Sulphonated polyaniline/MWCNTs nanocomposite: preparation and promising thermoelectric performance
Abstract
Abstract
Here is concise description of in situ prepared polyaniline and its nanocomposite with multi-walled carbon nanotubes followed by sulfonation. Thus, prepared materials were characterized by Fourier transform infrared spectroscopy, X-ray diffraction analysis, field emission scanning electron microscopy and electro-thermal analysis. Incorporation of ultrasonicated multi-walled carbon nanotubes significantly increased the electrical conductivity due to π–π interaction of polyaniline with multi-walled carbon nanotubes and its back to back sulfonation further rendered fortification. Finally, as-prepared nanocomposite showed greater electrical conductivity as well as improved thermal stability in terms of DC electrical conductivity retention under isothermal and cyclic aging conditions.
Keywords
- Pani/MWCNTs nanocomposite,
- In situ polymerization,
- Sulfonation,
- Isothermal and cyclic aging
References
- Dong et al. (2007) Preparation and electrochemical characterization of polyaniline/multi-walled carbon nanotubes composites for supercapacitor (pp. 7-13) https://doi.org/10.1016/j.mseb.2007.06.017
- Gospodinova and Terlemezyan (1998) Conducting polymers prepared by oxidative polymerization: polyaniline (pp. 1443-1484) https://doi.org/10.1016/S0079-6700(98)00008-2
- Subrahmanyam et al. (2012) Mechanical and electrical conductivity studies of PANI-PVA and PANI-PEO blends (pp. 27-30)
- Ansari and Mohammad (2012) Thermal stability and electrical properties of dodecyl-benzene-sulfonic-acid doped nanocomposites of polyaniline and multi-walled carbon nanotubes (pp. 3541-3548) https://doi.org/10.1016/j.compositesb.2011.11.031
- Lin and Wu (2009) Synthesis and characterization of externally doped sulfonated polyaniline/multi-walled carbon nanotube composites (pp. 2559-2565) https://doi.org/10.1016/j.compscitech.2009.07.013
- Huang et al. (2003) Polyaniline nanofibers: facile synthesis and chemical sensors (pp. 314-315) https://doi.org/10.1021/ja028371y
- Song and Choi (2013) Conducting polyaniline nanowire and its applications in chemiresistive sensing (pp. 498-523) https://doi.org/10.3390/nano3030498
- Huang et al. (2002) Polyaniline nanowires by electropolymerization from liquid crystalline phases (pp. 388-391) https://doi.org/10.1039/b107499g
- Bai et al. (2009) Non-covalent functionalization of graphene sheets by sulfonated polyaniline (pp. 1667-1669) https://doi.org/10.1039/b821805f
- Koul et al. (2001) Compensated sulphonated polyaniline—correlation of processibility and crystalline structure (pp. 295-299) https://doi.org/10.1016/S0379-6779(01)00364-2
- Drelinkiewicz et al. (2009) Polyaniline stabilized highly dispersed Pt nanoparticles: preparation characterization and catalytic properties (pp. 630-642) https://doi.org/10.1016/j.reactfunctpolym.2009.04.007
- Wei and Epstein (1995) Synthesis of highly sulfonated polyaniline (pp. 123-125) https://doi.org/10.1016/0379-6779(95)03362-9
- Cai et al. (2013) Facile hydrothermal synthesis and surface functionalization of polyethyleneimine-coated iron oxide nanoparticles for biomedical applications (pp. 1722-1731) https://doi.org/10.1021/am302883m
- Hatamzadeh et al. (2012) Chemical modification of polyaniline by N-grafting of polystyrenic chains synthesized via nitroxide-mediated polymerization (pp. 1008-1017) https://doi.org/10.1590/S0103-50532012000600003
- Zhao et al. (2015) Nanocomposites of sulfonic polyaniline nanoarrays on graphene nanosheets with an improved supercapacitor performance (pp. 682-690) https://doi.org/10.1002/chem.201404840
- Yue and Epstein (1990) Synthesis of self-doped conducting polyaniline (pp. 2800-2801) https://doi.org/10.1021/ja00163a051
- Ansari and Mohammad (2011) Thermal stability, electrical conductivity and ammonia sensing studies on p-toluenesulfonic acid doped polyaniline: titanium dioxide (pTSA/Pani:TiO2) nanocomposites (pp. 122-129) https://doi.org/10.1016/j.snb.2011.03.036
- Morrison and Boyd (1992) Prentice Hall Pvt. Ltd.
- Pahovnik et al. (2013) Polyaniline nanostructures prepared in acidic aqueous solutions of ionic liquids acting as soft templates (pp. 1381-1390) https://doi.org/10.1016/j.eurpolymj.2013.02.019
- Kondawar et al. (2013) Carbon nanotubes reinforced conducting polyaniline and its derivative poly (o-anisidine) composites (pp. 35-38) https://doi.org/10.5185/amlett.2013.icnano.101
- Wang et al. (2014) Crosslinked polyaniline nanorods with improved electrochemical performance as electrode material for supercapacitors (pp. 12323-12329) https://doi.org/10.1039/C4TA02231A
10.1007/s40089-018-0246-2