Ru-functionalized Ni-doped dual phases of α/γ-Fe2O3 nanosheets for an optimized acetone detection
Copyright (c) 2025 Ruonan Tian, Zeyuan Gao, Ruifeng Lang, Na Li, Huilin Gu, Gang Chen, Hongtao Guan, Elisabetta Comini, Chengjun Dong (Author)

This work is licensed under a Creative Commons Attribution 4.0 International License.
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Abstract
Abstract
Lately novel strategies to enhance the sensing properties on iron oxide have been proposed to achieve high performance gas sensors for acetone detection. In this working report, the synthesis of iron-glycerate (Fe-Gly) using glycerol to combine with Fe
3+
is first presented. Depending on the thermal treatment, this compound can evolve into γ-Fe
2
O
3
, α/γ-Fe
2
O
3
and α-Fe
2
O
3
. α/γ-Fe
2
O
3
shows better sensing performance as far as acetone detection is concerned. Using the dual phases of α/γ-Fe
2
O
3
as a fundamental building block, their sensing properties were further improved using Ni doping and Ru nanoparticles functionalization. The high response and selectivity to acetone detection was ascribed to the synergistic effects of unique nanosheets, mixed phases, rich oxygen vacancies and excellent catalytic activity of Ru nanoparticles.
Graphical abstract
Keywords
- Fe2O3,
- Dual phases,
- Nanosheets,
- Gas sensor,
- Acetone detection
References
- Amiri et al. (2020) Nanostructured metal oxide-based acetone gas sensors: a review https://doi.org/10.3390/s20113096
- Baharuddin et al. (2019) Advances in chemiresistive sensors for acetone gas detection https://doi.org/10.1016/j.mssp.2019.104616
- Broza et al. (2018) Synergy between nanomaterials and volatile organic compounds for non-invasive medical evaluation (pp. 4781-4859) https://doi.org/10.1039/C8CS00317C
- Zhou et al. (2020) Nanomaterial-based gas sensors used for breath diagnosis (pp. 3231-3248) https://doi.org/10.1039/C9TB02518A
- Li et al. (2019) Advances in designs and mechanisms of semiconducting metal oxide nanostructures for high-precision gas sensors operated at room temperature (pp. 470-506) https://doi.org/10.1039/C8MH01365A
- Walker et al. (2019) Synergistic effects in gas sensing semiconducting oxide nano-heterostructures: a review (pp. 624-640) https://doi.org/10.1016/j.snb.2019.01.049
- Yang et al. (2018) A simple gas sensor based on zinc ferrite hollow spheres: highly sensitivity, excellent selectivity and long-term stability (pp. 34-40) https://doi.org/10.1016/j.snb.2018.10.056
- Xiong et al. (2021) Confined synthesis of 2D ultrathin ZnO/Co3O4 nanomeshes heterostructure for superior triethylamine detection at low temperature https://doi.org/10.1016/j.snb.2021.130486
- Siebert et al. (2020) Facile fabrication of semiconducting oxide nanostructures by direct ink writing of readily available metal microparticles and their application as low power acetone gas sensors https://doi.org/10.1016/j.nanoen.2019.104420
- Xue and Wang (2020) A review of the α-Fe2O3 (hematite) nanotube structure: recent advances in synthesis, characterization, and applications (pp. 10912-10932) https://doi.org/10.1039/D0NR02705G
- Song et al. (2019) 3D α-Fe2O3 nanorods arrays@graphene oxide nanosheets as sensing materials for improved gas sensitivity (pp. 1331-1340) https://doi.org/10.1016/j.cej.2019.03.254
- Wu et al. (2019) Ultrafast response/recovery and high selectivity of the H2S gas sensor based on α-Fe2O3 nano-ellipsoids from one-step hydrothermal synthesis (pp. 12761-12769) https://doi.org/10.1021/acsami.8b22517
