10.57647/j.ijic.2025.1602.10

Green Synthesis and Investigation of the Functional Behavior of Carbon Quantum Dots in Elastomeric Compounds Based on (BR/SBR)

  1. Department of Chemistry, North Tehran Branch, Islamic Azad University, Tehran, Iran

Received: 2025-03-10

Revised: 2025-05-13

Accepted: 2025-05-28

Published in Issue 2025-06-30

How to Cite

Vosooghnia, M., Motiee, F., & Van, A. (2025). Green Synthesis and Investigation of the Functional Behavior of Carbon Quantum Dots in Elastomeric Compounds Based on (BR/SBR) . International Journal of Industrial Chemistry, 16(2). https://doi.org/10.57647/j.ijic.2025.1602.10

PDF views: 104

Abstract

In this study, carbon quantum dot nanomaterials obtained from sugarcane bagasse have been used in the liquid phase in five distinct formulations as a substitute for aromatic oil and part of carbon black in BR/SBR elastomeric compounds. This research aimed to study the rheological, mechanical, and thermal properties of the compounds developed with carbon quantum dots. DLS (Dynamic Light Scattering), HR-TEM (High-Resolution Transmission Electron Microscope), FESEM (Field Emission Scanning Electron Microscope), and FTIR (Fourier Transform Infrared Spectroscopy) were used to characterize the carbon quantum dot. Also, tensile strength, wear, rheometry, and Thermogravimetric analysis (TGA) tests were used to check elastomeric compounds' mechanical, rheological, and thermal properties. Based on the obtained data, sample N3 showed the best rheological, mechanical, and thermal properties among the manufactured samples. Overall, these nanomaterials are expected to be an appropriate substitute for the aromatic oil used in the rubber industry.

Keywords

  • BR/SBR elastomeric compounds,
  • Carbon quantum dot,
  • FESEM,
  • HR-TEM,
  • Mechanical analysis,
  • Sugarcane bagasse

