10.1007/s40095-019-00323-2

The role of alkali metal and alkaline metal earth in natural zeolite on combustion of Albizia Falcataria sawdust

  1. Department of Mechanical Engineering, Universitas Muhammadiyah Jember, Jember, East Java, 68152, ID
  2. Department of Mechanical Engineering, Brawijaya University, Malang, East Java, 65145, ID
Cover Image

Published in Issue 2020-01-11

How to Cite

Hairul Bahri, M., Wijayanti, W., Hamidi, N., & Wardana, I. N. G. (2020). The role of alkali metal and alkaline metal earth in natural zeolite on combustion of Albizia Falcataria sawdust. International Journal of Energy and Environmental Engineering, 11(2 (June 2020). https://doi.org/10.1007/s40095-019-00323-2

PDF views: 144

HTML views: 105

Abstract

Abstract The combustion process of Albizia falcataria (AF) sawdust with the addition of natural zeolite (NZ) was observed experimentally using PT 1600 LINSEIS Simultaneous thermal analyzer (STA). The results showed that alkali metal and alkaline metal earth in NZ play an essential role in the process of decomposing the Hemicellulose AF molecule. The results of the molecular analysis show that the chemical balance of the mixture determines the combustion temperature. Excess NZ becomes a thermal burden which slows down the combustion reaction because heat does not sufficiently activate alkali metal and alkaline metal earth in NZ. In a small amount, NZ is less involved in the AF decomposition process. It shows that a mixture of AF and NZ can increase combustion kinetic in the right mix. Addition of 15–20% of NZ decreases the ignition temperature within faster burning rate. Activated alkali metal and alkaline metal earth decompose hemicellulose faster so that they burn completely in minimizing pollutant and maximizing LHV. Greater NZ completes the decomposition much earlier so that at the resting time of the process NZ slightly absorbs heat sinking LHV. The drastic reduction of Ca due to NZ make the fuel is suitable for boiler because Ca is responsible for agglomeration and corrosion.

Keywords

  • Albizia falcataria,
  • Ignition temperature,
  • Combustion kinetic,
  • Zeolite catalyst

