Preparation and Characterization of Visible-Light-driven Sm-doped Bi2MoO6 Photocatalyst Used for Enhanced Degradation of Rhodamine
- Division of Physical Science, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand
- Department of Industrial Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai 50200, Thailand
- Advanced Scientific Instruments Unit (ASci Unit), Faculty of Science, Chiang Mai University, Chiang Mai 50200, Thailand
- Materials Science Research Center, Faculty of Science, Chiang Mai University, Chiang Mai 50200, Thailand
- Department of Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai 50200, Thailand
- Materials Science Research Center, Faculty of Science, Chiang Mai University, Chiang Mai 50200, Thailand
Received: 2025-11-26
Revised: 2026-01-11
Accepted: 2026-02-01
Published in Issue 2026-06-30
Published Online: 2026-05-11

This work is licensed under a Creative Commons Attribution 4.0 International License.
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Abstract
Bi2MoO6 samples containing different weight contents of Sm dopant as the visible-light-driven photocatalyst were successfully synthesized by hydrothermal method. All of them were certified as orthorhombic Bi2MoO6 nanoplates. The visible-light absorption range of Bi2MoO6 was increased by increasing in the Sm dopant. Different weight contents of Sm dopant containing in Bi2MoO6 were studied through the degradation of rhodamine B (RhB) under visible light irradiation. The photocatalytic efficiency of 1% Sm doped-Bi2MoO6 nanoplates was the highest of 96.27% or 3.91 times of Bi2MoO6 (24.65%) by increasing specific surface area, visible light harvest and separation of charge carriers.
Highlights
- Visible-light-driven Sm-doped Bi2MoO6 photocatalysts were synthesized by hydrothermal method.
- Pure phase of Sm-doped Bi2MoO6 nanoplates was produced in this research.
- The photocatalytic reaction of samples was tested by rhidamine B (RhB) degradation under visible light irradiation.
- 1% Sm-doped Bi2MoO6 showed the highest photocatalytic performance in this research.
Keywords
- Active radicals,
- Photocatalysis,
- Photocatalytic mechanism,
- Sm-doped Bi2MoO6
References
- T. Chankhanittha, V. Somaudon, J. Watcharakitti, V. Piyavarakorn, and S. Nanan. Mater. Lett., 258(2020):126764. https://doi.org/10.1016/j.matlet.2019.126764
- J. Xue, F. Li, S. Li, J. Zhang, and Q. Bi. Int. J. Electrochem. Sci., 17(2022):220136. https://doi.org/10.20964/2022.01.29
- A. Phuruangrat, P. Keereesaensuk, K. Karthik, P. Dumrongrojthanath, N. Ekthammathat, S. Thongtem, and T. Thongtem. J. Inorg. Organomet. Polym. Mater., 30(2020):322–329. https://doi.org/10.1007/s10904-019-01190-4
- J. Wang, Y. Sun, Z. Wang, C. Wu, and P. Rao. Russ. J. Phys. Chem. A, 93(2019):736–742. https://doi.org/10.1134/S0036024419040307
- J. Du, I. Ahmad, I.M. Ashraf, F.B.M. Ahmed, A. Aslam, I. Ali, A. Mohammad, and M.A. Khasawneh. Inter. J. Hydro. Energy, 100(2025):1361-1384. https://doi.org/10.1016/j.ijhydene.2024.12.421
- I. Ahmad, R. Bousbih, A. Mahal, W.Q. Khan, M. Aljohani, M.A. Amin, N.N.A. Jafar, M.S. Jabir, H. Majdi, A.S. Alshomrany, M. Shaban, I. Ali, and H. Bayahia. Mater. Sci. Semicond. Process., 180(2024):108578. https://doi.org/10.1016/j.mssp.2024.108578
