress in synthesis and applications https://doi.org/10.1016/j.cis.2021.102441
  5. Yang et al. (2021) Superhydrophobic magnetic hollow carbon microspheres with hierarchical micro/nano-structure for ultrafast and highly-efficient multitasking oil-water separation (pp. 70-78) https://doi.org/10.1016/j.carbon.2020.11.078
  6. Brown et al. (2012) Magnetic control over liquid surface properties with responsive surfactants (pp. 2414-2416) https://doi.org/10.1002/anie.201108010
  7. Shaban et al. (2020) Surfactants: recent advances and their applications https://doi.org/10.1016/j.coco.2020.100537
  8. Wagay et al. (2020) Synthesis, aggregation and adsorption behavior of benzyldimethylhexadecylammonium based double-chained metallosurfactants https://doi.org/10.1016/j.molliq.2019.112234
  9. Wang et al. (2018) Recent progress of magnetic surfactants: self-assembly, properties and functions (pp. 81-90) https://doi.org/10.1016/j.cocis.2018.01.014
  10. Dai et al. (2019) Design and functionalization of magnetic ionic liquids surfactants (MILSs) containing alkyltrimethylammonium fragment (pp. 170-174) https://doi.org/10.1016/j.molliq.2018.12.096
  11. Dai et al. (2021) Magnetic microemulsions stabilized by alkyltrimethylammonium-based magnetic ionic liquids surfactants (MILSs) (pp. 1846-1851) https://doi.org/10.1021/acs.jpcb.0c09305
  12. Gupta et al. (2020) Surfactant based synthesis and magnetic studies of cobalt ferrite (pp. 1-13) https://doi.org/10.1007/s00339-020-03823-9
  13. Xu et al. (2015) Ordered DNA-surfactant hybrid nanospheres triggered by magnetic cationic surfactants for photon-and magneto-manipulated drug delivery and release (pp. 4004-4012) https://doi.org/10.1021/acs.biomac.5b01372
  14. Yi et al. (2021) Amphiphilic Au nanoclusters modulated by magnetic gemini surfactants as a cysteine chemosensor and an MRI contrast agent (pp. 3130-3138) https://doi.org/10.1021/acs.langmuir.0c03618
  15. Brown et al. (2013) Properties of new magnetic surfactants (pp. 3246-3251) https://doi.org/10.1021/la400113r
  16. Brown et al. (2015) Magnetic surfactants (pp. 140-150) https://doi.org/10.1016/j.cocis.2015.08.002
  17. Degen et al. (2014) About the role of surfactants on the magnetic control over liquid interfaces (pp. 11563-11566) https://doi.org/10.1021/la503142q
  18. Fortenberry et al. (2019) Stability of ionic magnetic surfactants in aqueous solutions: measurement techniques and impact on magnetic processes (pp. 11843-11849) https://doi.org/10.1021/acs.langmuir.9b02189
  19. Bordes and Holmberg (2015) Amino acid-based surfactants—do they deserve more attention? 222(222) (pp. 79-91) https://doi.org/10.1016/j.cis.2014.10.013
  20. Holmberg (2001) Natural surfactants (pp. 148-159) https://doi.org/10.1016/S1359-0294(01)00074-7
  21. Polarz et al. (2013) Panoscopic structures by hierarchical cascade self-assembly of inorganic surfactants with magnetic heads containing dysprosium ions (pp. 13665-13670) https://doi.org/10.1002/anie.201303565
  22. Polarz et al. (2014) Hybrid surfactant systems with inorganic constituents (pp. 946-954) https://doi.org/10.1002/anie.201303159
  23. Schmid et al. (2018) Saponins from European licorice roots (Glycyrrhiza glabra) (pp. 1734-1744) https://doi.org/10.1021/acs.jnatprod.8b00022
  24. Tykarska et al. (2012) Supramolecular organization of neutral and ionic forms of pharmaceutically relevant glycyrrhizic acid amphiphile self-assembly and inclusion of small drug molecules (pp. 2133-2137) https://doi.org/10.1021/cg300160c
  25. Wan et al. (2017) Responsive emulsion gels with tunable properties formed by self-assembled nanofibrils of natural saponin glycyrrhizic acid for oil structuring (pp. 2394-2405) https://doi.org/10.1021/acs.jafc.6b05242
  26. Brown et al. (2016) Magnetic surfactants and polymers with gadolinium counterions for protein separations (pp. 699-705) https://doi.org/10.1021/acs.langmuir.5b04146
  27. Payra et al. (2018) Natural polyphenol surfactants: solvent-mediated spherical nanocontainers and their stimuli-responsive release of molecular payloads (pp. 8025-8033) https://doi.org/10.1021/acs.chemmater.8b03741
  28. Kleindienst et al. (2015) Using dispersants after oil spills: impacts on the composition and activity of microbial communities (pp. 388-396) https://doi.org/10.1038/nrmicro3452
  29. Cirillo et al. (2011) Molecularly imprinted polymers for the selective extraction of glycyrrhizic acid from liquorice roots (pp. 1058-1063) https://doi.org/10.1016/j.foodchem.2010.09.077
  30. Pan et al. (2000) Microwave-assisted extraction of glycyrrhizic acid from licorice root (pp. 173-177) https://doi.org/10.1016/S1369-703X(00)00057-7
  31. Smith, B.C.: The carbonyl group, part I: introduction. Spectroscopy
  32. 32
  33. , 31–36 (2017)
  34. Hayakawa et al. (2019) Effect of moderate magnetic fields on the surface tension of aqueous liquids: a reliable assessment (pp. 10030-10033) https://doi.org/10.1039/C9RA00849G
  35. Reed et al. (2020) Interfacial vs bulk phenomena effects on the surface tensions of aqueous magnetic surfactants in uniform magnetic fields (pp. 10074-10081) https://doi.org/10.1021/acs.langmuir.0c01215
  36. Gibbs, J.W.: The collected works of J. Willard Gibbs, volume I: thermodynamics. Yale University Press (1928)
  37. Wang et al. (2016) Formulation and evaluation of novel glycyrrhizic acid micelles for transdermal delivery of podophyllotoxin (pp. 1623-1635) https://doi.org/10.3109/10717544.2015.1135489
  38. Dodrill, B., Cryotronics, L.S.: Magnetic media measurements with a VSM. Lake Shore Cryotronics, Westerville 575 (1999)
  39. Yi et al. (2019) Magnetic gemini surfactants (pp. 9538-9545) https://doi.org/10.1021/acs.langmuir.9b01478
  40. Nieboer and Richardson (1980) The replacement of the nondescript term ‘heavy metals’ by a biologically and chemically significant classification of metal ions (pp. 3-26) https://doi.org/10.1016/0143-148X(80)90017-8
  41. Atkins, P.W., Friedman, R.S.: Molecular quantum mechanics. Oxford University Press (2011)
  42. Morrish, A.H.: The physical principles of magnetism (2001)