https://doi.org/10.1007/s40090-020-00214-0

Influence of Fe dopant concentrations on physicochemical and photocatalytic properties of Bi2WO6/CeO2 nanocomposites for rhodamine B degradation

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  • Natda Wetchakun*1,
  • Khatcharin Wetchakun2,
  • Sumet Sakulsermsuk1,
  1. Program of Physics, Faculty of Science, Ubon Ratchathani Rajabhat University, Ubon Ratchathani, 34000, Thailand
  2. Department of Physics and Materials Science, Faculty of Science, Photocatalysts and 2D Materials Research Laboratory, Chiang Mai University, Chiang Mai, 50200, Thailand

Published in Issue 2023-11-17

How to Cite

Wetchakun, N., Wetchakun, K., & Sakulsermsuk, S. (2023). Influence of Fe dopant concentrations on physicochemical and photocatalytic properties of Bi2WO6/CeO2 nanocomposites for rhodamine B degradation. International Journal of Industrial Chemistry, 11(3). https://doi.org/https://doi.org/10.1007/s40090-020-00214-0
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Abstract

Fe-doped Bi2WO6/CeO2 nanocomposite materials were prepared by co-precipitation and hydrothermal methods. The physicochemical properties and photocatalytic activities of Bi2WO6/CeO2 nanocomposites after doping with Fe3+ ions were systematically investigated. The 0.2Fe-doped Bi2WO6/CeO2 nanocomposites exhibited the optimal photocatalytic activity in the degradation of rhodamine B (RhB), reaching to 62% degradation after 120 min irradiation, which was 10.3 and 2.7 times higher than CeO2 and Bi2WO6, respectively. The improved photocatalytic activity was mainly ascribed to the enhanced charge carrier separation efficiency of the direct Z-scheme heterojunction system. Moreover, the effective trapping of photogenerated electrons and holes by iron ions inhibits the electronâhole recombination. By a trapping experiment, the main radicals (O2·â) in the photocatalysis experiment were further ascertained. Finally, we proposed the photocatalytic mechanism of Fe-doped Bi2WO6/CeO2 nanocomposite for RhB degradation.

Keywords

  • Bi2WO6/CeO2,
  • Iron doping,
  • Nanocomposite,
  • Photocatalytic Activity,
  • Wastewater treatment
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