References

  1. Suksaeree J, Pichayakorn W, Monton C, Sakunpak A, Chusut T, Saingam W. Rubber polymers for transdermal drug delivery systems. Ind Eng Chem Res. 2014;53(2). doi:10.1021/ie403619b
  2. Schaefer R. Mechanical properties of rubber. In: Harris’ Shock and Vibration Handbook. ; 2010:6:33-1.
  3. Zhang G, Feng H, Liang K, et al. Design of next-generation cross-linking structure for elastomers toward green process and a real recycling loop. Sci Bull. 2020;65(11). doi:10.1016/j.scib.2020.03.008
  4. Basu D, Das A, Stöckelhuber KW, Wagenknecht U, Heinrich G. Advances in layered double hydroxide (LDH)-based elastomer composites. Prog Polym Sci. 2014;39(3). doi:10.1016/j.progpolymsci.2013.07.011
  5. Sivaraman R, Roseenid T, Siddanth S. Reinforcement of elastomeric rubber using carbon fiber laminates. Int J Innov Res Sci Eng Technol. 2013;2(7):3123-3130.
  6. Yang J, Li K, Tang C, et al. Recent Progress in Double Network Elastomers: One Plus One is Greater Than Two. Adv Funct Mater. 2022;32(19). doi:10.1002/adfm.202110244
  7. Jovanović S, Samaržija-Jovanović S, Marković G, Jovanović V, Adamović T, Marinović-Cincović M. Ternary NR/BR/SBR rubber blend nanocomposites. J Thermoplast Compos Mater. 2018;31(2). doi:10.1177/0892705717697778
  8. Hwang K, Lee J, Kim W, et al. Comparison of SBR/BR blend compound and ESBR copolymer having same butadiene contents. Elastomers Compos. 2019;54(1):54-60.
  9. Wu W, Chen D. Silica-modified SBR/BR blends. J Appl Polym Sci. 2011;120(6). doi:10.1002/app.33576
  10. Maurice M. Rubber Technology. Springer Science & Business Media; 2013.
  11. Malas A, Pal P, Das CK. Effect of expanded graphite and modified graphite flakes on the physical and thermo-mechanical properties of styrene butadiene rubber/polybutadiene rubber (SBR/BR) blends. Mater Des. 2014;55. doi:10.1016/j.matdes.2013.10.038
  12. Gao M, Zheng F, Xu J, et al. Surface modification of nano-sized carbon black for reinforcement of rubber. Nanotechnol Rev. 2019;8(1). doi:10.1515/ntrev-2019-0036
  13. Song K, Zhang Y, Meng J, et al. Structural polymer-based carbon nanotube composite fibers: Understanding the processing-structure-performance relationship. Materials (Basel). 2013;6(6). doi:10.3390/ma6062543
  14. Barrera CS, Cornish K. Processing and mechanical properties of natural rubber/waste-derived nano filler composites compared to macro and micro filler composites. Ind Crops Prod. 2017;107. doi:10.1016/j.indcrop.2017.05.045
  15. Fan Y, Fowler GD, Zhao M. The past, present and future of carbon black as a rubber reinforcing filler – A review. J Clean Prod. 2020;247. doi:10.1016/j.jclepro.2019.119115
  16. Lu Y, Liu J, Hou G, et al. From nano to giant? Designing carbon nanotubes for rubber reinforcement and their applications for high performance tires. Compos Sci Technol. 2016;137. doi:10.1016/j.compscitech.2016.10.020
  17. Dwivedi C, Manjare S, Rajan SK. Recycling of waste tire by pyrolysis to recover carbon black: Alternative & environment-friendly reinforcing filler for natural rubber compounds. Compos Part B Eng. 2020;200. doi:10.1016/j.compositesb.2020.108346
  18. KUMAR V. Nanofillers in Natural Rubber. Nat Rubber Mater. 2013;2: Composi(8):34.
  19. Sahakaro K. Mechanism of reinforcement using nanofillers in rubber nanocomposites. In: Progress in Rubber Nanocomposites. ; 2017. doi:10.1016/B978-0-08-100409-8.00003-6
  20. Farshbaf M, Davaran S, Rahimi F, Annabi N, Salehi R, Akbarzadeh A. Carbon quantum dots: recent progresses on synthesis, surface modification and applications. Artif Cells, Nanomedicine Biotechnol. 2018;46(7). doi:10.1080/21691401.2017.1377725
  21. Shabbir H, Csapó E, Wojnicki M. Carbon Quantum Dots: The Role of Surface Functional Groups and Proposed Mechanisms for Metal Ion Sensing. Inorganics. 2023;11(6). doi:10.3390/inorganics11060262
  22. Kim Y, Jang G, Lee TS. New Fluorescent Metal-Ion Detection Using a Paper-Based Sensor Strip Containing Tethered Rhodamine Carbon Nanodots. ACS Appl Mater Interfaces. 2015;7(28). doi:10.1021/acsami.5b04724
  23. Sun Y, Zhang M, Bhandari B, Yang C. Recent Development of Carbon Quantum Dots: Biological Toxicity, Antibacterial Properties and Application in Foods. Food Rev Int. 2022;38(7):1513-1532. doi:10.1080/87559129.2020.1818255
  24. Manikandan V, Lee NY. Green synthesis of carbon quantum dots and their environmental applications. Environ Res. 2022;212(PB):113283. doi:10.1016/j.envres.2022.113283
  25. Li X, Zhao S, Li B, Yang K, Lan M, Zeng L. Advances and perspectives in carbon dot-based fluorescent probes: Mechanism, and application. Coord Chem Rev. 2021;431. doi:10.1016/j.ccr.2020.213686
  26. Gu J, Li X, Zhou Z, et al. 2D MnO 2 nanosheets generated signal transduction with 0D carbon quantum dots: synthesis strategy, dual-mode behavior and glucose detection. Nanoscale. 2019;11(27):13058-13068.
  27. Wei JS, Ding C, Zhang P, et al. Robust Negative Electrode Materials Derived from Carbon Dots and Porous Hydrogels for High-Performance Hybrid Supercapacitors. Adv Mater. 2019;31(5). doi:10.1002/adma.201806197
  28. Messina MM, Barrionuevo SD, Coustet ME, et al. Graphene and Carbon Dots for Photoanodes with Enhanced Performance. ACS Appl Nano Mater. 2021;4(7). doi:10.1021/acsanm.1c01295
