Synthesis of new CuO/La2CoFe2O7 nanocomposite, and investigation of Its photocatalytic property in removing organic dye
- Department of Chemistry, Payame Noor University, Tehran, Iran
Received: 2025-02-08
Revised: 2025-03-29
Accepted: 2025-04-26
Published in Issue 2025-05-03
Copyright (c) -1 Somaye Khammarnia, Hassan Hassani (Author)

This work is licensed under a Creative Commons Attribution 4.0 International License.
How to Cite
PDF views: 218
Abstract
Some novel CuO (x)/La2CoFe2O7 (x=0-70%) nanocomposites were synthesized using the sol-gel method. The formation of CuO (x)/La2CoFe2O7 (x=0-70%) nanocomposites was verified via various methods such as XRD, SEM, TEM, FTIR, UV-VIS, VSM, and photoluminescence. A transmission electron microscope images show spherical particles such as La2CoFe2O7 and CuO (60%)/LCoFO with average grain sizes of 30 and 20 nm, respectively. VSM images show that the coercivity and saturation magnetization of this sample are about 137.53 Oe and 95.284 emu/g.The photocatalytic activity of CuO/La2CoFe2O7 (CuO/LCoFO) nanoparticles was investigated by photodegradation under UV light irradiation and under optimized conditions of dye concentration (1.5 × 10-3 M), pH (= 6), irradiation time (50 min), and catalyst dose (7.0 g/L). Nanocomposite 60% shows the highest photocatalytic activity compared to pure LCoFO nanocomposite and other photocatalysts. A non-toxic, cheap, and highly active CuO (60%)/LCoFO nanocomposite photocatalyst was proposed to remove Methyl green (MG) and Basic fuchsin (BF) dyes under UV light irradiation.
Research Highlights
- Novel CuO (x)/La2CoFe2O7 (x=0-70100%) nanoparticles were successfully synthesized
- Novel CuO (x)/La2CoFe2O7 (x=0-70%) nanoparticles Used as a catalyst
- These nanocatalyst showed excellent photocatalytic activity
- These nanocatalyst showed excellent photocatalytic activity for in removing organic dyes
- These nanocatalyst showed excellent photocatalytic activity for in removing organic dyes
- CuO(60%)LCoFO nanocomposite showed the highest MG and BF dye removal among the synthesized nanocomposites
Keywords
- Basic fuchsin,
- Methyl green,
- Nanocomposite,
- Photocatalysts
References
- . S. Hussain, N. Farooq, A.S. Alkorbi, R. Alsaiari N.A. Alhemiary, M. Wang, G. Qiao, J Mole Liq, 362(2022) 119765-119777. https://doi.org/10.1016/j.molliq.2022.119765.
- . Nezamzadeh-Ejhieh,A. Shahriari, E, INT J PHOTOENERGY, 2011. doi:10.1155/2011/5181533.
- . Bakar Siddique, A. Shaheen, M. A. Abbas, A, Zaman,Y Bratty, M.A Najmi,A. Hanbashi, A Mustaqeem, M. Alhazmi, H.A., Rehman, Z.ur. Zoghebi, K. Hatem M.A. Amin,H.M.A, Heliyon 10 (2024) e40679. https://doi.org/10.1016/j.heliyon.2024.e40679.
- . Assad, N.a, Abbas, A, Rehman,M.F.ur. Naeem-ul-Hassan, M, RSC Adv, 14(2024), 22344–22358. DOI: 10.1039/d4ra03573a.
- . Z.Haider Ali, L. Abdulazeem, W. Alwan Kadhim, M. H. Kzar, O. J. Al-sareji, "Sci. Rep.", 14(2024) 31593. https://doi.org/10.1038/s41598-024-76090-w.
- . B. Zohra, K. Aicha , S. Fatima, B. Nourredine , D. Zoubir, Che Eng J 136(2008) 295-305. doi:10.1016/j.cej.2007.03.086.
- . J. Grzechulska , A .W. Morawski, Appl. Catal. B Environ. 36(2002) 45-51. https://doi.org/10.1016/S0926-3373(01)00275-2.
- . Seidi,F. Hedayati, K, J Nanostruct, 10 (2020) 497-508 . DOI: 10.22052/JNS.2020.03.006.
- . A. A Okab, Z. H Jabbar, B. H Graimed, A.I Alwared, Nanomedicine & Nanotechnology Open Access (NNOA) 14(2023) 1-13. DOI: 10.23880/nnoa-16000272.
- . Q. Zhou, Z. Fang, J. Li, M. Wang, Micropor. Mesopor. Mater., 202(2015) 22–35. https://doi.org/10.1016/j.micromeso.2014.09.040.
