TY - EJOUR AU - Ahmad, Nur AU - Yuliasari, Nova AU - Arsyad, Fitri Suryani AU - Royani, Idha AU - Mohadi, Risfidian AU - Lesbani, Aldes PY - 2023 DA - November TI - Catalytic oxidative desulfurization of dibenzothiophene by heterogeneous M2+/Al-layered double hydroxide (M2+ = Zn, Mg, Ni) modified zinc oxide T2 - Iranian Journal of Catalysis VL - 13 L1 - https://oiccpress.com/iranian-journal-of-catalysis/article/catalytic-oxidative-desulfurization-of-dibenzothiophene-by-heterogeneous-m2-al-layered-double-hydroxide-m2-zn-mg-ni-modified-zinc-oxide-2/ DO - 10.30495/ijc.2023.1972458.1973 N2 - In this study, the preparation of layered double hydroxide-metal oxide (ZnAl-ZnO, MgAl-ZnO, and NiAl-ZnO) was successful. The characterization of the catalyst used XRD, FTIR, and SEM analysis. The catalyst shows high oxidative desulfurization of dibenzothiophene. The percentage conversion of dibenzothiophene on ZnAl-ZnO, MgAl-ZnO, and NiAl-ZnO was 99.38%, 99.34%, and 99.90%, respectively. The acidities of ZnAl-ZnO, MgAl-ZnO, and NiAl-ZnO were 0.798, 2.469, and 0.184 mmol/g, respectively. The catalysts are heterogeneous systems, and the advantage is that they can be used for reusability. After 3 cycles of catalytic reactions at 323 K for 30 min, reusability proves that the percentage conversion of dibenzothiophene on ZnAl-ZnO, MgAl-ZnO, and NiAl-ZnO had a stable structure. Highlights Preparation of layered double hydroxide modified zinc oxide (LDH-ZnO) was successful The catalysts shows high oxidative desulfurization of dibenzothiophene The percentage conversion of dibenzothiophene on ZnAl-ZnO, MgAl-ZnO, and NiAl-ZnO was 99.38%, 99.34%, and 99.90%, respectively The catalysts are heterogeneous systems, and the advantage is that they can be used for reusability IS - 1 PB - OICC Press KW - Dibenzothiophene, Heterogeneous catalyst, Layered Double Hydroxide, Oxidative desulfurization, Reusability. EN -