Synergistic Analysis of Adsorption-Desorption Characteristics Based on Pressure-Desorption Capacity: A Case Study of Xiaohuigou Coal Mine in China
- China Coal Research Institute Fushun Branch, Shenfu Demonstration Zone, Liaoning, China
- State Key Laboratory of Coal Mine Disaster Prevention and Control, China Coal Technology and Engineering Group Shenyang Research Institute, Shenfu Demonstration Zone 113122, China
- Liaoning Technical University, School of Safety Science and Engineering, Huludao, Liaoning 125100, China
- Shenyang Urban Construction University, School of Architecture and Planning, Shenyang, Liaoning 110167, China
- Liaoning University, School of Information, Shenyang, Liaoning 110136, China
Received: 2025-09-07
Accepted: 2025-11-26
Published in Issue 2025-12-31
Copyright (c) 2025 Yongming Zou, aolin Cao, Jie Kang, Yuntao Liang, Congna Hao, Linlin Ding, Fuchao Tian (Author)

This work is licensed under a Creative Commons Attribution 4.0 International License.
How to Cite
PDF views: 58
Abstract
To thoroughly reveal the intrinsic relationships among coal gas adsorption-desorption characteristics, coal structure, and oxidation activity under deep high-temperature and high-pressure conditions, and optimize gas extraction schemes for high-gas mines, we performed a study. Coal samples from the 2201 mining face of No.2 coal seam in Xiaohuigou Coal Mine, China, were selected as the research object. A series of tests were systematically conducted under experimental temperature: 30-120℃, pressure: 0.5-2.5MPa, including proximate analysis, ultimate analysis, adsorption-desorption experiments, thermogravimetric analysis (TG), and Brunauer-Emmett-Teller (BET) pore structure test. The regulatory mechanism of coal gas adsorption and desorption under the coupling effect of temperature and pressure was clarified. The response mechanism between the pore structure of coal samples and their pyrolysis characteristics was determined. An optimization method for gas extraction parameters based on "synergistic regulation of pressure and desorption capacity" was established. This technology was successfully applied to the gas control scenario of the 2201 working face. After applying this technology, the average gas concentration at the upper corner of the working face decreased to 0.40%, with the maximum concentration controlled below 0.67%. The width of the goaf oxidation zone was reduced from the original 40-50 m to 25-30 m. The pure gas extraction flow rate per borehole reached 3.77 m3/min, equivalent to the extraction effect of 580 Φ113 mm reverse drilling holes. The cumulative pure gas extraction volume reached 7.01×105 m³, which effectively guarantees the safe production during the high-intensity mining of the working face.
Keywords
- Adsorption pressure,
- Gas desorption,
- Thermogravimetric analysis (TG),
- Pore structure analysis,
- Gas extraction
References
- Wang S. M., Shen Y .J., Song S .J., et al. Changes in the Status of Coal Energy and Its Green and Low-Carbon Development Under the "Dual Carbon" Goals. Journal of China Coal Society, 2023, 48 (7): 2599-2612. DOI: https://doi.org/10.13225/j.cnki.jccs.CN23.0260
- Xuelong L, Shaojie C, Enyuan W, et al. Rockburst mechanism in coal rock with structural surface and the microseismic (MS) and electromagnetic radiation (EMR) response. Engineering Failure Analysis, 2021,124. DOI: https://doi.org/10.1016/J.ENGFAILANAL.2021.105396
- Tian F.C., Jia D.X., Chen M.Y., et al. Research Progress on the Characteristics of Spontaneous Combustion of Gas-Bearing Coal Under the Compound Disaster Environment of Goaf. Journal of China Coal Society, 2024, 49 (6): 2711-2727. DOI: https://doi.org/10.13225/j.cnki.jccs.2023.0855