- H. Lee, S.H. Park, Y.K. Park, B.H. Kim, S.J. Kim, and S.C. Jung. Chem. Cent. J., 7(2013):156. https://doi.org/10.1186/1752-153X-7-156
- S. Singh, N. Parveen and H. Gupta. Environ. Technol. Innov., 12(2018):189-195. https://doi.org/10.1016/j.eti.2018.09.001
- G. Muthuraman, and T.T. Teng. J. Indust. Eng. Chem., 15(2009):841-846. https://doi.org/10.1016/j.jiec.2009.09.010
- S.S. Imam, and H.F. Babamale. Asian J. Chem. Sci., 7(2020):25-37. https://doi.org/10.9734/AJOCS/2020/v7i119013
- H. Li, W. Li, F. Wang, X. Liu, C. Ren, and X. Miao. Appl. Surf. Sci., 427(2018):1046-1053. http://dx.doi.org/10.1016/j.apsusc.2017.09.106
- I. Ahmad, S. Shukrullah, M.Y. Naz, E. Ahmed, M. Ahmad, A.J. Obaidullah, A. Alkhouri, A. Mahal, and Y.Y. Ghadi. Mater. Sci. Semicond. Process., 172(2024):108088. https://doi.org/10.1016/j.mssp.2023.10808
- L. Sawunyama, O.A. Oyewo, S.S. Makgato, M.F. Bopape, and D.C. Onwudiwe. Discover Nano, 20(2025):1. https://doi.org/10.1186/s11671-024-04178-3
- Y. Liu, F. Zhou, S. Zhan, and Y. Yang. J. Inorg. Organomet. Polym. Mater., 27(2017):1365–1375. https://doi.org/10.1007/s10904-017-0590-0
- Y. Liu, F. Zhou, S. Zhan, Y. Yang, and Y. Yin. Chem. Res. Chin. Univ., 32(2016):284-290. https://doi.org/10.1007/s40242-016-5315-3
- A. Phuruangrat, S. Buapoon, T. Bunluesak, P. Suebsom, S. Thongtem, and T. Thongtem. J. Aust. Ceram. Soc., 58(2022):71–82. https://doi.org/10.1007/s41779-021-00665-3
- V. Shanmugam, A.L. Muppudathi, S. Jayavel, and K.S. Jeyaperumal. Arabian J. Chem., 13(2020):2439–2455. https://doi.org/10.1016/j.arabjc.2018.05.009
- Z. Qin, C. Liu, J. Tan, H. Mei, W. Xue, and W. Wei. Res. Chem. Intermed., 51(2025):1491–1510. https://doi.org/10.1007/s11164-025-05503-w
- H. Pan, N. Xu, Y. Zhang, L. Liu, J. He, and H. Xie. J. Mater. Res., 40(2025):463–476. https://doi.org/10.1557/s43578-024-01510-6
- Y. Chen, X. Su, C. Yang, L. Dou, J. Zhong, and M. Li. Mater. Chem. Phys., 326(2024):129860. https://doi.org/10.1016/j.matchemphys.2024.129860
- M. Chakraborty, S. Ghosh, and V. Mahalingam. Energy Fuels, 4(2020):1507-1514. https://doi.org/10.1039/C9SE00796B
- J. Zhao, Y. Yang, W. Yu, Q. Ma, X. Dong, X. Wang, J. Wang, and G. Liu. J. Mater. Sci.: Mater. Electron., 28(2017):543–552. https://doi.org/10.1007/s10854-016-5557-3
- S. Cao, L. Li, J. Dong, B. Wang, H. Wei, M. Ji, G. Liu, J. Xia, and H. Li. J. Alloy. Compds., 1010(2025):177807. https://doi.org/10.1016/j.jallcom.2024.177807
- G. Ren, S. Liu, Z. Li, H. Bai, X. Hu, and X. Meng. Sol. RLL, 6(2022):2200154. https://doi.org/10.1002/solr.202200154
- L. Xie, J. Ma, and G. Xu. Mater. Chem. Phys., 110(2008):197–200. https://doi.org/10.1016/j.matchemphys.2008.01.035
- A.M. Cruz, and S.O. Alfaro. J. Mole. Catal. A, 320(2010):85–91. https://doi.org/10.1016/j.molcata.2010.01.008
- Q. Wang, J. Ge, W. Liu, H. Zhang, and R. Li. Catalysts, 15(2025):198. https://doi.org/10.3390/catal15030198
- Y. Miao, G. Pan, Y. Huo, and H. Li. Dyes Pigm., 99(2013):382-389. http://dx.doi.org/10.1016/j.dyepig.2013.05.005
