Enhancing the Performance of Butadiene Rubber and Natural Rubber Elastomers Using Green-Synthesized Carbon Quantum Dots Derived from Sugarcane Bagasse Waste
- Department of Chemistry, NT. C., Islamic Azad University, Tehran, Iran
Received: 2025-05-10
Revised: 2025-07-10
Accepted: 2025-09-29
Published in Issue 2025-12-30
Copyright (c) 2025 Arman Van, Mohamadamin Vosooghnia, Fereshteh Motiee (Author)

This work is licensed under a Creative Commons Attribution 4.0 International License.
How to Cite
PDF views: 33
Abstract
In this research work, carbon quantum dot nanoparticles derived from sugarcane bagasse were used in place of rubber industry aromatic oil and a portion of carbon black in five unique samples of the NR/BR elastomer mixture. The purpose of this research was to analyze the various mechanical, thermal, and rheological properties of the obtained mixtures. Comprehensive tests, including HR-TEM (High-Resolution Transmission Electron Microscopy), FESEM (Field Emission Scanning Electron Microscopy), DLS (Dynamic Light Scattering), and FTIR (Fourier Transform Infrared Spectroscopy), were employed to elucidate the properties of carbon quantum dots. In the following, elongation, tensile strength, abrasion resistance, rheometry, and Thermogravimetric analysis (TGA) tests were utilized to evaluate the mechanical, rheological, and thermal properties of the elastomeric mixtures. According to the collected results, among the synthesized samples, sample N3 had the most outstanding thermal, rheological, and mechanical properties. Overall, it is predicted that the interaction of carbon quantum dots with NR/BR elastomer can lead to reduced environmental risks and increased mechanical properties in the rubber industry.
Keywords
- Carbon Quantum Dots,
- Green Synthesis,
- Mechanical Properties,
- NR/BR Elastomers,
- Sugarcane Bagasse,
- Sustainable Materials,
- Thermal Stability
References
- Joshi AM. Rubbers and Elastomers in Specialty Applications. In: Specialty Polymers and Materials. Apple Academic Press; 2025:293-314.
- Fazli A, Rodrigue D. Waste rubber recycling: A review on the evolution and properties of thermoplastic elastomers. Materials (Basel). 2020;13(3):782.
- Kamankesh P, Ghayedi Z. Archive of SID . ir Archive of SID . ir Archive of SID . ir Archive of SID . ir. J Sci Eng Elit. 2023;12(47):84-92.
- Bokobza L. Natural rubber nanocomposites: A review. Nanomaterials. 2019;9(1). https://doi.org/10.3390/nano9010012
- Jovanović S, Samaržija-Jovanović S, Marković G, Jovanović V, Adamović T, Marinović-Cincović M. Ternary NR/BR/SBR rubber blend nanocomposites. J Thermoplast Compos Mater. 2018;31(2):265-287. https://doi.org/10.1177/0892705717697778
- Alipour A. Study the morphology, microstructure. In: International Conference on Nanotechnology and Biosensors IPCBEE. Vol 25. 2011:44-48.
- Bokobza L. Elastomer Nanocomposites : Effect of Filler – Matrix and Filler – Filler Interactions. Published online 2023.
- Srivastava SK, Mishra YK. Nanocarbon reinforced rubber nanocomposites: Detailed insights about mechanical, dynamical mechanical properties, payne, and mullin effects. Nanomaterials. 2018;8(11):1-56. https://doi.org/10.3390/nano8110945
- Fan Y, Fowler GD, Zhao M. The Past, Present and Future of Carbon Black as a Rubber Reinforcing Filler – A Review. Vol 247. Elsevier B.V.; 2020. https://doi.org/10.1016/j.jclepro.2019.119115
- Dwivedi C, Manjare S, Rajan SK. Recycling of waste tire by pyrolysis to recover carbon black: Alternative & environment-friendly reinforcing filler for natural rubber compounds. Compos Part B Eng. 2020;200(July):108346. ttps://doi.org/10.1016/j.compositesb.2020.108346
- Casalini R, Bogoslovov R, Qadri SB, Roland CM. Nanofiller reinforcement of elastomeric polyurea. Polymer (Guildf). 2012;53(6):1282-1287. https://doi.org/10.1016/j.polymer.2012.01.034
- Abd Razak J, Haji Ahmad S, Mohamad N, et al. Role of Nanofillers in Elastomer–Elastomer Blends. INC; 2024.https://doi.org/10.1016/B978-0-323-88655-0.00006-9
- Zhao DL, Chung TS. Applications of carbon quantum dots (CQDs) in membrane technologies: A review. Water Res. 2018;147:43-49. https://doi.org/10.1016/j.watres.2018.09.040
- Das R, Bandyopadhyay R, Pramanik P. Carbon quantum dots from natural resource: A review. Mater Today Chem. 2018;8:96-109. https://doi.org/10.1016/j.mtchem.2018.03.003