- . H. Tian, J. Ma, K. Li, J. Li, Ceram. Int. 35(2009) 1289-1292. https://doi.org/10.1016/j.ceramint.2008.05.003.
- . H. Yang, K. Zhang, R. Shi, X. Li, X. Dong, Y. Yu, J. Alloy. Compd. 413(2006) 302–306. https://doi.org/10.1016/j.jallcom.2005.06.061.
- . Yousefi, A . Nezamzadeh-Ejhieh, A. Iran.J.Catal.11(2021) 247-259..http://oiccpress.com/ijc/article/view/3600
- . S.Khammarnia, J. Saffari, M-S Ekrami-Kakhki, Journal of Color Science and Technology(JCST) 17(2023) 245-255. DOR: 20.1001.1.17358779.1402.17.3.5.8.
- . K. Varaprasad, K. Ramam, G.S.M. Reddy, R. Sadiku, RSC Adv. 4(2014) 60363–60370. DOI:10.1039/C4RA09980J.
- . J. Zhu, H. Li, L. Zhong, P. Xiao, X. Xu, X. Yang, Z. Zhao, J. Li, ACS Catal. 4(2014) 2917–2940. https://doi.org/10.1021/cs500606g.
- . Q. Yu, X. Meng, T. Wang, P. Li, L. Liu, K. Chang, G. Liu, J. Ye, Chem. Commun. 51(2015) 3630–3633. https://doi.org/10.1039/C4CC09240F.
- . Y. Qu, W. Zhou, Y. Xie, L. Jiang, J. Wang, G. Tian, Z. Ren, C. Tian, H. Fu, Chem. Commun. 49(2013) 8510–8512. http://doi.org/10.1039/C3CC43435D.
- . J. Yang, R. Hu, W. Meng, Y. Du, Chem. Commun. 2016, 52, 2620-2623. http://doi.org/10.1036/C5CC09222A.
- . K. Zhou, R. Wang, B. Xu, Y. Li, Nanotechnology 17 (2006) 3939-3943. DOI 10.1088/0957-4484/17/15/055.
- . Y. Soltanabadi, M. Jourshabani, Z. Shariatinia, Separation and Purification Technology, 202(2018) 227-241. https://doi.org/10.1016/j.seppur.2018.03.019.
- . http://pd.chem.ucl.ac.uk/pdnn/peaks/sizedet.htm
- . Satheeshkumar, M.K. Ranjith Kumar, E. Srinivas, C. Prasad, G. Meena, S.S. Pradeep, I. Suriyanarayanan, N. Sastry, D.L, J. Magn. Magn. Mater, 484 (2019) 120125. https://doi.org/10.1016/j.jmmm.2019.03.128.
- . W. Li, H. Shen, J. Xu, J. Sol-Gel Sci. Technol. 76(2015) 637–643. https://doi.org/10.1007/s10971-015-3815-0.
- . W. Fan, Z. Sun, J. Wang, J. Zhou, K. Wu, Y. Cheng, J. Power Sourc. 312(2016) 223–233. https://doi.org/10.1016/j.jpowsour.2016.02.069.
- . T. Yosuke, S. Hiromi, N. Kazuya, Mater.Res. Bull. 41(2006) 834–841. https://doi.org/10.1016/j.materresbull.2005.10.004.
- . M. Vaseem, A. Umar, S. H. Kim, Y.-B. Hahn, J. Phys. Chem. C 112(2008) 5729–5735. https://doi.org/10.1021/jp710358j.
- . L. Hou, G. Sun, K. Liu, Y. Li, F. Gao, Preparation, J. Sol-Gel Sci. Technol. 40(2006) 9–14. https://doi.org/10.1007/s10971-006-8368-9.
- . G. Kliche, Z.V. Popovic, Phys. Rev. B 42(1990) 10060-10066. https://doi.org/10.1103/PhysRevB.42.10060.
- . W. Wang, L. Xu, R. Zhang, J. Xu, F. Xian, J. Su, F.Yang, Chem. Phys. Lett. 721(2019) 57-61. https://doi.org/10.1016/j.cplett.2019.02.031
- . A.A. Samokhvalov, T. I. Arbusova, N. A. Viglin, S. V. Naumov, V. R. Galakhov, D. A. Zatsepin, Yu. A. Kotov, O. M. Samatov, D. G. Kleshchev, Physics of the Solid State 40(1998) 268–271. https://doi.org/10.1134/1.1130290.
