@article{Hosseini_2024, title={Thermodynamic study of an effective catalytic system, hydrogen peroxide and methyltrioxorhenium}, volume={4}, url={https://oiccpress.com/iranian-journal-of-catalysis/article/thermodynamic-study-of-an-effective-catalytic-system-hydrogen-peroxide-and-methyltrioxorhenium/}, abstractNote={The thermodynamic of the known and very effective catalytic system, hydrogen peroxide (H2O2) and methyltrioxorhenium (MTO) is studied in different solvents using UV-Visible spectroscopic method. The thermodynamic parameters (ΔG, ΔH and ΔS) for two equilibrium reactions, MTO + H2O2 ⇌ A + H2O and A + H2O2 ⇌ B.H2O (A, [MeRe(O)2(O2)]; B.H2O, [MeRe(OH2)(O)(O2)2]), are determined. The obtained free energies of the reactions depend on dielectric constants of solvent, which are explained by Onsager’s reaction field theory.}, number={3}, journal={Iranian Journal of Catalysis}, publisher={OICC Press}, author={Hosseini, Fatemeh Niroomand}, year={2024}, month={Feb.}, keywords={hydrogen peroxide, Methyltrioxorhenium, Thermodynamic study} }