10.30495/ijc.2022.1960932.1943

Silver supported on mesoporous silica combination with H2O2: active, recyclable, and selective oxidation component for conversion of olefines to 1, 2-diols

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  • Shakiba Samadi1,
  • Hadi Shafiei*1,
  • Davoud Soudbar1,
  • Hassan Fathinejad2,
  1. Department of Chemistry, Arak Branch, Islamic Azad University, Arak, Iran
  2. Department of Chemistry, Farahan Branch, Islamic Azad University, Farahan, Iran
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Published in Issue 2023-12-22

How to Cite

Samadi, S., Shafiei, H., Soudbar, D., & Fathinejad, H. (2023). Silver supported on mesoporous silica combination with H2O2: active, recyclable, and selective oxidation component for conversion of olefines to 1, 2-diols. Iranian Journal of Catalysis, 12(4). https://doi.org/10.30495/ijc.2022.1960932.1943
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Abstract

The selective oxidation of olefins is a key academic and industrial research challenge. Herein, silver was supported on mesoporous silica through a facile synthesis procedure, and characterized using various technics such as FT-IR, XRD, SEM, BET, and EDX. This efficient separable agent alongside aqueous H2O2 was applied to the oxidation of various olefines (1-octen, 1-hexene, cyclohexene, cyclooctene, styrene, and 1, 2-diphenylmethane) to 1, 2-diol under mild reaction conditions (65 â) with high conversion and excellent selectivity. The promoter exhibited excellent reusability and stability in the reaction medium.  

Highlights

  • Synthesis of new catalyst: Mesoporous silica based silver/H2O2
  • Selective oxidation of alkenes
  • Recovery of catalyst
  • Efficient catalyst for selective oxidation of olefins to 1,2-diols

Keywords

  • 2-diol,
  • Mesoporous silica,
  • Nanocomposite,
  • Selective oxidation,
  • Silver
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