TY - EJOUR
AU - Samadi, Shakiba
AU - Shafiei, Hadi
AU - Soudbar, Davoud
AU - Fathinejad, Hassan
PY - 2023
DA - December
TI - Silver supported on mesoporous silica combination with H2O2: active, recyclable, and selective oxidation component for conversion of olefines to 1, 2-diols
T2 - Iranian Journal of Catalysis
VL - 12
L1 - https://oiccpress.com/iranian-journal-of-catalysis/article/silver-supported-on-mesoporous-silica-combination-with-h2o2-active-recyclable-and-selective-oxidation-component-for-conversion-of-olefines-to-1-2-diols/
DO - 10.30495/ijc.2022.1960932.1943
N2 - The selective oxidation of olefins is a key academic and industrial research challenge. Herein, silver was supported on mesoporous silica through a facile synthesis procedure, and characterized using various technics such as FT-IR, XRD, SEM, BET, and EDX. This efficient separable agent alongside aqueous H2O2 was applied to the oxidation of various olefines (1-octen, 1-hexene, cyclohexene, cyclooctene, styrene, and 1, 2-diphenylmethane) to 1, 2-diol under mild reaction conditions (65 ℃) with high conversion and excellent selectivity. The promoter exhibited excellent reusability and stability in the reaction medium.   Highlights Synthesis of new catalyst: Mesoporous silica based silver/H2O2 Selective oxidation of alkenes Recovery of catalyst Efficient catalyst for selective oxidation of olefins to 1,2-diols 
IS - 4
PB - OICC Press
KW - Mesoporous silica, Silver, Selective oxidation, 2-diol, Nanocomposite 
EN -