@article{Shafe-Mehrabadi_Sadeghi_Mosslemin_Hashemian_2023, title={Nano-cellulose-OSnCl4-x: Green and natural-based renewable nanocatalyst for one-pot synthesis of 2-amino-3-phenylsulfonyl-4H-pyran derivatives}, volume={12}, url={https://oiccpress.com/iranian-journal-of-catalysis/article/nano-cellulose-osncl4-x-green-and-natural-based-renewable-nanocatalyst-for-one-pot-synthesis-of-2-amino-3-phenylsulfonyl-4h-pyran-derivatives/}, DOI={10.30495/ijc.2022.1958448.1933}, abstractNote={A highly efficient, eco-friendly procedure has been proposed for the synthesis of 2-amino-3-phenylsulfonyl-4H-pyran derivatives via nano-cellulose-OSnCl4-x catalyst prepared from cotton as support treated with tin tetrachloride (SnCl4). This catalyst is characterized by FT-IR, FESEM, TEM, TGA, and EDX. The TEM results confirmed the size of the nano-cellulose-OSnCl4-x catalyst was below 30 nm. The efficiency of this solid acid catalyst was investigated in one-pot, three-component condensation reactions with aromatic aldehydes, dimedone, and phenylsulfonylacetonitrile under reflux conditions. As a result, 2-amino-3-phenylsulfonyl-4H-pyran derivatives were produced under facile conditions in high yield (84-95%) and high rate (30-50 min) using nano-cellulose-OSnCl4-x as a recyclable catalyst. Highlights Preparation, characterization and application of nano-cellulose-OSnCl4-x as a green and natural-based nanocatalyst Nano-cellulose-OSnCl4-x as a renewable nanocatalyst for one-pot synthesis of 2-amino-3-phenylsulfonyl-4H-pyran derivatives Synthesis of new derivatives of 2-amino-7,8-dihydro-7,7-dimethyl-4-phenyl-3-(phenylsulfonyl)-4H-chromen-5(6H)-one Prominent among the advantages of this method are working simplicity, mild reaction condition, short reaction times, higher yields, and environmental friendliness }, number={4}, journal={Iranian Journal of Catalysis}, publisher={OICC Press}, author={Shafe-Mehrabadi, Sayed Rasul and Sadeghi, Bahareh and Mosslemin, Mohammad Hossein and Hashemian, Saeedeh}, year={2023}, month={Dec.}, keywords={Pyran derivatives, Dimedone, Nano-cellulose-OSnCl4-x., Green chemistry, Phenylsulfonylacetonitrile} }