OICC Press Journal of Nanostructure in Chemistry 2193-8865 11 4 (December 2021) 2021 02 09 Mechanical activation of TiO2/Fe2O3 nanocomposite for arsenic adsorption: effect of ball-to-powder ratio and milling time 10.1007/s40097-021-00388-8 EN Mercyrani Babudurai Nanoscience and Nanotechnology Program, Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional (CINVESTAV-IPN), Ciudad de México, 07360, MX Onyekachi Nwakanma Department of Electrical Engineering (SEES), Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional (CINVESTAV-IPN), Ciudad de México, 07360, MX Araceli Romero-Nuñez Department of Electrical Engineering (SEES), Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional (CINVESTAV-IPN), Ciudad de México, 07360, MX Ravichandran Manisekaran Laboratorio de Investigación Interdisciplinaria, Área de Nanoestructuras y Biomateriales, Escuela Nacional de Estudios Superiores Unidad León; Universidad Nacional Autónoma de México, León, Guanajuato, MX Velumani Subramaniam Nanoscience and Nanotechnology Program, Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional (CINVESTAV-IPN), Ciudad de México, 07360, MX Department of Electrical Engineering (SEES), Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional (CINVESTAV-IPN), Ciudad de México, 07360, MX Homero Castaneda Department of Materials Science and Engineering, Texas A&M University, College Station, TX, 77843, US Anish Jantrania Department of Biological and Agricultural Engineering, Agrilife Extension, Texas A&M University, College Station, TX, 77843, US Journal Article 2021 02 09 Abstract Arsenic contamination and its removal from the ground or natural water become an inevitable research line as it is highly carcinogenic and toxic. In the last few decades, nanotechnology has been achieved to provide accessible clean water for all living organisms. In this work, the various ratios of TiO 2 /γ-Fe 2 O 3 nanocomposite (T/M NCs) synthesized using the ball-milling route serve as nano-adsorbent for removing arsenic species. This study presents a non-toxic, low-cost, and easily accessible method for synthesizing NCs in large quantities for adsorption, offering promising results for arsenic removal from water. The ball-milling synthesis provides a comparatively, cost-effective strategy and for modulating the properties of nanostructured materials. The milling time and ball-to-powder ratio variations allow modifying the T/M NCs properties during the synthesis. The structural, morphological, and optical characterizations using X-ray diffraction, high-resolution electron microscopy, and UV–Vis analysis showed the formation of predominantly spherical-shaped anatase TiO 2 and cubic γ-Fe 2 O 3 with varying bandgap between 2.06 and 2.14 eV, which changes because of the nanomaterial phase transformation during the milling process. Elemental compositional analysis using EDS showed the uniform distribution of Ti and Fe atoms. The vibrational modes observed using Raman spectroscopy confirmed the presence of anatase TiO 2 and γ-Fe 2 O 3 within the NCs and showed the associated variations with changes in synthesis parameters. X-ray photoelectron spectroscopy analysis of the synthesized ratios indicated a variation in the binding energy (ΔBE) and the evidence of charge transfer in between TiO 2 and γ-Fe 2 O 3 NCs. The adsorption studies using the various T/M NCs ratios show varying performances. The enhanced performances obtained for the NC of anatase TiO 2 and γ-Fe 2 O 3 with the most intense phase peak ratio ( I (101) / I (311) ) of 1.2 and above shows decreased adsorption efficiency with the phase changes into rutile TiO 2 , hematite, and pseudorutile phases. The elimination of As(III) and As(V) using the synthesized NCs confirms that the ball milling technique can produce nanomaterials with desirable properties for adsorption purposes. Graphic abstract The effect of BPR and milling time on TiO 2 /γ-Fe 2 O 3 nanocomposite (T/M NCs) and its impact on Arsenic adsorption.