Low temperature synthesis of anacardic-acid-capped cadmium chalcogenide nanoparticles
Abstract
Abstract
We report the low temperature synthesis of CdE (E = S, Se and Te) semiconductor nanoparticles capped by anacardic acid, an environmentally benign naturally occurring capping ligand. The cadmium chalcogenide nanoparticles were synthesized by reacting the reduced chalcogen powder with cadmium chloride to form the corresponding bulk material which was then dispersed in tri-
n
-octylphosphine (TOP) and thermolysed in anacardic acid. The low temperature of the reaction and the use of a naturally occurring oil solvent make this a relatively green synthetic route. The optical properties of the anacardic-acid-capped cadmium chalcogenide particles show evidence of quantum confinement. The particles were characterized by X-ray diffraction and electron microscopy techniques.
Keywords
- Anacardic acid,
- CdE,
- Nanoparticles,
- Optical properties,
- Electron microscopy
References
- Lane (2001) The grand challenges of nanotechnology (pp. 95-103) https://doi.org/10.1023/A:1017951230941
- Alivisatos (1996) Semiconductor clusters, nanocrystals, and quantum dots (pp. 933-937) https://doi.org/10.1126/science.271.5251.933
- Ciftja and Faruk (2005) Two-dimensional quantum-dot helium in a magnetic field: variational theory https://doi.org/10.1103/PhysRevB.72.205334
- Harju et al. (1998) Variational wave function for a two- electron quantum dot (pp. 145-149) https://doi.org/10.1016/S0921-4526(98)00461-X
- Grundmann et al. (1995) Ultranarrow luminescence lines from single quantum dots (pp. 4043-4046) https://doi.org/10.1103/PhysRevLett.74.4043
- Ciftja (2013) Understanding electronic systems in semiconductor quantum dots https://doi.org/10.1088/0031-8949/88/05/058302
- Bruchez et al. (1998) Semiconductor nanocrystals as fluorescent biological labels (pp. 2013-2016) https://doi.org/10.1126/science.281.5385.2013
- Chan and Nie (1998) Quantum dot bioconjugates for ultrasensitive nonisotopic detection (pp. 2016-2018) https://doi.org/10.1126/science.281.5385.2016
- Wang et al. (2005) Biological assembly of nanocircuit prototypes from protein-modified CdTe nanowires (pp. 243-248) https://doi.org/10.1021/nl0482682
- Chen et al. (2009) An oleic acid-capped CdSe quantum-dot sensitized solar cell https://doi.org/10.1063/1.3117221
- Gao et al. (2000) Electroluminescence of different colors from polycation/CdTe nanocrystal self-assembled films (pp. 2297-2302) https://doi.org/10.1063/1.372177
- Greenham et al. (1996) Charge separation and transport in conjugated-polymer/semiconductor-nanocrystal composites studied by photoluminescence quenching and photoconductivity (pp. 17628-17637) https://doi.org/10.1103/PhysRevB.54.17628
- Brus (1984) Electron-electron and electron-hole interactions in small semiconductor crystallites: the size dependence of the lowest excited electronic state (pp. 4403-4409) https://doi.org/10.1063/1.447218
- Murray et al. (1993) Synthesis and characterization of nearly monodisperse CdE (E = S, Se, Te) semiconductor nanocrystallites (pp. 8706-8715) https://doi.org/10.1021/ja00072a025
- Manna et al. (2000) Synthesis of soluble and processable rod-, arrow-, teardrop-, and tetrapod-shaped CdSe nanocrystals (pp. 12700-12706) https://doi.org/10.1021/ja003055+
- Peng and Peng (2001) Formation of high-quality CdTe, CdSe, and CdS nanocrystals using CdO as precursor (pp. 183-184) https://doi.org/10.1021/ja003633m
- He and Gu (2006) Synthesis and characterization of monodisperse CdSe nanocrystals at lower temperature. Colloids and surfaces (pp. 111-116) https://doi.org/10.1016/j.colsurfa.2005.07.017
- Dunpall et al. (2012) An in vitro assessment of the interaction of cadmium selenide quantum dots with DNA, iron, and blood platelets (pp. 995-1002) https://doi.org/10.1002/iub.1100
- Boatman et al. (2005) A safer, easier, faster synthesis for CdSe quantum dot nanocrystals (pp. 1697-1699) https://doi.org/10.1021/ed082p1697
- Mntungwa et al. (2011) A facile route to shape controlled CdTe nanoparticles (pp. 500-506) https://doi.org/10.1016/j.matchemphys.2011.01.039
- Maseko et al. (2010) The influence of the cadmium source on the shape of CdSe nanoparticles (pp. 1037-1040) https://doi.org/10.1016/j.matlet.2010.02.002
- Sapra et al. (2006) Phosphine-free synthesis of monodisperse CdSe nanocrystals in olive oil (pp. 3391-3395) https://doi.org/10.1039/b607022a
- Patel et al. (2011) Simple non-aqueous fabrication route for oleic acid capped luminescent cadmium sulphide quantum dots at relatively low temperature (pp. 61-65) https://doi.org/10.4236/snl.2011.13011
- Mlowe et al. (2013) Lead chalcogenides stabilized by anacardic acid (pp. 263-268) https://doi.org/10.1016/j.mssp.2012.10.017
- Paramashivappa et al. (2001) Novel method for isolation of major phenolic constituents from cashew (Anacardium occidentale L.) Nut Shell Liquid (pp. 2548-2551) https://doi.org/10.1021/jf001222j
- Lucio et al. (2010) Synthesis and cytotoxicity screening of substituted isobenzofuranones designed from Anacardic acids (pp. 3480-3489) https://doi.org/10.1016/j.ejmech.2010.05.015
- Bawendi et al. (1990) The quantum mechanics of larger semiconductor clusters (“quantum dots”) (pp. 477-496) https://doi.org/10.1146/annurev.pc.41.100190.002401
- Ithuria and Dubertret (2008) Quasi 2D colloidal CdSe platelets with thicknesses controlled at the atomic level (pp. 16504-16505) https://doi.org/10.1021/ja807724e
- Efros et al. (1996) Band-edge exciton in quantum dots of semiconductors with a degenerate valence band: dark and bright exciton states (pp. 4843-4856) https://doi.org/10.1103/PhysRevB.54.4843
- Yoffe (2001) Semiconductor quantum dots and related systems: electronic, optical, luminescence and related properties of low dimensional systems (pp. 1-208) https://doi.org/10.1080/00018730010006608
- Norris et al. (1996) Size dependence of exciton fine structure in CdSe quantum dots (pp. 16347-16354) https://doi.org/10.1103/PhysRevB.53.16347
- Bawendi et al. (1992) Luminescence properties of CdSe quantum crystallites: resonance between interior and surface localized states (pp. 946-956) https://doi.org/10.1063/1.462114
- Bandaranayake et al. (1995) Structural phase behavior in II-VI semiconductor nanoparticles (pp. 831-833) https://doi.org/10.1063/1.115458
- Patterson (1939) The Scherrer formula for X-Ray particle size determination (pp. 978-982) https://doi.org/10.1103/PhysRev.56.978
- Rogach et al. (1999) Synthesis and characterization of a size series of extremely small thiol-stabilized CdSe nanocrystals (pp. 3065-3069) https://doi.org/10.1021/jp984833b
- Blokland et al. (2011) Exciton lifetime of CdTe nanocrystal quantum dots in high magnetic fields https://doi.org/10.1103/PhysRevB.83.035304
10.1007/s40089-014-0106-7