  29. Choi Y, Choi Y, Kwon OH, Kim BS. Carbon Dots: Bottom-Up Syntheses, Properties, and Light-Harvesting Applications. Chem - An Asian J. 2018;13(6). doi:10.1002/asia.201701736
  30. S. T, D. RS. Green synthesis of highly fluorescent carbon quantum dots from sugarcane bagasse pulp. Appl Surf Sci. 2016;390. doi:10.1016/j.apsusc.2016.08.106
  31. Wang Y jing, Zheng G, Shen J, Liu W, Zhu X jun. Simulation of dynamic light scattering signal for ultrafine particles based on the exponential model. Optoelectron Lett. 2010;6(4). doi:10.1007/s11801-010-9145-0
  32. Marouzi S, Darroudi M, Hekmat A, Sadri K, Kazemi Oskuee R. One-pot hydrothermal synthesis of carbon quantum dots from Salvia hispanica L. seeds and investigation of their biodistribution, and cytotoxicity effects. J Environ Chem Eng. 2021;9(4). doi:10.1016/j.jece.2021.105461
  33. Huang S, Li W, Han P, et al. Carbon quantum dots: Synthesis, properties, and sensing applications as a potential clinical analytical method. Anal Methods. 2019;11(17). doi:10.1039/c9ay00068b
  34. Arumugham T, Alagumuthu M, Amimodu RG, Munusamy S, Iyer SK. A sustainable synthesis of green carbon quantum dot (CQD) from Catharanthus roseus (white flowering plant) leaves and investigation of its dual fluorescence responsive behavior in multi-ion detection and biological applications. Sustain Mater Technol. 2020;23:e00138. doi:10.1016/j.susmat.2019.e00138
  35. Baweja H, Jeet K. Economical and green synthesis of graphene and carbon quantum dots from agricultural waste. Mater Res Express. 2019;6(8). doi:10.1088/2053-1591/ab28e5
  36. Wang RC, Lu JT, Lin YC. High-performance nitrogen doped carbon quantum dots: Facile green synthesis from waste paper and broadband photodetection by coupling with ZnO nanorods. J Alloys Compd. 2020;813. doi:10.1016/j.jallcom.2019.152201
  37. Vandarkuzhali SAA, Jeyalakshmi V, Sivaraman G, Singaravadivel S, Krishnamurthy KR, Viswanathan B. Highly fluorescent carbon dots from Pseudo-stem of banana plant: Applications as nanosensor and bio-imaging agents. Sensors Actuators, B Chem. 2017;252. doi:10.1016/j.snb.2017.06.088
  38. Tang LC, Zhao L, Qiang F, Wu Q, Gong LX, Peng JP. Mechanical properties of rubber nanocomposites containing carbon nanofillers. In: Carbon-Based Nanofillers and Their Rubber Nanocomposites: Fundamentals and Applications. ; 2019. doi:10.1016/B978-0-12-817342-8.00012-3
  39. Dhanasekar S, Baskar S, Vishvanathperumal S. Cure characteristics, compression set, swelling behaviors, abrasion resistance and mechanical properties of nanoclay (Cloisite 15A, Cloisite 20A and Cloisite 30B) filler filled EPDM/NBR blend system. J Polym Res. 2023;30(10). doi:10.1007/s10965-023-03759-7
  40. Damircheli M, MajidiRad AH. The Influence of the Dispersion Method on the Morphological, Curing, and Mechanical Properties of NR/SBR Reinforced with Nano-Calcium Carbonate. Polymers (Basel). 2023;15(13). doi:10.3390/polym15132963
  41. Poozhikunnath A, Favata J, Ahmadi B, et al. Correlative Microscopy-Based Approach for Analyzing Microscopic Impurities in Carbon Black for Lithium-Ion Battery Applications. J Electrochem Soc. 2019;166(14). doi:10.1149/2.0761914jes
  42. Hu Y, Gao Z, Yang J, Chen H, Han L. Environmentally benign conversion of waste polyethylene terephthalate to fluorescent carbon dots for “on-off-on” sensing of ferric and pyrophosphate ions. J Colloid Interface Sci. 2019;538. doi:10.1016/j.jcis.2018.12.016
  43. Bhattacharya M, Bhowmick AK. Synergy in carbon black-filled Natural rubber nanocomposites. Part I: Mechanical, dynamic mechanical properties, and morphology. J Mater Sci. 2010;45(22). doi:10.1007/s10853-010-4699-6
  44. Song J, Ma L, He Y, Yan H, Wu Z, Li W. Modified graphite filled natural rubber composites with good thermal conductivity. Chinese J Chem Eng. 2015;23(5). doi:10.1016/j.cjche.2014.05.022
  45. Sadasivuni KK, Ponnamma D, Thomas S, Grohens Y. Evolution from graphite to graphene elastomer composites. Prog Polym Sci. 2014;39(4). doi:10.1016/j.progpolymsci.2013.08.003
  46. Yang J, Tian M, Jia QX, Zhang LQ, Li XL. Influence of graphite particle size and shape on the properties of NBR. J Appl Polym Sci. 2006;102(4). doi:10.1002/app.24844
  47. Ismail MN, Khalaf AI. Styrene-butadiene rubber/graphite powder composites: Rheometrical, physicomechanical, and morphological properties. J Appl Polym Sci. 2011;120(1). doi:10.1002/app.33101
  48. Saha T, Bhowmick AK. Influence of nanofiller on thermal degradation resistance of hydrogenated nitrile butadiene rubber. Rubber Chem Technol. 2019;92(2). doi:10.5254/rct.18.82616
  49. Srivastava SK. Thermal properties of rubber nanocomposites based on carbon nanofillers. In: Carbon-Based Nanofillers and Their Rubber Nanocomposites: Fundamentals and Applications. ; 2019. doi:10.1016/B978-0-12-817342-8.00010-X
  50. Farida E, Bukit N, Ginting EM, Bukit BF. The effect of carbon black composition in natural rubber compound. Case Stud Therm Eng. 2019;16. doi:10.1016/j.csite.2019.100566
  51. Namitha LK, Chameswary J, Ananthakumar S, Sebastian MT. Effect of micro- and nano-fillers on the properties of silicone rubber-alumina flexible microwave substrate. Ceram Int. 2013;39(6). doi:10.1016/j.ceramint.2013.02.047