10.1007/s40089-017-0199-x

Kinetics adsorption study of the ethidium bromide by graphene oxide as adsorbent from aqueous matrices

  1. Young Researchers and Elite Club, East Tehran Branch, Islamic Azad University, Tehran, IR
  2. Department of Chemistry, Shahr-e-Qods Branch, Islamic Azad University, Tehran, IR
  3. Department of Chemistry, Science and Research Branch, Islamic Azad University, Tehran, IR Department of Chemistry, Shahid Beheshti University, Tehran, IR
Cover Image

Published in Issue 2017-01-30

How to Cite

Rajabi, M., Moradi, O., & Zare, K. (2017). Kinetics adsorption study of the ethidium bromide by graphene oxide as adsorbent from aqueous matrices. International Nano Letters, 7(1 (March 2017). https://doi.org/10.1007/s40089-017-0199-x

HTML views: 37

PDF views: 123

Abstract

Abstract In this study of ethidium bromide, adsorption from aqueous matrices by graphene oxide as adsorbent was investigated. Influencing parameters in the adsorption study included contact time, temperature, and pH. The optimum time was selected 17 min, and the best value of pH was determined at 8. All adsorption experiments were performed at 298 K temperature. The maximum wavelength of ethidium bromide was 475 nm. The Elovich, four types of the pseudo-second-order, the pseudo-first-order, and intra-particle diffusion kinetic adsorption models were used for kinetic study, and the results show that adsorption of ethidium bromide on graphene oxide surface best complied with type (I) of the pseudo-second-order kinetic model.

Keywords

  • Kinetics,
  • Adsorption,
  • Ethidium bromide,
  • Graphene oxide,
  • Aqueous matrices