- A. Phuruangrat, P. Dumrongrojthanath, B. Kuntalue, S. Thongtem, and T. Thontem. Mater. Lett., 196(2017):256-259. https://doi.org/10.1016/j.matlet.2017.03.073
- Z. Liu, X. Liu, C. Yu, L. Wei, and H. Ji. Sep. Purif. Technol., 247(2020):116951. https://doi.org/10.1016/j.seppur.2020.116951
- H. Qiu, S. Liu, X. Ma, Y. Li, Y. Fan, W. Li, and H. Zhou. J. Miner. Metall. Mater., 30(2023):1824 https://doi.org/10.1007/s12613-023-2656-z
- M. Wang, M. You, P. Guo, H. Tang, C. Lv, Y. Zhang, T. Zhu, and J. Han. J. Alloy. Compds., 728(2017):739-746. https://doi.org/10.1016/j.jallcom.2017.09.066
- B. Zhang, C. Fang, J. Ning, R. Dai, Y. Liu, Q. Wu, F. Zhang, W. Zhang, S. Dou, and X. Liu. Carbon Neutraliz., 2(2023):646–660. https://doi.org/10.1002/cnl2.96
- L. Yan, J. Tang, Q. Qiao, H. Cai, Y. Dong, J. Jin, Y. Xu, and H. Gao. Nanomaterials, 13(2023):214. https://doi.org/10.3390/nano13010214
- C.N. Ri, S.G. Kim, K.S. Ju, H.S. Ryo, C.H. Muna, and U.H. Kim. RSC Adv., 8(2018):5433–5440. https://doi.org/10.1039/c7ra12766a
- Y. Ma, Y. Jia, Y. Lin, and W. Shi. Dalton Trans., 48(2019)12009-12012. https://doi.org/10.1039/C9DT02028D
- D. Wang, H. Shen, L. Guo, C. Wang, F. Fu, and Y. Liang. Appl. Surf. Sci., 436(2018):536–547. https://doi.org/10.1016/j.apsusc.2017.12.002
- H. Li, X. Yu, X. Hao, Z. Zhang, Y. Wang, and J. Li. Nanomaterials, 10(2020):646. https://doi.org/10.3390/nano10040646
- X. Yang, X. Li, B. Zhang, T. Liu, and Z. Chen. ACS Sustainable Chem. Eng., 12(2024):6519−6528. https://doi.org/10.1021/acssuschemeng.3c07871
- Q. Sun, M. Ke, Y. Zhao, B. Wang, J. Zhang, and J. Sheng. Appl. Surf. Sci., 563(2021):150104. https://doi.org/10.1016/j.apsusc.2021.150104
- C. Yu, Z. Wu, R. Liu, H. He, W.g Fan, and S. Xue. J. Phys. Chem. Solids, 93(2016):7–13. http://dx.doi.org/10.1016/j.jpcs.2016.02.008
- Y. Chen, L. Wang, J. Zhong, M. Li, H. Fan, and C. Tian. Desalin. Water Treat., 235(2021):200–208. https://doi.org/10.5004/dwt.2021.27586
- X. Zhang, M. Zhang, and K. Cao. CrystEngComm, 21(2019):6208-6218. https://doi.org/10.1039/C9CE01043B
- C.Z. Jiang, X.D. Lu, Y.Q. Tan, and S. Bai. Adv. Mate. Res., 391-392(2012):1283-1286. http://dx.doi.org/10.4028/www.scientific.net/AMR.391-392.1283
- Powder Diffract. File, JCPDS-ICDD, 12 Campus Blvd., Newtown Square, PA 19073-3273, U.S.A., (2004).
- S.S. Priya, and V.A. Ferby. Ceram. Inter., 50(2024):40729-40735. https://doi.org/10.1016/j.ceramint.2024.07.114
- T.A. Jose, T. Krishnapriya, A. Jose, C.S. Rajesh, C. Joseph, and P.R. Biju. J. Alloy. Compds., 963(2023):171104. https://doi.org/10.1016/j.jallcom.2023.171104
- S. Yuan, Y. Zheng, Y. Chu, C. Xia, R. Dong, J. Xu, B. Teng, Y. Wu, and Y. He. Green Energy Environ., (2025) In Press. https://doi.org/10.1016/j.gee.2025.07.005
- S. Patil, S. Seal, Y. Guo, A. Schulte, and J. Norwood. Appl. Phys. Lett., 88(2006):243110. https://doi.org/10.1063/1.2210795
- S. Kobayashi, Y. Ikuhara, and T. Mizoguchi. Phys. Rev. B, 98(2018):134114. https://doi.org/10.1103/PhysRevB.98.134114
- V.A. Gushchina, A.G. Son, A.A. Egorova, A.A. Arkhipenko, M.A. Teplonogova, N.N. Efimov, and S.A. Kozyukhin. Russ. J. Inorg. Chem., 69(2024):940–948. 10.1134/S0036023624600928
- A. Phuruangrat, Y. Chimupala, A. Somdee, T. Thongtem, and S. Thongtem. Russ. J. Phys. Chem. A, 99(2025):808–820. https://doi.org/10.1134/S0036024425700414