- Wang et al. (2017) Ionic liquid-assisted synthesis of α-Fe2O3 mesoporous nanorod arrays and their excellent trimethylamine gas-sensing properties for monitoring fish freshness (pp. 19846-19856) https://doi.org/10.1039/C7TA06392J
- Teng et al. (2020) A spendable gas sensor with higher sensitivity and lowest detection limit towards H2S: porous α-Fe2O3 hierarchical tubule derived from poplar branch https://doi.org/10.1016/j.cej.2019.123679
- Song et al. (2020) Nanosheet-assembled, hollowed-out hierarchical γ-Fe2O3 microrods for high-performance gas sensing (pp. 3754-3762) https://doi.org/10.1039/C9TA12052A
- Zahmouli et al. (2020) High performance Gd-doped γ-Fe2O3 based acetone sensor https://doi.org/10.1016/j.mssp.2020.105154
- Zhang et al. (2020) Highly sensitive H2S sensors based on metal-organic framework driven γ-Fe2O3 on reduced graphene oxide composites at room temperature https://doi.org/10.1016/j.snb.2020.128804
- Ghosh et al. (2017) ZnO/γ-Fe2O3 charge transfer interface toward highly selective H2S sensing at a low operating temperature of 30 °C (pp. 1831-1838) https://doi.org/10.1021/acssensors.7b00636
- Wang et al. (2011) CO2-assisted template synthesis of porous hollow bi-phase γ-/α-Fe2O3 nanoparticles with high sensor property (pp. 17776-17782) https://doi.org/10.1039/c1jm12879e
- Zhao et al. (2015) From solid-state metal alkoxides to nanostructured oxides: a precursor-directed synthetic route to functional inorganic nanomaterials (pp. 198-212) https://doi.org/10.1039/C4QI00191E
- Dong et al. (2019) A review on WO3 based gas sensors: morphology control and enhanced sensing properties https://doi.org/10.1016/j.jallcom.2019.153194
- Wang et al. (2020) Oxygen vacancy defects engineering on Ce-doped α-Fe2O3 gas sensor for reducing gases https://doi.org/10.1016/j.snb.2019.127165
- Wu et al. (2017) Preparation of electrospun Cu-doped α-Fe2O3 semiconductor nanofibers for NO2 gas sensor (pp. S535-S540) https://doi.org/10.1016/j.ceramint.2017.05.285
- Mao et al. (2020) Highly improved ethanol gas response of n-type α-Fe2O3 bunched nanowires sensor with high-valence donor-doping https://doi.org/10.1016/j.jallcom.2020.154248
- Wang et al. (2020) Advances in doped ZnO nanostructures for gas sensor (pp. 1553-1567) https://doi.org/10.1002/tcr.202000088
- Zhang et al. (2021) Hierarchical flower-like NiFe2O4 with core–shell structure for excellent toluene detection (pp. 1578-1587) https://doi.org/10.1007/s12598-020-01547-6
- Zhang et al. (2020) ZnO-decorated In/Ga oxide nanotubes derived from bimetallic In/Ga MOFs for fast acetone detection with high sensitivity and selectivity (pp. 26161-26169) https://doi.org/10.1021/acsami.0c04580
- Wang et al. (2019) Homophase structure for promoting electron transfer in gas-sensing https://doi.org/10.1016/j.snb.2019.126940
- Li et al. (2021) Iron doped cobalt fluoride derived from CoFe layered double hydroxide for efficient oxygen evolution reaction https://doi.org/10.1016/j.cej.2021.130686
- Zhang et al. (2019) MOFs-derived NiFe2O4 fusiformis with highly selective response to xylene (pp. 102-110) https://doi.org/10.1016/j.jallcom.2018.12.389
- Sahm et al. (2006) Basics of oxygen and SnO2 interaction; work function change and conductivity measurements (pp. 78-83) https://doi.org/10.1016/j.snb.2006.04.004
