<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE ArticleSet PUBLIC "-//NLM//DTD PubMed 2.7//EN" "https://dtd.nlm.nih.gov/ncbi/pubmed/in/PubMed.dtd">
<ArticleSet>
<Article>
<Journal>
<PublisherName>OICC Press</PublisherName>
<JournalTitle>Journal of Nanostructure in Chemistry</JournalTitle>
<Issn>2193-8865</Issn>
<Volume>9</Volume>
<Issue>4 (December 2019)</Issue>
<PubDate PubStatus="epublish">
<Year>2019</Year>
<Month>10</Month>
<Day>23</Day>
</PubDate>
</Journal>
<ArticleTitle>Improvement of dyes removal from aqueous solution by Nanosized cobalt ferrite treated with humic acid during coprecipitation</ArticleTitle>
<VernacularTitle></VernacularTitle>
<FirstPage></FirstPage>
<LastPage></LastPage>
<ELocationID EIdType="doi">10.1007/s40097-019-00318-9</ELocationID>
<Language>EN</Language>
<AuthorList>
<Author>
<FirstName>Shaimaa M.</FirstName>
<LastName>Ibrahim</LastName>
<Affiliation>Chemistry Department, Faculty of Education, Ain Shams University, Cairo, EG</Affiliation>
<Identifier Source="ORCID"></Identifier>
</Author>
<Author>
<FirstName>Abdelrahman A.</FirstName>
<LastName>Badawy</LastName>
<Affiliation>Physical Chemistry Department, National Research Centre, Cairo, 12622, EG</Affiliation>
<Identifier Source="ORCID"></Identifier>
</Author>
<Author>
<FirstName>Hisham A.</FirstName>
<LastName>Essawy</LastName>
<Affiliation>Department of Polymers and Pigments, National Research Centre, Cairo, 12622, EG</Affiliation>
<Identifier Source="ORCID"></Identifier>
</Author>
</AuthorList>
<PublicationType>Journal Article</PublicationType>
<History>
<PubDate PubStatus="received">
<Year>2019</Year>
<Month>10</Month>
<Day>23</Day>
</PubDate>
</History>
<Abstract>Abstract
Highly effective novel adsorbent [CoFe
2
O
4
-humic acid(HA)] was synthesized by co-precipitation technique at pH 6 (H6) and pH 8 (H8). XRD, 
S
BET
 and Zeta-potential measurements were used to study the physicochemical properties of the prepared nanoparticles. XRD results showed that the chemical treatment of CoFe
2
O
4
 by HA causes the appearance of carbon as new active sites for adsorption process. Batch adsorption tests were achieved to eliminate anionic remazole-red (RR-133) and cationic methylene blue (MB) dyes. The obtained data showed that H6 and H8 solids calcined at 300 and 500 °C have higher adsorption rate for removing of dye than unmodified cobalt iron mixed oxide. The removal reached 100% after a period of dye contact time 2 min and 30 min for RR and MB, respectively. The uptake of RR and MB was much affected by the pH of dye solution. The pseudo-second-order kinetic model was the most fitted well and the adsorption process followed the Langmuir isotherm model. The adsorption of dye on adsorbent was chemisorption process. The as-prepared adsorbents can be regenerated and reused four times for both dyes. The efficiency of the prepared nano-samples and durability as adsorbent were accomplished.
Graphic abstract
</Abstract>
<ObjectList>
<Object Type="keyword">
<Param Name="value">Remazole-red</Param>
</Object>
<Object Type="keyword">
<Param Name="value">Methylene blue</Param>
</Object>
<Object Type="keyword">
<Param Name="value">CoFe2O4</Param>
</Object>
<Object Type="keyword">
<Param Name="value">Humic acid</Param>
</Object>
<Object Type="keyword">
<Param Name="value">Nanomaterials</Param>
</Object>
</ObjectList>
</Article>
</ArticleSet>