- Z. Qiang, X. Liu, F. Li, T. Li, M.g Zhang, H. Singh, M. Huttul, and W. Cao. Chem. Eng. J., 403(2021):126327. https://doi.org/10.1016/j.cej.2020.126327
- J. He, W. Wang, F. Long, Z. Zou, Z. Fu, and Z. Xu. Mater. Sci. Eng. B, 177(2012):967-974. https://doi.org/10.1016/j.mseb.2012.04.018
- I.M. Pinatti, F.A. Pires, P.B. Almeida, P.F.S. Pereira, M.D. Teodoro, E. Guillamón, A.Z. Simões, J. Andrés, E. Longo, and I.L.V. Rosa. J. Lumin., 243(2022):118675. https://doi.org/10.1016/j.jlumin.2021.118675
- O.A. Oyewo, W.R. Abd-Ellatif, S.S. Makgato, H.M. Sabaa, O.E. Ogunjinmi, and S.A. Mahmoud, Discov. Mater., 5(2025):274. https://doi.org/10.1007/s43939-025-00414-4
- O.C. Olatunde, D.C. Onwudiwe, and S. Makgato, Results Chem., 17 (2025):102611. https://doi.org/10.1016/j.rechem.2025.102611
- L. Zhang, T. Xu, X. Zhao, and Y. Zhu. Appl. Catal. B, 98(2010):138-146. https://doi.org/10.1016/j.apcatb.2010.05.022
- G. Greczynski, and L. Hultman. Sci. Rep., 11(2021):11195. https://doi.org/10.1038/s41598-021-90780-9
- G. Greczynski, and L. Hultman. ChemPhysChem, 18(2017):1507-1512. https://doi.org/10.1002/cphc.201700126
- A.D. Vishwanath, J.S. Shankar, N.M. Eknath, A.A. Eknath, and K.N. Haribhau. Orient. J. Chem., 32(2016):933-940. http://dx.doi.org/10.13005/ojc/320219
- P. Kaur, Kriti, Rahul, S. Chalotra, H. Kaur, A. Kandasami, and D.P. Singh. Appl. Surf. Sci. Adv., 5(2021):100100. https://doi.org/10.1016/j.apsadv.2021.100100
- M. Agarwal, S.K. Garg, K. Asokan, D. Kanjilal, and P. Kumar. RSC Adv., 7(2017):13836–13845. DOI: 10.1039/c6ra25237k
- Q. Liu, Y. Liu, C. Li, J. Li, H. He, Y. Li, and W. Li. J. Mater. Sci.: Mater. Electron., 28(2017):4004–4013. DOI 10.1007/s10854-016-6013-0
- Z. Tian, Y. Zeng, H. Zhao, J. Yang, and H. Zhang. Catal. Commun., 177(2023):106665. https://doi.org/10.1016/j.catcom.2023.106665
- H.N. Tran, S. Park, F.T.A. Wibowo, N.V. Krishna, J.H. Kang, J.H. Seo, H. Nguyen-Phu, S.Y. Jang, and S. Cho. Adv. Sci., 7(2020):2002395. DOI: 10.1002/advs.202002395
- X. Liu, J. Gao, Y. Chen, C. Li, J. Chen, W. Qu, X. Chen, Z. Ma, and X. Tang. ChemCatChem, 10(2018):3999– 4003. https://doi.org/10.1002/cctc.201800818
- B.K.Shukla, S. Rawat, M.K. Gautam, H. Bhandari, S. Garg, and J. Singh. Molecules, 27(2022):2309. https://doi.org/10.3390/molecules27072309
- L. Cheng, L. Liu, D. Wang, F. Yang, and J. Ye. J. of CO₂ Util., 29(2019):196–204. https://doi.org/10.1016/j.jcou.2018.12.013
- X. Meng, and Z. Zhang. Appl. Surf. Sci., 392(2017):169-180. https://doi.org/10.1016/j.apsusc.2016.08.113
- N.A. Morozov, O.Yu. Sinelshchikova, N.V. Besprozvannykh, and T.P. Maslennikova. Russ. J. Inorg. Chem., 65(2020):1127–1134. DOI: 10.1134/S0036023620080124
- W. Kong, H. Jiang, X. Chen, B. Chen, H. Wang, Z. Shi, L. Chen, J. Wen, P. He, J. Wu, and J. Lin. J. Taiwan Inst. Chem. Eng., 181(2026):106515. https://doi.org/10.1016/j.jtice.2025.106515
- Y. Sun, J. Wu, T. Ma, P. Wang, C. Cui, and D. Ma, Appl. Surf. Sci., 403 (2017):141–150. http://dx.doi.org/10.1016/j.apsusc.2017.01.130
- S. Chang, F. Li, Y. Cai, and Y. Shen. Digest J. Nanomater. Biostruct., 13(2018):369-374.