- . W. Wang, W.Feng, J. Yuan, N. Pang, X. Zhao, M. Li, Z. Bao, K.Zhu, D. Odkhuu, Physica B: Condensed Matter 540(2018) 33-37. https://doi.org/10.1016/j.physb.2018.04.018.
- . Martı ´n-Herna´ndez, F. Ferre,E.C, J. Geophys. Res,. 112 (2007), B03105. doi:10.1029/2006JB004340.
- . S. Li, L. Jing, W. Fu, L. Yang, B. Xin, H. Fu, Mater. Res. Bull. 42(2007) 203–212. https://doi.org/10.1016/j.materresbull.2006.06.010.
- . Ma, P. Jiang, W. Wang, F. Li, F. Shen, P. Chen, M. Wang, Y. Liu, J. Li, P, J. Alloy Compd. 578 (2013) 501–506. https://doi.org/10.1016/j.jallcom.2013.07.026.
- . Zhou, Q. Fang, Z. Li, J. Wang, M, Micropor. Mesopor. Mater. 202 (2015) 22–35. https://doi.org/10.1016/j.micromeso.2014.09.040
- . R. Gusain, P. Kumar, O.P. Sharma, S.L. Jain, O.P. Khatri, Appl. Catal. B Environ., 181(2016) 352-362. https://doi.org/10.1016/j.apcatb.2015.08.012.
- . S. Khammarnia, J.Saffari, M.S. Ekrami-Kakhki, Chem Rev Lett 7(2024) 123 -133. 10.22034/CRL.2024.434922.1277.
- . S. Khammarnia, A. Akbari, J. Saffari2, M-S.Ekrami-Kakhki, J. Clust. Sci. 30(2019) 1383 -1391. https://doi.org/10.1007/s10876-019-01580-1.
- . M. H. Habibi, A. Hassanzadeh, S. Mahdavi, J.Photochem Photobiol. A Chem. 172(2005) 89-96. https://doi.org/10.1016/j.jphotochem.2004.11.009.
- . A. Akyol and M. Bayramoğlu, J. Hazard. Mater. 124(2005) 241-246. https://doi.org/10.1016/j.jhazmat.2005.05.006.
- . B. Neppolian, M. V Shankar, V. Murugesan, Semiconductor assisted photodegradation of textile dye, (2002) ISSN: 0975-1084 (Online); 0022-4456 (Print).
- . E. Bizani, K. Fytianos, I. Poulios, V. Tsiridis, J.Hazard. Mater. 136(2006) 85-94. https://doi.org/10.1016/j.jhazmat.2005.11.017.
- . A.P. Toor, A. Verma, C.K. Jotshi, P.K. Bajpai, V. Singh, Dye. Pigment. 68(2006) 53-60. https://doi.org/10.1016/j.dyepig.2004.12.009.
- . I.K. Konstantinou, T.A. Albanis, Appl. Catal. B Environ. 49(2004) 1-14. https://doi.org/10.1016/j.apcatb.2003.11.010.
- . R. Ahmad. J Hazard Mater. 171(2009) 767- 773. https://doi.org/10.1016/j.jhazmat.2009.06.060.
- . Sharafzadeh,S, Zolgharnein, J. Nezamzadeh–Ejhieh, A, Dermanaki Farahani, S. Int. J. Hydrogen Energy, 106 (2025) 1429–1442. https://doi.org/10.1016/j.ijhydene.2025.02.031.
- . G. Mishra, M. Mukhopadhyay, Sci. Rep. 9, 4345 (2019). https://doi.org/10.1038/s41598-019-40775-4.
- . Gita, S. Shukla, S.P. Deshmukhe, G. Choudhury, T.G. Saharan, N. Singh, A.K, Bull. Environ. Contam. Toxicol., 106 (2021) 302-309. https://doi.org/10.1007/s00128-020-03074-7.
- Farhadian, M. Kazemzad, M, Synth. React. Synth. React. Inorg. M., 46 (2016) 458-463. https://doi.org/10.1080/15533174.2014.988802
- . Shariati1, M., Babaei1, A. Azizi1, A, J. Mater. Res.,38(2023) 2666-2678. https://doi.org/10.1557/s43578-023-00990-2.
- . Jeevarathinam, M. Asharani, I. V, Sci. Rep. 9718 (2024). https://doi.org/10.1038/s41598-024-60008-7.
- . Mylarappa, M . Selvam,C b, Harisha K. Sanjeevappa,H.K c, Prasanna Kumar S G,P d, Krishnamurthy, G. a, Kalasad Muttanagoud, N. Results in Surfaces and Interfaces 14 (2024) 100202. https://doi.org/10.1016/j.rsurfi.2024.100202
10.57647/j.ijc.2025.1502.14