References

  1. Lunn and Sansone (1987) Ethidium bromide: destruction and decontamination of solutions (pp. 453-458) https://doi.org/10.1016/0003-2697(87)90419-2
  2. Stevenson et al. (1995) Comparison of isometamidium chloride and homidium bromide as prophylactic drugs for trypanosomiasis in cattle at Nguruman, Kenya (pp. 257-258) https://doi.org/10.1016/0001-706X(94)00080-K
  3. Najafi and Rajabi (2015) Thermal gravity analysis for the study of stability of graphene oxide–glycine nanocomposites (pp. 187-190) https://doi.org/10.1007/s40089-015-0154-7
  4. Neto et al. (2009) The electronic properties of graphene https://doi.org/10.1103/RevModPhys.81.109
  5. Yari et al. (2016) Removal of Pb(II) ion from aqueous solution by graphene oxide and functionalized graphene oxide-thiol: effect of cysteamine concentration on the bonding constant 57(24) (pp. 11195-11210) https://doi.org/10.1080/19443994.2015.1043953
  6. Choi et al. (2010) Synthesis of graphene and its applications: a review (pp. 52-71) https://doi.org/10.1080/10408430903505036
  7. Najafi et al. (2015) Thermodynamics of the adsorption of nickel ions from aqueous phase using graphene oxide and glycine functionalized graphene oxide (pp. 106-113) https://doi.org/10.1016/j.molliq.2015.04.033
  8. Dreyer et al. (2010) The chemistry of graphene oxide (pp. 228-240) https://doi.org/10.1039/B917103G
  9. Rajabi et al. (2015) Adsorption of methyl orange dye from water solutions by carboxylate group functionalized multi-walled carbon nanotubes 6(3) (pp. 227-240)
  10. Robati et al. (2015) Raman spectroscopy and TGA studies for the synthesis of multiwalled carbon nanotube-functionalized thiol (MWCNT-SH) nanocomposites: study of effect of concentration (pp. 179-182) https://doi.org/10.1007/s40089-015-0152-9
  11. Sedaghat (2013) Synthesis of clay–CNTs nanocomposite https://doi.org/10.1186/2193-8865-3-24
  12. Demiral and Güngör (2016) Adsorption of copper(II) from aqueous solutions on activated carbon prepared from grape bagasse (pp. 103-113) https://doi.org/10.1016/j.jclepro.2016.02.084
  13. Robati et al. (2016) Removal of hazardous dyes-BR 12 and methyl orange using graphene oxide as an adsorbent from aqueous phase (pp. 687-697) https://doi.org/10.1016/j.cej.2015.08.131
  14. Chi and Zhao (2009) Adsorption of formaldehyde molecule on the intrinsic and Al-doped graphene: a first principle study (pp. 1085-1090) https://doi.org/10.1016/j.commatsci.2009.05.017
  15. Li et al. (2012) Uranium(VI) adsorption on graphene oxide nanosheets from aqueous solutions (pp. 539-546) https://doi.org/10.1016/j.cej.2012.09.030
  16. Zhao et al. (2011) Kinetic and thermodynamic study of 1-naphthol adsorption from aqueous solution to sulfonated graphene nanosheets (pp. 185-190) https://doi.org/10.1016/j.cej.2011.07.072
  17. Fan et al. (2013) Synthesis of magnetic-cyclodextrin–chitosan/graphene oxide as nanoadsorbent and its application in dye adsorption and removal (pp. 601-607) https://doi.org/10.1016/j.colsurfb.2012.11.023
  18. Zhang et al. (2014) Adsorption of Pb(II) and Hg(II) from aqueous solution using magnetic CoFe2O4-reduced graphene oxide (pp. 177-182) https://doi.org/10.1016/j.molliq.2013.12.015
  19. Kim et al. (2015) Adsorption isotherms and kinetics of cationic and anionic dyes on three-dimensional reduced graphene oxide macrostructure (pp. 1191-1196) https://doi.org/10.1016/j.jiec.2014.05.033
  20. Mishra and Ramaprabhu (2011) Functionalized graphene sheets for arsenic removal and desalination of sea water (pp. 39-45) https://doi.org/10.1016/j.desal.2011.01.038
  21. Rajabi et al. (2016) Adsorption of malachite green from aqueous solution by carboxylate group functionalized multi-walled carbon nanotubes: determination of equilibrium and kinetics parameters (pp. 130-138) https://doi.org/10.1016/j.jiec.2015.11.001
  22. Açıkyıldız et al. (2015) A comparative examination of the adsorption mechanism of an anionic textile dye (RBY 3GL) onto the powdered activated carbon (PAC) using various the isotherm models and kinetics equations with linear and non-linear methods (pp. 279-284) https://doi.org/10.1016/j.apsusc.2015.07.021
  23. Robati et al. (2016) Effect of electrostatic interaction on the methylene blue and methyl orange adsorption by the pristine and functionalized carbon nanotubes (pp. 1-6) https://doi.org/10.1016/j.physe.2016.04.005
  24. Alia et al. (2016) Potential of using green adsorbent of heavy metal removal from aqueous solutions: adsorption kinetics, isotherm, thermodynamic, mechanism and economic analysis (pp. 317-332) https://doi.org/10.1016/j.ecoleng.2016.03.015
  25. Yari et al. (2015) Kinetics of the adsorption of Pb(II) ions from aqueous solutions by graphene oxide and thiol functionalized graphene oxide (pp. 50-57) https://doi.org/10.1016/j.molliq.2015.05.022
  26. Fu et al. (2015) Adsorption of methylene blue by a high-efficiency adsorbent (polydopamine microspheres): kinetics, isotherm, thermodynamics and mechanism analysis (pp. 53-61) https://doi.org/10.1016/j.cej.2014.07.101
  27. An et al. (2016) Removal of sulfonated humic acid from aqueous phase by modified coal fly ash waste: Equilibrium and kinetic adsorption studies (pp. 264-271) https://doi.org/10.1016/j.fuel.2015.10.069
  28. Lee (2016) Equilibrium, kinetic and thermodynamic parameter studies on adsorption of acid yellow 14 using activated carbon 54(2) (pp. 255-261) https://doi.org/10.9713/kcer.2016.54.2.255
  29. Wongrueng et al. (2016) Kinetic adsorption of fluoride from an aqueous solution onto a dolomite sorbent 20(3) (pp. 1-9) https://doi.org/10.4186/ej.2016.20.3.1
  30. Koçer and Acemioğlu (2016) Adsorption of Basic green 4 from aqueous solution by olive pomace and commercial activated carbon: process design, isotherm, kinetic and thermodynamic studies 57(35) (pp. 16653-16669) https://doi.org/10.1080/19443994.2015.1080194
  31. Al-Jabari (2016) Kinetic models for adsorption on mineral particles comparison between Langmuir kinetics and mass transfer (pp. 27-37) https://doi.org/10.1016/j.eti.2016.04.005
  32. Hafeznezami et al. (2016) Adsorption and desorption of arsenate on sandy sediments from contaminated and uncontaminated saturated zones: Kinetic and equilibrium modeling (pp. 290-301) https://doi.org/10.1016/j.envpol.2016.05.029