TY - EJOUR AU - Hosseinian, A. AU - Mahjoub, A.R. AU - Movahedi, M. PY - 2024 DA - March TI - Using a bithiazole complex as precursor to synthesis of CdO-CdS nanocomposite via direct thermal decomposition T2 - International Journal of Nano Dimension (Int. J. Nano Dimens.) VL - 1 L1 - https://oiccpress.com/international-journal-of-nano-dimension/article/using-a-bithiazole-complex-as-precursor-to-synthesis-of-cdo-cds-nanocomposite-via-direct-thermal-decomposition/ DO - 10.7508/ijnd.2010.0x.007 N2 - A new tris-chelate Cd(II) complex, [Cd(DADMBTZ)3](ClO3)2 has been successfully synthesized and characterized by IR, 1H, 13C NMR spectroscopy, elemental analysis and single crystal X-ray determination. The thermal behavior, UV-Vis and fluorescence spectra of compound were studied. In reaction with DADMBTZ, Cadmium (II) forms a tris-chelate complex with nearly C3 symmetry for coordination polyhedron, DADMBTZ acts as a bidentate ligand. In complex the ClO3 - anions are symmetrically different. Complex makes 2-D and 3-D networks via N-H…O and N-H…N hydrogen bonds, respectively. The nanocomposite CdO-CdS have been prepared using [Cd(DADMBTZ)3](ClO3)2 as precursor via thermal decomposition. As-prepared CdO-CdS nanocomposite was characterized By X-ray diffraction measurements (XRD), scanning electron microscopy (SEM). IS - 1 PB - OICC Press KW - Nanocomposite, Thermal decomposition, Bithiazole, complex, CdO-CdS EN -