References

  1. Bakaruddin (1992) The University of Melbourne
  2. J. A. Duke.: Handbook of energy crops. 1983. Available:
  3. https://hort.purdue.edu/newcrop/duke_energy/Albizia_falcataria.html
  4. .
  5. Lazaroiu et al. (2018) Experimental investigations of innovative biomass energy harnessing solutions https://doi.org/10.3390/en11123469
  6. Lazaroiu et al. (2017) Biomass combustion with hydrogen injection for energy applications (pp. 351-357) https://doi.org/10.1016/j.energy.2017.03.133
  7. Lazaroiu, G., Mihaescu, L., Pisa, I., Pop, E., Negreanu, G.N., Berbece, V., HYDROGEN-An energy vector in efficient combustion of energy willow. In: 2014, 49th international universities power engineering conference (UPEC), ClujNapoca, ROMANIA, SEP 02–05, 2014, ISBN:978-1-4799-6557-1, Book Group Author(s) IEEE. Publisher IEEE (2014).
  8. https://doi.org/10.1109/UPEC.2014.6934830
  9. Pisa et al. (2012) Experimental studies on the corrosion occurrence during biomass combustion process 11(9) (pp. 1555-1560) https://doi.org/10.30638/eemj.2012.19
  10. Demirbas (2004) Combustion characteristics of different biomass fuels 30(2) (pp. 219-230) https://doi.org/10.1016/j.pecs.2003.10.004
  11. Kantarelis et al. (2014) Effect of zeolite to binder ratio on product yields and composition during catalytic steam pyrolysis of biomass over transition metal modified HZSM5 (pp. 119-125) https://doi.org/10.1016/j.fuel.2013.12.054
  12. Horne and Williams (1995) The effect of zeolite ZSM-5 catalyst deactivation during the upgrading of biomass-derived pyrolysis vapours 34(1) (pp. 65-85) https://doi.org/10.1016/0165-2370(94)00875-2
  13. Horne and Williams (1996) Upgrading of biomass-derived pyrolytic vapours over zeolite ZSM-5 catalyst: effect of catalyst dilution on product yields 75(9) (pp. 1043-1050) https://doi.org/10.1016/0016-2361(96)00082-8
  14. Azeez et al. (2011) Journal of analytical and applied pyrolysis effects of zeolites on volatile products of beech wood using analytical pyrolysis 91(2) (pp. 296-302) https://doi.org/10.1016/j.jaap.2011.03.007
  15. Gil et al. (2010) Bioresource technology thermal behaviour and kinetics of coal/biomass blends during co-combustion 101(14) (pp. 5601-5608) https://doi.org/10.1016/j.biortech.2010.02.008
  16. Kai et al. (2011) The effect of biomass components on the co-combustion characteristics of biomass with coal (pp. 1274-1278)
  17. Shen and Qinlei (2006) Study on MSW catalytic combustion by TGA 47(11–12) (pp. 1429-1437) https://doi.org/10.1016/j.enconman.2005.08.016
  18. Zhaosheng et al. (2008) Kinetic studies on catalytic combustion of rice and wheat straw under air- and oxygen-enriched atmospheres, by using thermogravimetric analysis 32(11) (pp. 1046-1055) https://doi.org/10.1016/j.biombioe.2008.02.001
  19. Zhang et al. (2015) Bioresource Technology Thermogravimetric investigation on characteristic of biomass combustion under the effect of organic calcium compounds (pp. 174-181) https://doi.org/10.1016/j.biortech.2014.10.077
  20. Shen et al. (2009) Kinetic study on thermal decomposition of woods in oxidative environment 88(6) (pp. 1024-1030) https://doi.org/10.1016/j.fuel.2008.10.034
  21. Kusuma et al. (2013) Natural zeolite from Pacitan Indonesia, as catalyst support for transesterification of palm oil (pp. 121-126) https://doi.org/10.1016/j.clay.2012.04.021
  22. Hernawan et al. (2015) Modification of Gunungkidul natural zeolite as bioethanol dehydrating agents (pp. 116-120) https://doi.org/10.1016/j.egypro.2015.01.042
  23. Magdziarz and Wilk (2018) Thermogravimetric study of biomass, sewage sludge and coal combustion 75(2013) (pp. 425-430)
  24. López-González et al. (2013) Thermogravimetric-mass spectrometric analysis on combustion of lignocellulosic biomass (pp. 562-574) https://doi.org/10.1016/j.biortech.2013.06.052
  25. Konsomboon et al. (2011) Effect of kaolin addition on ash characteristics of palm empty fruit bunch (EFB) upon combustion 88(1) (pp. 298-305) https://doi.org/10.1016/j.apenergy.2010.07.008
  26. Zhaosheng et al. (2009) Thermogravimetric analysis of rice and wheat straw catalytic combustion in air-and oxygen-enriched atmospheres 50(3) (pp. 561-566) https://doi.org/10.1016/j.enconman.2008.10.022
  27. Gai et al. (2013) Thermogravimetric and kinetic analysis of thermal decomposition characteristics of low-lipid microalgae (pp. 139-148) https://doi.org/10.1016/j.biortech.2013.09.137
  28. Huber and Corma (2007) Synergies between bio-and oil refineries for the production of fuels from biomass 46(38) (pp. 7184-7201) https://doi.org/10.1002/anie.200604504
  29. Khan et al. (2008) Biomass combustion in fluidized bed boilers: potential problems and remedies 90(1) (pp. 21-50) https://doi.org/10.1016/j.fuproc.2008.07.012
  30. Cheng et al. (2012) A modulated-TGA approach to the kinetics of lignocellulosic biomass pyrolysis/combustion 97(9) (pp. 1606-1615) https://doi.org/10.1016/j.polymdegradstab.2012.06.027
  31. Yang et al. (2006) Liang DT, In-depth investigation of biomass pyrolysis based on three major components: hemicellulose, cellulose and lignin 201(17) (pp. 388-393) https://doi.org/10.1021/ef0580117
  32. Stefanidis et al. (2014) Journal of analytical and applied pyrolysis a study of lignocellulosic biomass pyrolysis via the pyrolysis of cellulose, hemicellulose and lignin (pp. 143-150) https://doi.org/10.1016/j.jaap.2013.10.013
  33. Pang et al. (2014) Relationship between thermal behaviour of lignocellulosic components and properties of biomass (pp. 312-320) https://doi.org/10.1016/j.biortech.2014.09.042
  34. Williams and Williams (1996) The influence of temperature and heating rate on the slow pyrolisis of biomass 1481(96) (pp. 6-7)
  35. Liu et al. (2002) Catalytic reduction of SO2 during combustion of typical Chinese coals 79(2) (pp. 157-169) https://doi.org/10.1016/S0378-3820(02)00110-8
  36. Shenqi et al. (2011) Effects of alkaline metal on coal gasification at pyrolysis and gasification phases 90(5) (pp. 1723-1730) https://doi.org/10.1016/j.fuel.2011.01.033