- T. Chankhanittha, B. Johnson, R.J. Bushby, T. Butburee, P. Khemthong, and S. Nanan. J. Alloy. Compds., 1008(2024):176764. https://doi.org/10.1016/j.jallcom.2024.176764
- M. Xiao, M. Li, Y. Lun, Q. Pan, B. Ai, and J. Xiong. J. Nanomater., 2021(2021)8955548. https://doi.org/10.1155/2021/8955548
- Z.X. Dai, L.Y. Zhang, C.L. Ruan, Z.Q. Yun and G.H. Zheng. Digest J. Nanomater. Biostruct., 17(2022):179-191. https://doi.org/10.15251/DJNB.2022.171.179
- A. Phuruangrat, S. Buapoon, T. Bunluesak, P. Suebsom, S. Wannapop, T. Thongtem, and S. Thongtem. Solid State Sci., 128(2022):106881. https://doi.org/10.1016/j.solidstatesciences.2022.106881
- T. Zhou, D. Xu, M.g Lu, P. Wang, J. Zhu. Res. Chem. Intermed., 44(2018):6431–6444. https://doi.org/10.1007/s11164-018-3499-5
- X.Q. Feng, M. Zhou, Y. Du, J.Y. Cai, J.Y. Bi, J.Y. Wang, Y.D. Wang, and X.F. Li. Russ. J. Inorg. Chem., 70(2025):306–318. https://doi.org/10.1134/S0036023624603118
- H.T. Nguyen, V.D. Doan, T.L.H. Nguyen, A.T. Nguyen, Q.H. Tran, V.A. Tran, and V.T. Le. RSC Adv., 15(2025):6241–6259. https://doi.org/10.1039/d5ra00625b
- F. Elgharbi, F. Baragh, T. Hu, J.S.M. Quimbayo, R. Brahmi, A. Heponiemi, and M. Agunaou. Surf. Interf., 80(2026):108370. https://doi.org/10.1016/j.surfin.2025.108370
- T.K.M.P. Kumar, and S.K.A. Kumar. Photochem. Photobiol. Sci., 18(2019):148-154. https://doi.org/10.1039/C8PP00330K
- J. Li, F. Yang, Q. Zhou, R. Ren, L. Wu, and Y. Lv. J. Colloid Interf. Sci., 546(2019):139-151. https://doi.org/10.1016/j.jcis.2019.03.028
- J. Yang, H. Zhu, Y. Peng, P. Li, S. Chen, B.g Yang, and J. Zhang. Nanomaterials, 10(2020):756. http://dx.doi.org/10.3390/nano10040756
- D. Wang, Y. Zhu, J. Li, W. Yang, Y. Zhao, and G. Chen. Colloids Surf. A, 727(2025):138136. https://doi.org/10.1016/j.colsurfa.2025.138136
- A. Mancuso, S. Mottola, O. Sacco, V. Vaiano, and I.D. Marco. Nanomaterials, 13(2023):3130. https://doi.org/10.3390/nano13243130
- A.A. Rasheed-Adeleke, N.H. Seheri, O.A. Oyewo, S.S. Makgato, H. Ferjani, and D.C. Onwudiwe. Appl. Phys. A, 131(2025):857. https://doi.org/10.1007/s00339-025-08960-7
- A. Salaeh, A. Phuruangrat, A. Somdee, T. Thongtem, and S. Thongtem. Iran. J. Catal., 15(2025):152520. https://doi.org/10.57647/j.ijc.2025.1502.20
- A. Salaeh, A. Phuruangrat, A. Somdee, T. Thongtem, and S. Thongtem. Russ. J. Phys. Chem. A, 99(2025):2159–2170. https://doi.org/10.1134/S0036024425701614
- M. Tomar, C. Bosch, J. Everaert, R. Bhimpuria, A. Thapper, A. Orthaber, and K.E. Borbas. Org. Lett., 26(2024):10752−10756. https://doi.org/10.1021/acs.orglett.4c03723
10.57647/ijc.2026.1602.19