TY - EJOUR
AU - Hosseini, Fatemeh Niroomand
PY - 2024
DA - February
TI - Thermodynamic study of an effective catalytic system, hydrogen peroxide and methyltrioxorhenium
T2 - Iranian Journal of Catalysis
VL - 4
L1 - https://oiccpress.com/iranian-journal-of-catalysis/article/thermodynamic-study-of-an-effective-catalytic-system-hydrogen-peroxide-and-methyltrioxorhenium/
N2 - The thermodynamic of the known and very effective catalytic system, hydrogen peroxide (H2O2) and methyltrioxorhenium (MTO) is studied in different solvents using UV-Visible spectroscopic method. The thermodynamic parameters (ΔG, ΔH and ΔS) for two equilibrium reactions, MTO + H2O2 ⇌ A + H2O and A + H2O2 ⇌ B.H2O (A, [MeRe(O)2(O2)]; B.H2O, [MeRe(OH2)(O)(O2)2]), are determined. The obtained free energies of the reactions depend on dielectric constants of solvent, which are explained by Onsager’s reaction field theory.
IS - 3
PB - OICC Press
KW - hydrogen peroxide, Methyltrioxorhenium, Thermodynamic study 
EN -