- Liu et al. (2020) Synergistically boosting oxygen evolution reaction of Fe-MOF by Ni doping and fluorination (pp. 7889-7892) https://doi.org/10.1039/D0CC03422C
- Zhao et al. (2019) Ru octahedral nanocrystals with a face-centered cubic structure, 111 facets, thermal stability up to 400 °C, and enhanced catalytic activity (pp. 7028-7036) https://doi.org/10.1021/jacs.9b01640
- Tong et al. (2015) High-quality elliptical iron glycolate nanosheets: selective synthesis and chemical conversion into FexOy nanorings, porous nanosheets, and nanochains with enhanced visible-light photocatalytic activity (pp. 16493-16503) https://doi.org/10.1039/C5NR03689E
- Sun et al. (2020) High-temperature gas sensor based on novel Pt single atoms@SnO2 nanorods@SiC nanosheets multi-heterojunctions (pp. 21808-21817) https://doi.org/10.1021/acsami.0c02160
- Zhang et al. (2019) An acetone gas sensor based on nanosized Pt-loaded Fe2O3 nanocubes (pp. 59-67) https://doi.org/10.1016/j.snb.2019.03.082
- Wang et al. (2021) In-situ generated TiO2/α-Fe2O3 heterojunction arrays for batch manufacturing of conductometric acetone gas sensors https://doi.org/10.1016/j.snb.2021.129926
- Yang et al. (2020) Optimization and gas sensing properties of Au nanoparticle modified α-Fe2O3 nanodisk structures for highly sensitive acetone detection (pp. 16174-16184) https://doi.org/10.1039/D0NJ03111A
- Yang et al. (2019) Enhanced selective acetone-sensing performance of hierarchical hollow SnO2/α-Fe2O3 microcubes (pp. 11984-11990) https://doi.org/10.1039/C9TC03879E
- Jia et al. (2019) Preparation and enhanced acetone sensing properties of flower-like α-Fe2O3/multi-walled carbon nanotube nanocomposites https://doi.org/10.1016/j.snb.2019.127012
- Kim and Lee (2014) Highly sensitive and selective gas sensors using p-type oxide semiconductors: overview (pp. 607-627) https://doi.org/10.1016/j.snb.2013.11.005
- Hübner et al. (2011) Influence of humidity on CO sensing with p-type CuO thick film gas sensors (pp. 347-353) https://doi.org/10.1016/j.snb.2010.10.046
- Ge et al. (2020) Ultrafast response and high selectivity toward acetone vapor using hierarchical structured TiO2 nanosheets (pp. 13200-13207) https://doi.org/10.1021/acsami.9b23181
- Peng et al. (2020) Acetone sensing with parts-per-billion limit of detection using a BiFeO3-based solid solution sensor at the morphotropic phase boundary https://doi.org/10.1016/j.snb.2020.128060
- Zhang et al. (2017) Controllable biomolecule-assisted synthesis and gas sensing properties of In2O3 micro/nanostructures with double phases (pp. 270-278) https://doi.org/10.1016/j.snb.2016.08.024
- Hu et al. (2014) Novel mixed phase SnO2 nanorods assembled with SnO2 nanocrystals for enhancing gas-sensing performance toward isopropanol gas (pp. 9832-9840) https://doi.org/10.1021/jp501550w
- Lin et al. (2017) The effect of Ni doping concentration on the gas sensing properties of Ni doped SnO2 (pp. 501-510) https://doi.org/10.1016/j.snb.2016.08.053
- Bai et al. (2020) Role of nickel dopant on gas response and selectivity of electrospun indium oxide nanotubes (pp. 447-457) https://doi.org/10.1016/j.jcis.2019.10.090
- Li et al. (2018) Modified impregnation synthesis of Ru-loaded WO3 nanoparticles for acetone sensing (pp. 249-256) https://doi.org/10.1016/j.snb.2018.03.037
- Wang et al. (2018) Oxygen vacancy-rich, Ru-doped In2O3 ultrathin nanosheets for efficient detection of xylene at low temperature (pp. 4156-4162) https://doi.org/10.1039/C8TC00638E
10.1007/s40097-022-00475-4