10.1007/s40097-021-00405-w

Ternary NiCuZr layered double hydroxide@MIL-101 (Fe)-NH2 metal-organic framework for photocatalytic degradation of methylene blue

  • Mostafa Khajeh*1,
  • Ali Reza Oveisi1,
  • Afsaneh Barkhordar1,
  • Mansoureh Rakhshanipour1,
  • Hamed Sargazi-Avval1,
  1. Department of Chemistry, University of Zabol, Zabol, IR

Published in Issue 04-05-2021

How to Cite

Khajeh, M., Oveisi, A. R., Barkhordar, A., Rakhshanipour, M., & Sargazi-Avval, H. (2021). Ternary NiCuZr layered double hydroxide@MIL-101 (Fe)-NH2 metal-organic framework for photocatalytic degradation of methylene blue. Journal of Nanostructure in Chemistry, 12(1 (February 2022). https://doi.org/10.1007/s40097-021-00405-w
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Abstract

Abstract Ternary NiCuZr layered double hydroxide (LDH)/MIL-101(Fe)-NH 2 (MOF), as a tetrametalic porous composite, was synthesized for the first time by an easy solution casting technique and assessed for catalytic photodegradation of methylene blue dye. The new photocatalyst was characterized by different procedures including PXRD, FTIR, SEM/EDS, UV–Vis DRS, and BET measurements. The photocatalyst activity was investigated under numerous conditions such as pH, amount of photocatalyst, and concentration of methylene blue. Under the optimum conditions, the photocatalytic degradation efficiency of the composite was > 98% after 10 min radiation that was greater than that of former solids. Quenching assessments showed that the holes (h + ) done a major effect on the degradation of the analyte under LED illumination.

Keywords

  • Ternary NiCuZr layered double hydroxide,
  • MIL-101(Fe)-NH2,
  • Iron-based MOF,
  • Photocatalyst,
  • Methylene blue,
  • Remediation

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