TY - EJOUR
AU - Hajipour, Abdol
AU - Abrishami, Fatemeh
PY - 2024
DA - February
TI - Application of dimeric ortho-palladated complex of 2-methoxyphenethylamine in the Heck coupling reaction
T2 - Iranian Journal of Catalysis
VL - 2
L1 - https://oiccpress.com/iranian-journal-of-catalysis/article/application-of-dimeric-ortho-palladated-complex-of-2-methoxyphenethylamine-in-the-heck-coupling-reaction/
N2 - The application of the [Pd{C6H3(CH2CH2NH2)-4-OMe-5-κ2-C,N}(μ-Br)]2 complex of 2-methoxyphenethylamine in the Heck coupling reaction was considered under both conventional and microwave irradiation conditions, and their results were compared. This complex is an efficient, stable and non-sensitive to air and moisture catalyst for the vinylation of substituted aryl halides with different electronic properties. The cross-coupled products were produced in good to excellent yields using a catalytic amount of this complex in N-methyl-2-pyrrolidone (NMP) at 130 °C. In comparison to conventional heating conditions, the reactions under microwave irradiation gave higher yields in shorter reaction times.
IS - 3
PB - OICC Press
KW - Catalyst, Microwave irradiation, Heck reaction, 2-Methoxyphenethylamine, Cyclopalladated complex 
EN -