- Chen L.Y., Li X.J., Shen Z.H., et al. Study on the Pore Structure and Fractal Characteristics of Outburst-Prone Coal in Northern Guizhou. China Safety Science Journal, 2020, 30 (2): 7. DOI: https://doi.org/110.16265/j.cnki.issn1003-3033.2020.02.011
- Wang L., Liu H.Q., Xie G.X., et al. Refined Characterization of Pore-Fracture Structure and Strength Deterioration Mechanism of Gas-Bearing Coal. Rock and Soil Mechanics, 2021, 42 (12): 3203-3216. DOI: https://doi.org/10.16285/j.rsm.2021.1039
- Shuang H. Q., Cui M. W., Li S. G., et al. Study on the In-situ Stress Distribution in Chenghe Mining Area and Its Influence on Gas Occurrence. Journal of Safety Science and Technology of China, 2025, 10 (21): 96-105. DOI: https://doi.org/10.11731/j.issn.1673-193x.2025.10.012
- Xu H.M.. Study on the Influence Laws of Temperature and Pressure on Gas Adsorption and Desorption of Coal Samples. Coal Mine Safety, 2014, 12 (33): 5-8. DOI: https://doi.org/10.3969/i.issn.1005-2798.2024.12.002
- Liu P., Chen W.P., Nie B.S., et al. Study on Pore Modification of Coal Mass by Broadband Ultrasonic Excitation and Its Regulation Mechanism on Gas Desorption Behavior. Journal of China Coal Society, 2025, 1 (1): 1-16. DOI: https://doi.org/10.13225/j.cnki.jccs.CQ25.0931
- Yan M., Long H., Bai Y., et al. Experimental Study on the Influence of Temperature Effect on the Adsorption and Desorption Characteristics of Coal Seam Gas. Mining Safety, 2019 , 3 (46): 6-10.
- Li Z.R., Tian F.C., Wang G., et al. Microscopic Fractal Characteristics of Spontaneous Combustion of Gas-Bearing Coal Under Different Temperatures and Adsorption Pressures. Journal of Coal Science and Technology,2025,53(5):213-232. DOI: https://doi.org/10.12438/cst.2024-0354
- Niroj Kumar Mohalik S M S K. TGA/DSC study to characterise and classify coal seams conforming to susceptibility towards spontaneous combustion. International Journal of Mining Science and Technology, 2022, 1 (32): 75-88. DOI: https://doi.org/10.1016/j.ijmst.2021.12.002
- Nevin Selcuk N S Y. Combustion behaviour of Turkish lignite in O2/N2 and O2/CO2 mixtures by using TGA-FTIR. Journal of Analytical and Applied Pyrolysis, 2011, 2 (90): 133-139. DOI: https://doi.org/10.1016/j.jaap.2010.11.003
- Li S, Tian F, Jiang W, et al. Experimental investigation on coal desorption characteristics and spontaneous combustion properties evolution under the coupled effect of temperature and pressure[J]. Fuel, 2023, 351 (000): 11. DOI: https://doi.org/10.1016/j.fuel.2023.128829
- Zhou X.Q.. Effects of Degassing Temperature and Particle Size on Pore Structure and Adsorption Properties of Coals with Different Metamorphic Degrees. Jiaozuo: Henan Polytechnic University, 2023. DOI: https://doi.org/10.27116/d.cnki.gjzgc.2023.001030
- Zhou Y.. Study on the Main Controlling Factors of Coal Reservoir Pores and the Relationship with Gas-Bearing Property in Typical Mining Areas of Medium-Rank Coal in Liupanshui and High-Rank Coal in Bijie. Guiyang: Guizhou University, 2024. DOI: https://doi.org/10.27047/d.cnki.ggudu.2024.001532
- Li X.J., Shen Z.H., Li W.W., et al. Exploration and Development Potential of Shale Gas in the Niutitang Formation, Fenggang Area, Northern Guizhou. Natural Gas Industry, 2016, 36 (12): 72-79. DOI: https://doi.org/10.3787/j.issn.1000-0976.2016.12.010
- Tian F.C., Li Z.R., Li S.K., et al. Study on the Evolutionary Characteristics of Desorption and Spontaneous Combustion of Gas-Bearing Coal Under High Temperature and High Pressure Conditions. Coal Science & Technology (0253-2336), 2024, 52 (7): 101-113. DOI: https://doi.org/10.12438/cst.2023-1046
- Li F, Jiang B, Cheng G, et al. Methane Adsorption Behavior and Energy Variations of Brittle Tectonically Deformed Coal under High Temperature and High Pressure. ACS omega, 2022, 7 (3): 2737-2751. DOI: https://doi.org/10.1021/acsomega.1c05383