- Arumugham T, Alagumuthu M, Amimodu RG, Munusamy S, Iyer SK. A sustainable synthesis of green carbon quantum dot (CQD) from Catharanthus roseus (white flowering plant) leaves and investigation of its dual fluorescence responsive behavior in multi-ion detection and biological applications. Sustain Mater Technol. 2020;23:e00138. https://doi.org/10.1016/j.susmat.2019.e00138
- S. T, D. RS. Green synthesis of highly fluorescent carbon quantum dots from sugarcane bagasse pulp. Appl Surf Sci. 2016;390:435-443. https://doi.org/10.1016/j.apsusc.2016.08.106
- Zhou Z, Li Z, Wang J, Wu Z, Fu Y. Solvothermal synthesis of nitrogen-doped carbon quantum dots for the sensitive detection of azithromycin. Nanotechnology. 2023;34(4). https://doi.org/10.1088/1361-6528/ac9d44
- Ateia EE, Rabie O, Mohamed AT. Assessment of the correlation between optical properties and CQD preparation approaches. Eur Phys J Plus. 2024;139(1). https://doi.org/10.1140/epjp/s13360-023-04811-7
- Nizam NUM, Hanafiah MM, Mahmoudi E, Mohammad AW. Synthesis of highly fluorescent carbon quantum dots from rubber seed shells for the adsorption and photocatalytic degradation of dyes. Sci Rep. 2023;13(1):1-17. https://doi.org/10.1038/s41598-023-40069-w
- Aslan M, Eskalen H, Kavgaci M. Carbon Quantum Dot (CQD) Nanoparticles Synthesized by Sucrose and Urea: Application as Reinforcement Effect on Al–Mg–Cu–Zn Composite. Russ J Gen Chem. 2023;93(8):2152-2160. https://doi.org/10.1134/S1070363223080236
- Marouzi S, Darroudi M, Hekmat A, Sadri K, Kazemi Oskuee R. One-pot hydrothermal synthesis of carbon quantum dots from Salvia hispanica L. seeds and investigation of their biodistribution, and cytotoxicity effects. J Environ Chem Eng. 2021;9(4):105461. https://doi.org/10.1016/j.jece.2021.105461
- Huang S, Li W, Han P, et al. Carbon quantum dots: Synthesis, properties, and sensing applications as a potential clinical analytical method. Anal Methods. 2019;11(17):2240-2258. https://doi.org/10.1039/c9ay00068b
- Thongchom C, Refahati N, Saffari PR, et al. An experimental study on the effect of nanomaterials and fibers on the mechanical properties of polymer composites. Buildings. 2022;12(1). https://doi.org/10.3390/buildings12010007
- Ismail MN, Khalaf AI. Styrene–butadiene rubber/graphite powder composites: Rheometrical, physicomechanical, and morphological properties. J Appl Polym Sci. 2011;120(1):298-304.
- Srinivas J. The Synergistic effect of nanoclay / nanosilica on mechanical properties and swelling resistance of ternary rubber ( NR / SBR / NBR ) blends nanocomposites. Published online 2023:1-31.
- Zhang J, Gu Z, Meng C, Wang J, Sui J. Morphology and selected properties of NR/BR/CNT nanocomposites effect of ethanol-assisted mixing. Polimery. 2023;68(5):251-258.
- Tang LC, Zhao L, Qiang F, Wu Q, Gong LX, Peng JP. Mechanical properties of rubber nanocomposites containing carbon nanofillers. In: Carbon-Based Nanofillers and Their Rubber Nanocomposites. Elsevier; 2019:367-423.
- Azizli MJ, Mokhtary M, Khonakdar HA, Goodarzi V. Hybrid Rubber Nanocomposites Based on XNBR/EPDM: Select the Best Dispersion Type from Different Nanofillers in the Presence of a Compatibilizer. J Inorg Organomet Polym Mater. 2020;30(7):2533-2550. https://doi.org/10.1007/s10904-020-01502-z
- Srivastava SK. Thermal properties of rubber nanocomposites based on carbon nanofillers. In: Carbon-Based Nanofillers and Their Rubber Nanocomposites. Elsevier; 2019:287-324.
- Saha T, Bhowmick AK. Influence of nanofiller on thermal degradation resistance of hydrogenated nitrile butadiene rubber. Rubber Chem Technol. 2019;92(2):263-285.
- Srinivas J, Jagatheeshwaran MS, Elayaperumal A, Vishvanathperumal S. The effect of nanoclay on mechanical and swelling resistance properties of ternary rubber (NR/SBR/NBR) blends nanocomposites. Published online 2023.
- Namitha LK, Chameswary J, Ananthakumar S, Sebastian MT. Effect of micro-and nano-fillers on the properties of silicone rubber-alumina flexible microwave substrate. Ceram Int. 2013;39(6):7077-7087.
- Damircheli M, MajidiRad A. The influence of the dispersion method on the morphological, curing, and mechanical properties of NR/SBR reinforced with nano-calcium carbonate. Polymers (Basel). 2023;15(13):2963.
- Barghamadi M, Karrabi M, Ghoreishy MHR, Mohammadian-Gezaz S. Effects of two types of nanoparticles on the cure, rheological, and mechanical properties of rubber nanocomposites based on the NBR/PVC blends. J Appl Polym Sci. 2019;136(25):1-11. https://doi.org/10.1002/app.47550
10.57647/j.ijic.2025.1604.16