10.7508/ijnd.2016.04.005

Synthesize and characterization of Aminosilane functionalized MCM-41 for removal of anionic dye: Kinetic and thermodynamic study

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  • Ali Torabinejad1,
  • Navid Nasirizadeh2,
  • Mohammad Esmail Yazdanshenas3,
  • Habib Allah Tayebi4,
  1. Department of Textile Engineering, Yazd Branch, Islamic Azad University, Yazd, Iran
  2. Department of Textile and Polymer Engineering, Yazd Branch, Islamic Azad University, Yazd, Iran.
  3. Department of Textile and Polymer Engineering, Yazd Branch, Islamic Azad University, Yazd, Iran
  4. Department of Textile Engineering, Qaemshahr Branch, Islamic Azad University, Qaemshahr, Iran

Published in Issue 2024-02-28

How to Cite

Torabinejad, A., Nasirizadeh, N., Yazdanshenas, M. E., & Tayebi, H. A. (2024). Synthesize and characterization of Aminosilane functionalized MCM-41 for removal of anionic dye: Kinetic and thermodynamic study. International Journal of Nano Dimension, 7(4). https://doi.org/10.7508/ijnd.2016.04.005
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Abstract

In this study, removal of Acid blue 62 from aqueous solution by mesoporous silicate MCM-41 modified by Aminopropyltriethoxysilane (APTES) composite was studied. Properties of synthesized composite were analyzed and confirmed by SEM, EDX and FTIR. Results show that Langmuir adsorption isotherm has the best compatibility with the results of experiments. Kinetic analysis using pseudo-first-order model, pseudo-second-order and the intra-particle diffusion model was carried out. Results also confirmed that adsorption process is compatible with the pseudo-second-order kinetic model. Thermodynamic parameters such as Gibbs free energy changes (ÎGo), Enthalpy changes (ÎHo) and Entropy changes (ÎSo) were calculated. Negative value of ÎGo and positive value of ÎHo show that adsorption of Acid blue 62 on aminated nanocomposite is a spontaneous process also endothermic.

Keywords

  • Acid blue 62,
  • Adsorption,
  • Adsorption Isotherm,
  • adsorption kinetic,
  • MCM-41
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