- Yang Y, Yu K, Ju Y, et al. Investigation on the Structure and Fractal Characteristics of Nanopores in High-Rank Coal: Implications for the Methane Adsorption Capacity. Journal of nanoscience and nanotechnology, 2021, 21 (1): 392-404. DOI: https://doi.org/10.1166/jnn.2021.18513
- Ma S, Wang Z, Wang L, et al. Inhibition mechanism and diffusion model of gas desorption in cylindrical coal core during frozen coring: Experimental simulation and validation[J]. Fuel, 2025,400:135779. DOI: https://doi.org/10.1016/J.FUEL.2025.135779
- Fu X, Liu X, Wu Q, et al. Characterization of Coal Particle Methane Desorption and Optimization of Desorption Model Based on Desorption Damage. ACS omega, 2024, 9 (8): 9170-9184. DOI: https://doi.org/10.1166/jnn.2021.18513
- Jia T, Liu C, Wei G, et al. Micro-Nanostructure of Coal and Adsorption-Diffusion Characteristics of Methane. Journal of nanoscience and nanotechnology, 2021, 21 (1): 422-430. DOI: https://doi.org/10.1166/jnn.2021.18733
- Ma S J, Wang Z F, Ren H Y, et al. Study on gas adsorption process of coal at low and variable temperature. China Safety Science Journal, 2019,29(10):124-129. DOI: https://doi.org/10.16265/j.cnki.issn1003-3033.2019.10.019
- Lei Shi Q L X G. Pyrolysis behavior and bonding information of coal — A TGA stud. Fuel Processing Technology, 2013, 1 (108): 125-132. DOI: https://doi.org/10.1016/j.fuproc.2012.06.023
- Li X, Zhao D, Li X, et al. Heat-dependent properties of methane diffusion in coal: an experimental study and mechanistic analysis. Environmental science and pollution research international, 2024, 31 (44): 56153-56173. DOI: https://doi.org/10.1016/j.fuproc.2012.06.023
- Krishna Kant Dwivedi E P S M K. A comparative study on pyrolysis characteristics of bituminous coal and low-rank coal using thermogravimetric analysis (TGA). International Journal of Coal Preparation and Utilization, 2019, 1 (42): 1-11. DOI: https://doi.org/10.1080/19392699.2019.1566130
- Wu Y.L., Ma J.W., Zhang W.L., et al. Study on the Characterization of Pore Structure of Tectonically Deformed Coal with Different Damage Types and Its Influence on Gas Desorption and Diffusion. Coal Science and Technology, 2025, 5 (46): 46-52. DOI: https://doi.org/10.19896/j.cnki.mtki.2025.05.009
- P S, A L, M L, et al. Mineralogical influence of mining intrusions in CFB combustion of Indian lignite. International Journal of Energy and Environmental Engineering, 2013, 4 (34): 1-11. DOI: https://doi.org/10.1007/s40095-019-00331-2
- Jin Y., Li D., Liu Y., et al. Study on Pyrolysis and Oxidation Characteristics of Coal Gangue Based on TGA-DSC. ACS omega, 2024, 9 (12): 14174-14186. DOI: https://doi.org/10.1021/acsomega.3c09743
- Cheng Y.P., Jiang J.Y.. Study on the Influence of Magmatic Rock Intrusion on the Micropore Characteristics of Coal Reservoirs in Huaibei Mining Area. Journal of China Coal Society, 2012, 4 (37): 634-640. DOI: https://doi.org/10.13225/j.cnki.jccs.2012.04.027
- Yuan A., Wang R., Yang X., et al. Integrated pore structure analysis and methane adsorption and desorption investigation in deep multi seam coal systems. Scientific reports, 2025, 15 (1): 34102. DOI: https://doi.org/10.1038/s41598-025-19347-2
- Shumin L, Haitao S, Dongming Z, et al. Experimental study of effect of liquid nitrogen cold soaking on coal pore structure and fractal characteristics[J]. Energy, 2023,275. DOI: https://doi.org/10.1016/J.ENERGY.2023.127470
- Gao M.. Gas Disaster Control and Ventilation System Design in Coal Mines. Energy and Energy Conservation, 2025, 1 (5): 75-78. DOI: https://doi.org/10.16643/j.cnki.14-1360/td.2025.05.067
10.57647/ijeee.2025.1603.13
