@article{Hir_Mokhtar_Rafaie_Daud_Shohaimi_Alam_2024, title={Efficient photodegradation of paracetamol by TiO2/ZnO photocatalyst and prediction via Fuzzy Inference System}, volume={14}, url={https://oiccpress.com/iranian-journal-of-catalysis/article/efficient-photodegradation-of-paracetamol-by-tio2-zno-photocatalyst-and-prediction-via-fuzzy-inference-system/}, DOI={10.57647/j.ijc.2024.1402.13}, abstractNote={  A facile chemical mixing approach was used to prepare TiO2/ZnO photocatalystswith different mass ratios. The photodegradation activity was tested against paracetamol in an aqueous phase assisted by low UVC-light intensity (9 W). TiO2/ZnO particles mainly exhibited irregular shapes with uniform distributions and high crystallinity degree, the primary oxidation state in the structure is titanium Ti4+ of anatase TiO2 (459.2 and 464.9 eV), and the presence of standard chemical state of Zn2+ (1021.9 and 1044.9 eV). The composite with a 1:5 mass ratio displayed a rapid and outstanding degradation percentage of 95% and a rate of 1.83 × 10-2 min-1. The best photocatalyst can be recycled up to five times towards paracetamol degradation without any regeneration step or severe deactivation. A Fuzzy inference system (FIS) was computed for the first time to investigate the relationship between the TiO2/ZnO ratio, degradation percentage, and rate constant. The optimal concentration of 9 mg/L was obtained, whereby the degradation percentage and rate were sufficiently maintained above 90% and 0.19 mg/L.min, respectively. Using a fuzzy logic controller (FLC) in this work enables future guidance and prediction for developing the best TiO2/ZnO photocatalysts for real-world water remediation processes. Highlights   1.      Facile preparation of TiO2/ZnO composite photocatalyst via simple mixing for degradation of paracetamol under low UVC light intensity (9 W).   2.      TiO2/ZnO particles are mostly exhibited irregular shapes with uniform distributions and high crystallinity degree, the main oxidation state in the structure is titanium Ti4+ of anatase TiO2 (459.2 and 464.9 eV), and the presence of standard chemical state of Zn2+ (1021.9 and 1044.9 eV).   3.      TiO2/ZnO (1:5) displayed a rapid and outstanding degradation percentage of 95% and rate of 1.83 × 10-2 min-1, in accordance with pseudo first-order kinetics.   4.      The optimal concentration of 9 mg/L was computed by the prediction using fuzzy inference system (FIS) for the first time, whereby the degradation percentage and rate were sufficiently maintained above 90% and 0.19 mg/L.min, respectively.   5.      The stability of TiO2/ZnO composite photocatalyst towards paracetamol degradation was retained up to 5 cycles, without undergo any regeneration procedure.    }, number={2}, journal={Iranian Journal of Catalysis}, publisher={OICC Press}, author={Hir, Zul Adlan Mohd and Mokhtar, Hamizah and Rafaie, Hartini Ahmad and Daud, Shaari and Shohaimi, Norshahidatul Akmar Mohd and Alam, Nik Muhammad Farhan Hakim Nik Badrul}, year={2024}, month={May}, keywords={Zinc oxide, Fuzzy inference system, Water remediation, Photodegradation, Titanium dioxide, Paracetamol} }